• Title/Summary/Keyword: Organic removal

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Characteristics of treatment by Electrolysis with a change of electrodes in sanitary landfill leachate (전기분해법에서의 전극변화에 따른 위생매립장 침출수의 처리특성)

  • Huh, Mock;Kim, Byung-Hyun;Kim, Gwang-Jin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.1
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    • pp.68-74
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    • 2002
  • This study was performed to examine the availability of electrolysis for removal of remaining biologically refractoty humus and residual color of leachate which is biologically pretreated in domestic waste matter sanitary landfill by recycling to landfill. The obtained results were as follows; 1) The electrolysis of leachate through covered bed represented that the removal efficiency of CODcr and color range from 70~80%, in color removal the only electrolysis for a treatment of leachate meet the critia of effluent. 2) The highest removal efficiency was represented in pH 7~8. 3) At anode used Al, Fe, Stainless the removal efficiency of CODcr and color was high in order of Fe, Al, stainless, in considering the settled ability of reaction product in economic or after electro coagulation the removal efficiency was highest when anode was the Fe electrode. 4) In this study conditions for removed both CODcr and Color ar the same time represented thar anode was used Fe, electrode-distance was 2cm and reaction time was 40min in 8volts.

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The Removal of Algae by Pre-oxidation (전산화 공정을 이용한 조류제거)

  • Son, Hee-Jong;Jung, Chul-Woo;Bae, Sang-Dae;Choi, Young-Ik;Kang, Lim-Seok
    • Journal of Environmental Science International
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    • v.18 no.3
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    • pp.289-298
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    • 2009
  • The blue-green algae which caused odor problem in the tap water are difficult to precipitate in sedimentation basin and clogged the filter void rapidly. The studies of this paper were not only oxidation, coagulation and sedimentation processes for effectively removing blue-green algae but yellow clay and polyamine for verification as coagulants aids. The results of this research are summarized as follows: Higher ozone dose(C) and longer contact time(T) were needed for a high degree of removing blue-green algae efficiency. the removal rate of blue-green algae was proportional to the $C\times T$ value. The removal percent of chlorophyll-a by sedimentation and filter without pre-ozonation was about 75% but 1 mg/L pre-ozonation could increase the removal percent of chlorophyll-a to 99% and more pre-ozonation could remove completely. Though the removal efficiency of turbidity could increased by high dose of chlorination, the dissolved organic carbon was increased. More chlorine dose from 4 to 10 mg/L dissolved organic carbon was decreased. Using yellow clay as coagulant aids increased density of floc so the settling velocity of floc become rising but polyamine could not increase settling velocity of floc though it could formated large floc.

Removal of Nitrogen in Seafood Processing Wastewater Using High-rate Anaerobic Process and Nitritation-denitritation (고율 혐기성 공정과 아질산-아탈질을 연계한 수산물가공폐수의 질소제거)

  • Choi, Yong-Bum;Kang, Dong-Gu;Park, Sang-Sung;Eum, Ki-Hyun;Rim, Jay-Myung;Kwon, Jae-Hyouk
    • Journal of Environmental Health Sciences
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    • v.37 no.4
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    • pp.315-322
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    • 2011
  • Objectives: Organic matter and nitrogen were removed using the EGSB process, a high-rate anaerobic process, in combination with a nitritation-denitritation process, in order to ensure the stable treatment of seafood processing wastewater. Methods: The upflow velocity of an EGGS reactor was operated at 10 m/hr for maximal organics removal efficiency. For removal of nitrogen from seafood processing wastewater a nitritation-denitriation process was applied Results: The efficiency of the EGSB process showed that it has an 80% or more organic matter (CODcr) removal efficiency with an HRT of six hours or more at influent loadings of 17.34 kgCOD/$m^3$/day or less. The methane product for TCODcr removal was 0.23-0.38 $m^3CH_4$/kgCODrem., which was similar to the theoretical generation of STP-state methane, 0.35 $m^3CH_4$/kgTCODrem. In the nitritation-denitritation process, the nitritation conversion rate to $NH_4^+$-N concentration was 82% to 87%, 72% to 81% and 64% to 69% when HRT was 24 hr, 21 hr and 18 hr, respectively. In the denitritation process, the ratio of SCOD consumption to NOx-N removal ranged from 2.347 to 2.587. It was 2.472 on average. Conclusions: The optimal HRT for stable processing of seafood processing wastewater is six hours or more. The ratio of nitrite to total NOx-N was 82% to 96%, which indicates that nitrite accounts for the largest portion of the product.

Effect of Several Native Moss Plants on Particulate Matter, Volatile Organic Compounds and Air Composition

  • Gong, Gyeong Yeop;Kang, Ji Su;Jeong, Kyeong Jin;Jeong, Jun Ho;Yun, Jae Gill
    • Journal of People, Plants, and Environment
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    • v.22 no.1
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    • pp.31-38
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    • 2019
  • Experiments were carried out to investigate the effects of mosses on the removal of particulate matter (PM 10) and volatile organic compounds (VOCs) in an indoor space and on the composition of air. For particulate matter removal experiments, 0.2 g mosquitto coil was burned in a glass chamber, where three kinds of mosses (Plagiomnium cuspidatum, Myuroclada maximowiczii, Etodon luridus) were placed. For VOCs removal experiments, 1 mL paint thinner was volatilized in a glass chamber, where Plagiomnium cuspidatum and Myuroclada maximowiczii were used. As a result, it was found that particulate matter was effectively removed by the three mosses, and the removal efficiency of particulate matter increased as the amount of mosses increased. The amount of VOCs was similar to the level in the control when a low amount of mosses (2 and 4 plates) was used. However, the removal efficiency of VOCs was significant when 6 plates of mosses were used. On the other hand, formaldehyde concentration was 40 times more than the control and carbon monoxide 30 times, when 0.2 g of mosquito repellent was completely burned in a glass chamber. Also formaldehyde removal effect was significant when 6 plates of mosses were placed. However, there was no change in the concentration of indoor oxygen, temperature and humidity by moss plants. In conclusion, the moss plants were effective in removing particulate matter and VOCs, and they are expected to be used for indoor decoration and landscape in order to improve indoor air quality in the future.

Effects of Antimicrobials on Methane Production in an Anaerobic Digestion Process (혐기소화공정에서 항생항균물질이 메탄생성에 미치는 영향)

  • Oh, Seung-Yong;Park, Noh-Back;Park, Woo-Kyun;Chun, Man-Young;Kwon, Soon-Ik
    • Korean Journal of Environmental Agriculture
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    • v.30 no.3
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    • pp.295-303
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    • 2011
  • BACKGROUND: Anaerobic digestion process is recently adapted technology for treatment of organic waste such as animal manure because the energy embedded in the waste can be recovered from the waste while the organic waste were digested. Ever increased demand for consumption of meat resulted in the excessive use of antimicrobials to the livestocks for more food production. Most antimicrobials administered to animals are excreted through urine and feces, which might highly affect the biological treatment processes of the animal manure. The aim of this study was to investigate the effects of antimicrobials on the efficiency of anaerobic digestion process and to clarify the interactions between antimicrobials and anaerobes. METHODS AND RESULTS: The experiment was consisted of two parts 1) batch test to investigate the effects of individual antibiotic compounds on production of methane and VFAs(volatile fatty acids), and removal efficiency of organic matter, and 2) the continuous reactor test to elucidate the effects of mixed antimicrobials on the whole anaerobic digestion process. The batch test showed no inhibitions in the rate of methane and VFAs production, and the rate of organic removal were observed with treatment at 1~10 mg/L of antimicrobials while temporary inhibition was observed at 50 mg/L treatment. In contrast, treatment of 100 mg/L antimicrobials resulted in continuous decreased in the rate of methane production and organic removal efficiency. The continuous reactor test conduced to see the influence of the mixed antimicrobials showed only small declines in the methane production and organic matter removal when 1~10 mg/L of combined antimicrobials were applied but this was not significant. In contrast, with the treatment of 50 mg/L of combined antimicrobials, the rate of organic removal efficiency in effluent decreased by 2~15% and the rate of biogas production decreased by 30%. CONCLUSION(s): The antimicrobials remained in the animal manure might not be removed during the anaerobic digestion process and hence, is likely to be released to the natural ecosystem. Therefore, the efforts to decline the usage of antimicrobials for animal farming would be highly recommended.

Removal Characteristics of Natural Organic Matters in Activated Carbon and Biofiltration Process (활성탄 공정과 생물여과 공정에서의 자연유기물질 제거특성)

  • Son, Hee-Jong;Choi, Keun-Joo;Kim, Sang-Goo
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.2
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    • pp.205-213
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    • 2007
  • We have studied NOM(natural organic matters) adsorption and biodegradation on 3 kinds of activated carbon and a anthracite. Coal based activated carbon showed the highest DOC(dissolved organic carbon) adsorption capability and roconut(samchully), wood (pica) in the order among the 3 kinds of activated carbon(F400). The biomass amount and activity also showed on coal, wood and coconut based activated carbon in the order. Over 15 minutes EBCT(empty bed contact time) needed to achieve 10 to 17% average removal efficiency and $18\sim24%$ maximum removal efficiency of NOM biodegradation in biofilter using anthracite. Hydrophobic and below 10,000 dalton NOM was much easier to adsorb into the activated carbon than hydrophilic NOM, THMFP(trihalomethane formation potential) and BDOC (biodegradable dissolved organic carbon)$_{slow}$ were much easier than HAA5FP(haloacetic acid 5 formation potential) and $BDOC_{rapid}$ to adsorb into the activated carbon. Hydrophilic and below 1,000 dalton NOM was much easily biodegraded and HAA5FP and $BDOC_{rapid}$ was easier than THMFT and $BDOC_{slow}$ to biodegrade in the biofilter.

Evaluation for the simultaneous Removal of Organic Matters and Nutrients by the RBC and tapered Aeration Processes with Bacillus sp. for the high Strength of Dairy Wastewater (바실러스 미생물을 이용한 고농도 유가공 폐수처리에 있어서 유기물질과 영양염류의 동시제거에 대한 평가)

  • Lee, Sang-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.2
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    • pp.195-202
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    • 2010
  • The evaluation of organic matters and nutrients removal was investigated for the synthetic wastewater and the high strength of dairy wastewater. Two different systems were performed for this research. System A composing of a single RBC with tapered aeration was fed with the synthetic wastewater for 74 days with 173L/day of influent, 200% of internal return and 100% of sludge return for the period 1 and 2. The feed conditions were maintained 346L/day of influent, 50% of internal return and sludge return for the period 3. The dairy wastewater was introduced to evaluate treatment efficiency for system B composing of dual RBCs and tapered aeration tanks for 50 days of experimental run time, in which hydraulic rates were maintained at the constant ratios of 346L/day, 50% of internal return and 50% of sludge return. The spiral string media made of nylon fibre was attached by Bacillus sp. in RBC for both systems. The specific area of string media was $1.4m^2$/m and biomass was maintained at the concentrations of 23g/m. The synthetic wastewater was supplied by 1,800mg/L of glucose, 500mg/L of $NH_4Cl$, and 500mg/L of $KH_2PO_4$ to system A. The dairy wastewater was supplied to system B from dairy production plant. The average influent concentrations were 1,334mg/L of BOD, 2,014mg/L of CODcr, 160mg/L of T-N, and 12mg/L of T-P in system A. The average influent concentrations of parameters were 1,006 mg/L for BOD, 1,875mg/L for $COD_{cr}$, 51.6mg/L for T-N and 8.9mg/L for T-P in system B. Results indicated that removal efficiencies of BOD and $COD_{cr}$ were more than 90% however, the removal efficiency of T-N was 87%, and that of T-P was 82% for system A. Removal efficiencies were 98.5% of BOD, 91.3% of nitrogen and 89% of phosphorus for system B. The removal efficiencies of organic matters, T-N and T-P were higher in system B than in system A. The effluent quality issued by the stringent national legislations for the discharge of the high strength of dairy products wastewater can be improved using sequential RBCsand tapered aeration reactors rather than a single RBC and tapered aeration reactors with Bacillus sp.

The Effect of the Attached Growth in Aerobic Reactor on Nitrogen Removal in A2/O processes (포기조에 충진된 고정상 담체가 A2/O공정에서 질소제거에 미치는 영향)

  • Whang, Gye-Dae;Bae, Sung-Hyun
    • Journal of Korean Society on Water Environment
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    • v.22 no.6
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    • pp.1022-1030
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    • 2006
  • Activated sludge reactors maintaining an MLSS of 3,000 mg/L and packed Bio Contact Media (BCM fixed beds) was studied in lab-scale to determine the optimal packing ratio and an HRT of aerobic reactor in terms of organic removal, nitrification, denitrification efficiencies. At all HRTs of 3 hr, 5 hr, 7 hr respectively, reactors without BCM, control reactors, had the lowest TCODcr removal efficiency about 74.6%, and reactors with the BCM packing ratios of 10%, 15%, 20% had a greater TCODcr removal efficiency above 81.4%. As HRT decreased, the TCODcr removal efficiency decreased also in all reactors. However, a better utilization of TCODcr even at a higher organic loading was observed in reactors with BCM. The nitrification efficiency at all reactors was greater than 94%, and reactor with 20% packing of BCM had the highest nitrification efficiency at 97.9% while the TKN loading increased at $0.085mgTKN/m^3{\ast}day$ as HRT decreased, In terms of denitrification efficiency, the reactor without BCM ranged from 11.6% to 13.7%, and the reactors with BCM ranged from 28.3% to 63.4% which suggests that the more BCM is packed in the reactors, the higher the denitrification efficiency is achieved. Two parallel $A^2/O$ systems maintaining an MLSS of 3,000 mg/L were operated to investigate the effect of BCM packing ratio of 20% on organic removal, nitrification, denitrification efficiencies. Packing with BCM in system of aerobic reactor affected the SCODcr removal efficiency that increased from 73% to 78%. The nitrification efficiency for both systems with or without BCM was greater than 95%. The denitrification efficiency of systems with BCM and without BCM was 85.8% and 81.8%, respectively which appears that the denitrification efficiency was increased slightly by packing BCM. Compared denitrification efficiency in $A^2/O$ system to previous experimental study with activated sludge reactors operates with the same HRT $A^2/O$ system showed only 29% greater denitrification efficiency. It suggests that $A^2/O$ system with BCM can achieve a similar level of denitrification efficiency when the HRT of anoxic reactor is decreased to some extent.

Denitrification of Synthetic Wastewater in Submerged Biofilter (침지식 여과조를 이용한 합성 폐수의 탈질화)

  • 오승용;조재윤;김인배
    • Journal of Aquaculture
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    • v.10 no.3
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    • pp.335-346
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    • 1997
  • Denitrification is one of the important processes of removing nitrate from in recirculating aquaculture systems. And this process is affected by many factors such as external organic carbon sources, hydraulic retention time (HRT), COD/NO3--N (C:N) ratio, etc. However, not many studies were done for the optimum conditions of denitrification in the recirculation system for aquaculture. Therefore, this study was conducted to find out the optimum removal condition of NO3--N using submerged denitrification biofilter. The combinations of two external organic carbon sources (glucose and methanol), two HRT (4 and 8-hour) and four differnent C : N ratios (3, 4, 5, 6) were tested. The removal efficiencies of NO3--N and total inorganic nitrogen (TIM) at 8-hour HRT were better than those at 4-hour's (P<0.05). The maximum removal efficiency of NO3--N by methanol (97.8%) was achieved at HRT and C : N ratio were 8-hour and 4.0 respectively. The efficiencies of methanol for the removal of NO3--N and TIN were always better than those of glucose (P<0.05). The maximum removal efficiencies of total inorgainc nitrogen (TIN) were gained at C : N ration of 5.0. The maximum removel efficiencies of TIN using methanol and glucose were 96.9% and 71.5% respectively. Anaerobic condition which is necessary for denitrification process was not made until the 8-hour HRT and higher C : N ratio (5.0). Removal of NO3--N at 4-hour HRT and C : N ration lower than 5.0 were inhibited by oxygen and/or low quantity of external organic carbon. Removal efficiencies of NO3--N were also inhibited by high C : N (6.0) ratio when HRT was 8-hour.

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Optimum dimensionally stable anode with volatilization and electrochemical advanced oxidation for volatile organic compounds treatment (전극의 부반응 기포발생에 따른 휘발특성과 전기화학고도산화능을 동시에 고려한 휘발성 유기화합물 처리용 최적 불용성전극 개발)

  • Cho, Wan-Cheol;Poo, Kyung-Min;Lee, Ji-Eun;Kim, Tae-Nam;Chae, Kyu-Jung
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.1
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    • pp.31-41
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    • 2019
  • Volatile organic compounds(VOCs) are toxic carcinogenic compounds found in wastewater. VOCs require rapid removal because they are easily volatilized during wastewater treatment. Electrochemical advanced oxidation processes(EAOPs) are considered efficient for VOC removal, based on their fast and versatile anodic electrochemical oxidation of pollutants. Many studies have reported the efficiency of removal of various types of pollutants using different anodes, but few studies have examined volatilization of VOCs during EAOPs. This study examined the removal efficiency for VOCs (chloroform, benzene, trichloroethylene and toluene) by oxidization and volatilization under a static stirred, aerated condition and an EAOP to compare the volatility of each compound. The removal efficiency of the optimum anode was determined by comparing the smallest volatilization ratio and the largest oxidization ratio for four different dimensionally stable anodes(DSA): Pt/Ti, $IrO_2/Ti$, $IrO_2/Ti$, and $IrO_2-Ru-Pd/Ti$. EAOP was operated under same current density ($25mA/cm^2$) and electrolyte concentration (0.05 M, as NaCl). The high volatility of the VOCs resulted in removal of more than 90% within 30 min under aerated conditions. For EAOP, the $IrO_2-Ru/Ti$ anode exhibited the highest VOC removal efficiency, at over 98% in 1 h, and the lowest VOC volatilization (less than 5%). Chloroform was the most recalcitrant VOC due to its high volatility and chemical stability, but it was oxidized 99.2% by $IrO_2-Ru/Ti$, 90.2% by $IrO_2-Ru-Pd/Ti$, 78% by $IrO_2/Ti$, and 75.4% by Pt/Ti anodes The oxidation and volatilization ratios of the VOCs indicate that the $IrO_2-Ru/Ti$ anode has superior electrochemical properties for VOC treatment due to its rapid oxidation process and its prevention of bubbling and volatilization of VOCs.