• Title/Summary/Keyword: Organic phosphorus

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Contemporary Organic Contamination Levels in Digested Sewage Sludge from Treatment Plants in Korea : (3) Organophosphorus Insecticides (우리나라 하수 및 폐수 처리 슬러지의 유기인계 살충제의 함량)

  • Hong Gi-Hoon;Lee Kang-Young;Chung Chang-Soo;Lee Hyun-Kyung
    • Journal of Environmental Science International
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    • v.15 no.3
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    • pp.229-236
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    • 2006
  • Organophosphorus pesticides (OPPs) contents in the sewage sludge derived from the residential and industrial areas were determined in order to characterize contemporary organic contamination levels as a part of the ongoing development of the environmentally sound sewage sludge management strategy in Korea. OPPs were extracted from freeze-dried sludges in a ultrasonic extractor. The extracts were cleaned-up by florisil column and subsequently fed into gas chromatograph/nitrogen phosphorus detector (GC/NPD) for determining OPP contents. Diazinon, dimethoate, disulfoton, EPN, malathion, methyl parathion, parathion, phorate and sulfotep were present in the appreciable amount in the domestic sewage sludges. The sum of the 9 OPPs in the sewage sludge varied from 534.8 to 15552.1 ${\mu}g/kg$, dry wt..

A Study on the Development of Regional Livestock Industry Based on Sustainable Agriculture in Korea (친환경농업을 위한 지역축산발전 방향에 관한 연구)

  • Sim, Jae-Chun
    • Korean Journal of Organic Agriculture
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    • v.13 no.4
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    • pp.339-355
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    • 2005
  • Nutrient balance is important to develop environmentally friendly agriculture. Phosphorus surplus in nutrient balance was more serious than that of nitrogen. Nitrogen and phosphorus exceeded twice the requirement at 30 cities/counties and 32 among 165, respectively. Given livestock waste and optimal nutrient balance, the proper number of animal feeding was 1.68LU/ha. Considering livestock waste only, the optimal number of livestock feeding was 3,918,000LU (heads) and, including fertilizer that would be 2,288,000LU. It is recommended to introduce the regional control system to regulate nutrient input and output, and the trading system of livestock feeding rights to control that.

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A Study on Phosphorus and Nitrogen Removal with Unit Operation in the Ferrous Nutrient Removal Process (철전기분해장치(FNR)에서 단위공정에 따른 질소와 인의 제거)

  • Kim, Soo Bok;Kim, Young-Gyu
    • Journal of Environmental Health Sciences
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    • v.39 no.1
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    • pp.83-89
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    • 2013
  • Objectives: The purpose of this experiment was to illuminate the relationship between the phosphorus removal rate of unit operation and the phosphorus removal rate of phosphorus volume loading in the Ferrous Nutrient Removal process, which consists of an anoxic basin, oxic basin, and iron precipitation apparatus. Methods: This study was conducted in order to improve the effect of nitrogen and phosphorus removal in domestic wastewater using the FNR (Ferrous Nutrient Removal) process which features an iron precipitation reactor in anoxic and oxic basins. The average concentration of TN and TP was analyzed in a pilot plant ($50m^3/day$). Results: The removal rate of T-N and T-P were 66.5% and 92.8%, respectively. The $NH_3-N$ concentration of effluent was 2.62 mg/l with nitrification in the oxic basin even though the influent was 17.7 mg/l. The $NO_3$-N concentration of effluent was 5.83 mg/l through nitrification in oxic basin even though the influent and anoxic basin were 0.82 mg/l and 1.00 mg/l, respectively. The specific nitrification of the oxic basin ($mg.NH_3$-Nremoved/gMLVSSd) was 16.5 and specific de-nitrification ($mg.NO_3$-Nremoved/gMLVSSd) was 90.8. The T-P removal rate was higher in the oxic basin as T-P of influent was consumed at a rate of 56.3% in the anoxic basin but at 90.3% in the oxic basin. The TP removal rate (mg.TP/g.MLSS.d) ranged from 2.01 to 4.67 (3.06) as the volume loading of T-P was increased, Conclusions: The test results showed that the electrolysis of iron is an effective method of phosphorus removal. Regardless of the temperature and organic matter content of the influent, the quality of phosphorus in the treated water was both relatively stable and high due to the high removal efficiency. Nitrogen removal efficiency was 66.5% because organic matter from the influent serves as a carbon source in the anoxic basin.

Effects of Chemical Amendments on Phosphorus and Total Volatile Fatty Acids in Hanwoo Slurry (한우액상분뇨에 화학제재를 첨가 시 인과 총 휘발성지방산 함량에 미치는 영향)

  • Choi, In-Hag;Choi, Jung-Hoon
    • Journal of Environmental Science International
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    • v.18 no.7
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    • pp.819-824
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    • 2009
  • The objectives of this study were to evaluate the effects of chemical additives on total phosphorus (TP), soluble reactive phosphorus (SRP), and total volatile fatty acids (total VFAs) in hanwoo slurry. The treatments in this study were ferrous sulfate, alum, and aluminum chloride, and applied at the rate of 0, 0.5, and 1.0 g/25 g of hanwoo slurry. All of the chemical treatments significantly lowered TP (11 to 53% of the untreated control), SRP (41 to 99.9% of the untreated control), and total VFAs (22 to 48.5% of the untreated control) by reducing hanwoo slurry pH (3.42 to 6.86). Among these chemical amendments, addition of 0.5 g ferrous sulfate, alum, and aluminum chloride to hanwoo slurry were the best results evaluated on farms with respect to reducing negative environmental impacts. In conclusion, the results of this study indicate that the use of chemical amendments should be considered in the development of best management practices (BMPs) for the hanwoo industries.

Characteristics of Nitrogen and Phosphorus Removal According to the Variation of Operating Cycles in (AO)2 SBBR ((AO)2 SBBR에서 운전주기에 따른 질소와 인 제거 특성 비교)

  • Park, Young-Seek;Kim, Dong-Seog
    • Journal of Environmental Science International
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    • v.16 no.1
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    • pp.45-53
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    • 2007
  • This study was carried out to investigate the variation of organic, nitrogen and phosphorus in $(AO)_2$ SBBR process according to the variation of operating cycle at the high TOC concentration. The operation time in anoxic (anaerobic) time to oxic time was 1:1. Three lab-scale SBBRS were fed with synthetic wastewater based on glucose as carbon source, The variation of total TOC removal was similar each other irrespective of operation time, however, the TOC concentrations in SBBRs showed a little difference according to the operating condition. In SBBR, complete nitrification was not occurred at all reactors, however, R3 showed a higher nitrification than R2. And in SBBR, the variation of operating time more affected at phosphorus removal than nitrogen removal. R2 which had the shortest time at the 1st aeration time showed the lowest phosphorus release and uptake efficacy.

The Processing of Livestock Waste Through the Use of Activated Sludge - Treatment with Intermittent Aeration Process -

  • Osada, T.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.5
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    • pp.698-701
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    • 2000
  • To prevent surface and underground water pollution, wastewater treatment is essential. Four bench-scale activated sludge units (10 L operational volumes) were operated at 5, 10 and $20^{\circ}C$ for evaluation of treatment efficiencies with typical wastewater from swine housing. The units were set for a 24-hour cycle. As compared to the conventional process, high removal efficiencies for organic substances, nitrogen and phosphorus in swine wastewater were obtained simultaneously with an intermittent aeration process (lAP). The NOx-N produced during an aeration period was immediately reduced to nitrogen gas (e.g. $N_2$ or $N_2O$) in the subsequent non-aeration periods, and nitrification in aeration periods occurred smoothly. Under these conditions, phosphorus removal occurred with the release of phosphorus during the non-aeration periods followed by the excess uptake of phosphorus in the activated sludge during aeration periods. It was confirmed that the lAP had a better ability to remove pollutants under both low temperatures and high nitrogen loading conditions than the ordinary method did. In addition to that, the total emission of $N_2O$ from lAP was reduced to approximately 1/50 of the conventional process for the same loading. By adopting an adequate aeration programme for individual swine wastewater treatment, this system will provide a promising means for nitrogen and phosphorus control without pH control or addition of methanol.

Measurement of Phosphorus in Soil and Water

  • Kim, Hye-Jin;Hwang, Seong-Woo;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.4
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    • pp.539-544
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    • 2011
  • The relative focus about phosphorus (P) which causes eutrophication characterized by increased growth of undesirable algae has increased in recent years. Phosphorus forms in soil and water include both organic and inorganic forms. There are also a large number of soil P determination methods that have been designed to account for various types of P and mechanisms controlling the chemistry of P in soil, water, and residual materials for environmentally relevant forms of P. However, phosphorus forms in soil, water, and residual materials are also difficult to standardize with any reasonable consensus, due to the number of different disciplines involved. Hence, it is essential to accurately define how P can be measured in soil, water, or residual material samples to avoid potential misinterpretations or inappropriate recommendations in determining amount and types of P. Therefore, we reviewed the testing methods which have appeared in the scientific literature to provide an overview of the soil test P most commonly used.

A Simultaneous Removal of Organic, Nitrogen and Phosphorus According to the Distribution of Aeration Time in (AO)2 SBBR ((AO)2 연속 회분식 생물막 반응기에서 포기 시간 배분에 따른 유기물 및 질소와 인의 동시 제거에 관한 연구)

  • Park Young-Seek;Kim Dong-Seog
    • Journal of Environmental Science International
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    • v.14 no.9
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    • pp.861-871
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    • 2005
  • This study was carried out to get more operational characteristics of Anoxic(anaerobic)-Oxic-Anoxic-Oxic $(AO)_2$ sequencing batch biofilm reactors (SBBRs) at the low TOC concentration, The operating time in anoxic (anaerobic) time to oxic time was I : I. Experiments were conducted to find the effects of the aeration time distribution on the organic matters and nutrients removal. Three lab-scale reactors were fed with synthetic wastewater based on glucose as carbon source. During studies, the operation mode was fixed. The first aeration time to the second aeration time in SBBR-I was 2 : 3, and those in SBBR-2 and SBBR-3 were I : 4 and 3 : 2, respectively. The organic removal efficiency didn't show large difference among three reactors of different aeration time distribution. However, from these study results, the optimum aeration time distribution in the first and the second aeration time for biological nutrient removal was shown as 3 : 2. The release of phosphorus was inhibited at the second non-aeration period because of the low TOC concentration and the nitrate produced by the nitrification at the first aeration period.

Effects of Green Manures on Rice using P32 (P32를 이용한 녹비의 수도에 대한 비효에 관하여)

  • 김길환
    • Journal of Plant Biology
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    • v.11 no.3
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    • pp.1-7
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    • 1968
  • Organic matter in rice-paddy soils exercises two antagonistic effects on the rice plant under water-logged conditions in growing season in the course of its decomposition: It liberates mineral nutrients and promotes soil fertility. On the other hand, however, it demands oxygen for its decay and therefore competes with rice roots for this element, when applied in large quantity of fresh status. For the practical end of rice culture, it is most desirable that these two effects should not contend with each other. To determine the proper content of organic materials to be applied, the influences of varied amounts of a homogeneous mixture of dried green manure, ranging from 0 to 20g/pot (1/20,000 tanbo), upon hte growth of rice was investigated in a sand culture. Labeled phosphorus fertilizer was also used in the form of KH232PO4 to evaluate the availability of this nutrient in the soil. Under the present experimental conditions, green mature seems to have influenced little on the growth of rice, except on number of grains produced and grains/straw ratio. Moreover, no sympton of growth inhibition is obsrvable even by the largest amount of its application. The available phosphorus, as estimated by A-value, appears to have increased, as the amount of organic materials applied increases. In view of the fact that pure sand instead of a paddy soil is used in this culture, the present results would not be directly applicable to practical rice farming. Besides, the estimated A-value is in need of further study, since it varies according to method of application, as suggested by Nishigki et. al. (1958).

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Effects of Dissolved Inorganic and Organic Nutrient (Nitrogen and Phosphorus) on the Growth of Dinoflagellate Alexandrium affine (와편모조류 Alexandrium affine의 생장에 미치는 용존태 무기 및 유기 영양염(질소와 인)의 영향)

  • Oh, Seok Jin;Kim, Ji Hye;Park, Kyung Woo;Kim, Seok-Yun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.5
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    • pp.630-638
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    • 2021
  • In this study, we investigated the effects of dissolved inorganic and organic nutrient on the growth of dinoflagellate Alexandrium affine (LIMS-PS-2345). The maximum uptake rates (ρmax) and half saturation constants (Ks) calculated from the uptake kinetics experiment were 77.0 pmol/cell/hr, 17.6 μM for nitrate and 15.5 pmol/cell/hr, 3.88 μM for phosphate, respectively. These results suggested that this species has high inorganic nutrient demand and a low affinity for inorganic nutrients. During the utilization of organic nutrients for A. affine, growth rates of experimental groups added by organic nitrogen (urea and glycine) and phosphorus (adenosine triphosphate and glycerol phosphate) were above 70 %, compared to the experimental groups added by inorganic nutrients. Thus, A. affine may need to utilize organic nutrients to understand the dominant strategy and advantageous position in the interspecific competition within low inorganic nutrient environments.