• Title/Summary/Keyword: Organic membrane

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Pervaporation Separation of Binary Organic-Aqueous Liquid Mixtures

  • Rhim, Ji-Won;Huang, Robert Y.M.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.10a
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    • pp.1-3
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    • 1991
  • A novel membrane separation process for the separation of liquid mixture is Pervaporation. The term, 'pervaporation', is a combination of permeation and evaporation, and was first introduced by kober[1] in 1917. In this technique, the liquid mixture in feed is in contact with one side of a dense non-porous membrane and after diffusing through the membrane is removed from the downstream side in the vapor phase, but is usually condensed afterwards to obtain a permeate in liquid from.

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MEK SEPARATION FROM ITS AQUEOUS SOLUTION BY MEMBRANE CONTACTOR

  • Hyoseong Ahn;Yoonjin Oh;Lee, Yongtaek
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.17-20
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    • 2003
  • Separation of MEK(methylethylketone) was carried out experimentally by a flat membrane contactor using a variety of extracting organic compounds. A correlation equation of Sherwood number was determined in terms of Reynolds number and Schmidt number for the flat membrane contactor system. This correlation equation was applied to get theoretically the overall mass transfer coefficient of MEK: it was compared to the experimental one. It was found that they are in good agreement.

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Pervaporation of Ketone from Water Using Silicalite-1 Membrane (Silicalite-1 분리막을 이용한 수용액으로부터 케톤의 투과증발 분리)

  • 이용택;오윤진;안효성;이혜련
    • Membrane Journal
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    • v.13 no.4
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    • pp.229-238
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    • 2003
  • Pervaporation is mainly used to separate liquid mixtures because it exhibits a high selectivity compared with traditional distillation processes and it is known to be an energy saying separation process. Zeolite membranes show better thermal. mechanical, chemical stability than polymer membranes and especially silicalite-1 membrane can effectively separate organic compounds from water because of its high hydrophobicity. In this study, volatile organic compounds of ketone are separated by pervaporation using silicalite-1 membrane. As a feed concentration of acetone and MEK increases, a permeation flux of acetone and MEK increases while a selectivity decreases.

Determination of Optimal Coagulation Condition for Coagulation-UF Water Treatment Process (응집-UF 정수공정을 위한 칠적응집조건의 결정)

  • Lee, Chul-Woo;An, Su-Kyong;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.8
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    • pp.799-806
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    • 2005
  • Applying coagulation process before membrane filtration showed not only reducing membrane fouling, but also improving the removal of dissolved organic materials that might otherwise not be removed by the membrane alone. Also, slow mixing didn't affect the reduction of membrane fouling, and rapid mixing using an in-line static mixer was more effective than using backmixer. In addition, only 11 percent of dissolved organic matter in raw water was the primary cause of fouling. Furthermore, tile primary foulant of UF membrane was hydrophobic substance, which can easily be removed by coagulation.

Synthesis and Characterization of Sulfonated Poly(phthalazinone ether sulfone)(sPPES)/Silica Membrane for Proton Exchange Membrane Materials

  • Kim, Dae Sik;Park, Ho Bum;Nam, Sang Young;Rhim, Ji Won;Lee, Young Moo
    • Korean Membrane Journal
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    • v.6 no.1
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    • pp.44-54
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    • 2004
  • Organic-inorganic composite membranes based on sulfonated poly(phthalazinone ether sulfone) (sPPES)/silica hybrid were prepared using the sol-gel process under acidic conditions. The sulfonation of PPES with concentrated sulfuric acid as sulfonation agent was carried out to prepare proton exchange membrane material. The behaviors of the proton conductivity and methanol permeability are depended on the sulfonation time (5-100 hr). The hybrid membranes composed of highly sulfonated PPES (IEC value: 1.42 meq./g) and silica were fabricated from different silica content (5-20 wt%) in order to achieve desirable proton conductivity and methanol permeability demanded for fuel cell applications. The silica particles within membranes were used for the purpose of blocking excessive methanol cross-over and for forming the path way to transport of the proton due to absorbing water molecules with ≡SiOH on silica. The presence of silica particles in the organic polymer matrix results in hybrid membranes with reduced methanol permeability and improved proton conductivity.

A Study on the Pretreatment Process for Sewage Reuse by Microfiltration Process (정밀여과에 의한 하수고도처리수의 재이용을 위한 전처리법에 관한 연구)

  • Kuk, Young-Long;Joo, Jae-Young;Bae, Yoon-Sun;Lee, Hye-In;Jung, In-Ho;Park, Chul-Hwi
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.5
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    • pp.595-601
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    • 2010
  • It is evident that Korea will continue its battle with water shortage and alternative program are being taken into action. One of the main actions is reusing 1,800 tons of effluent of 357 sewage treatment plant located nationwide. Therefore this study supplemented ozone oxidation methods that would increase the efficiency of organic oxidation and coagulation. Through this method, fouling will be controled sufficiently by preventing membrane process in the system for advanced sewage treatment. In this study, ozone-coagulation-microfiltration membrane were used. The final removal efficiency of the pretreated water from the result of the ozone-coagulation were 50% of CODcr, 38% of TP and 11% of TOC respectively. Water quality treatment has decreased about 80% for TP. Ozone-coagulation-microfiltration membrane maintains the high flux while decreasing the number of organic matter and the membrane fouling, and reducing the TP. As a result, in order to reuse the water from the sewage, the ozone-coagulation-microfiltration membrane type must be considered in order to achieve the best efficiency.