• Architectural research
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• v.16 no.4
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• pp.175-183
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• 2014

Contemporary architecture tends to deconstruct modern architecture based on rationalization just like reductionism and functionalism and secedes from it. It means change from mechanical to organic and ecological view of the world. According to these changes, consideration of a compositive relationship presented variety and complexity in architecture. Thus, the modern speculation based on rationalism cannot provide an alternative interpretation about complicated architectural phenomena. At this point in time, the purpose of this study is to investigate the possibilities of the fractal as an alternative tool of analysis and design in contemporary architecture. In this study, two major aspects are discussed. First, the fractal concepts just like 'fractal dimension', 'box-counting dimension' and 'fractal rhythm' can be applied to analysis in architecture. Second, the fractal formative principles just like 'scaling', 'superimposition trace', 'distortion' and 'repetition' can be applied to design in architecture. Fractal geometry similar to nature's patterned order can provide endless possibilities for analysis and design in architecture. Therefore further study of fractal geometry should be conducted synthetically from now on.

• Korean Institute of Interior Design Journal
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• no.37
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• pp.12-20
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• 2003

The purpose of this study is to propose a new design principles and to analyze the pattern of art and architecture applying fractal concepts. As this study is based on fractal geometry as a natural science, 1 intented to explain the concepts and provide some methods of generating fractal properties. Two major aspects are discussed. Frist, fractals are geometric shapes that are self-similar, in other words, they iterate a basic shape at ever increasing a decreasing dimensions. Self-similarity, irregularity, and scaling are fundamental characteristics of fractal geometry. Second, the fractal concepts of art and design can be analyzed and used as a critical tool. In both criticism and design, fractals provides a tool In fine, fractal geometry can be provided endless possibilities for artists and designers intended in expressing the more complex underlying rhythms and organic patterns of nature.

• Korean Chemical Engineering Research
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• v.55 no.1
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• pp.130-134
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• 2017

Organic aerosols dispersed in the atmosphere likely undergo phase separation. Such internally mixed particles are often described as comprising an organic phase and an aqueous phase separately. We studied the morphology of two liquid separated aerosols in the sub-microscale by using a simple thermodynamic model with Russian doll geometry. The morphology of particles can be easily predicted from the simple criteria on the surface tension and two algebraic equations (the volume constraint and Young equation). This result may give the potential explanation about the complex morphology of the organic airborne particles.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.6
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• pp.558-562
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• 2006

We have synthesized a new p-type polymer, poly(9,9'-n-dioctylfluorene-alt-phenoxazine) (PFPO), via the palladium catalyzed coupling reaction. The number average molecular weight ($M_n$) of PFPO was found to be 23,000. PFPO dissolves in common organic solvents such as chloroform and toluene. The UV-visible absorption maximum of the PFPO thin film is clearly blue-shifted with respect to that of F8T2, poly-(9,9'-n-dioctylfluorene-alt-bithiophene). The introduction of the phenoxazine moiety into the polymer system results in better field-effect transistor (FET) performance than that of F8T2. A solution processed PFPO TFT device with a top contact geometry was found to exhibit a hole mobility of $2.7{\times}10^{-4}cm^2/Vs$ and a low threshold voltage of -2 V with high on/off ratio(${\sim}10^4$).

• Proceedings of the Korean Vacuum Society Conference
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• 2005.02a
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• pp.53-53
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• 2005

• Korean Institute of Interior Design Journal
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• v.15 no.4 s.57
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• pp.115-122
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• 2006

The purpose of this study is to investigate the design principles of organic integration on furniture design by Frank Lloyd Wright. He consistently pursued organic principles in interior design, furniture and equipments. He insisted that every elements of a building can be integrated into architecture as if architecture can be a part of the nature. The study surveyed and analyzed the examples of furniture design in Wright houses from the viewpoints of spacial and formal integration as well as organic evolution. The study finds the characteristics of organic integration on furniture design as follows. He designed built-in furniture as an important part of the house, which seemed to grow up from the architecture design and a part of a building. He also designed and arranged free-standing furniture as spacial device in open floor plan. Moreover, furniture design repeated same geometry, modules, and proportion system of house design in order to integrate Into the building. In addition, material and color of furniture follow those of architecture. Wright's furniture design had changed from heavy forms in his early prairie houses to light and practical shapes in his Usonian period.

• Korean Institute of Interior Design Journal
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• v.19 no.2
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• pp.90-98
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• 2010

The concepts of laws like regularity or persistence or recurrence those are discovered in nature, became the essential elements in speculative philosophy, study and scientific technology. Western civilization was spread out by these natural laws. As this background, this study is aimed to research the theories of natural laws and the development of geometry as the descriptive tools and the development aspects of the concepts of space. According to Whitehead's four theories on the natural laws, the result of this study that aimed like that as follows. First, the theories on the immanence and imposition of the natural laws were the predominant ideas from ancient Greek to before the scientific revolution, the theory on the simple description like the positivism made the Newton-Cartesian mechanism and an absolutist world view. The theory on the conventional interpretation made the organicism and relativism world view according to non-Euclidean geometry. Second, the geometrical composition of ancient Greek architecture was an aesthetics that represented the immanence of natural laws. Third, in the basic symbol of medieval times, the numeral symbol was the frame of thought and was an important principal of architecture. Fourth, during the Renaissance, architecture was regarded as mathematics that made the order of universe to visible things and the geometry was regarded as an important architectural principal. Fifth, according to the non-Euclidean geometry, it was possible to present the natural phenomena and the universe. Sixth, topology made to lapse the division of traditional floor, wall and ceiling in contemporary architecture and made to build the continuous space. Seventy, the new nature was explained by fractal concepts not by Euclidean shapes, fractal presented that the essence of nature had not mechanical and linear characteristic but organic and non-linear characteristic.

• Applied Chemistry for Engineering
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• v.34 no.6
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• pp.633-639
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• 2023

We synthesized 2-(10-methyl-10H-phenothiazin-3-yl)-5-phenyl-1,3,4-oxadiazole (MPPO) and 5,5-(10-methyl-10H-phenothiazin-3,7-diyl)-bis-(2-phenyl-1,3,4-oxadiazole) (DPPO). MPPO has both electron-donating and electron-accepting substituents with asymmetric molecular geometry. By incorporating one extra electron-accepting group into MPPO, we created a symmetric molecule, which is DPPO. The optical and electrochemical properties of these compounds were measured. The lowest unoccupied molecular orbital (LUMO) level of DPPO was lower than that of MPPO. The excited-state dipole moment of DPPO, with symmetric geometry, was calculated to be 4.1 Debye, whereas MPPO, with asymmetric geometry, had a value of 7.0 Debye. The charge-carrier mobility of both compounds was similar. We fabricated non-doped organic light-emitting diodes (OLEDs) using D-A type molecules as an emitting layer. The current efficiency of the DPPO-based device was 7.8 cd/A, and the external quantum efficiency was 2.4% at 100 cd/m², demonstrating significantly improved performance compared to the MPPO-based device. The photophysical and electroluminescence (EL) characteristics of the two D-A type molecules showed that molecular symmetry, as well as the lowered LUMO level of DPPO, played critical roles in the enhancement of EL performance.

• Journal of the Korean Applied Science and Technology
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• v.15 no.3
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• pp.61-66
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• 1998

Cyclodextrin are obtained from starch by enzymatic degradation. The three best characterize forms are ${\alpha}$, ${\beta}$, ${\gamma}$ cyclodextrin consisting of 6, 7, and 8 D-glucose units, respectively. Each of the glucose units are in the rigid C1 chair conformation and are linked by ${\alpha}$ 1,4 bonds. This geometry gives the cyclodextrin the shape of a hollow truncated cone with the wider side formed by the secondary 2- and 3-hydroxy groups and the narrower side by the primary 6-hydroxy group. The most characteristics property of the cyclodextrin is their ability to form inclusion complexes with a wide range of guest moleculars. We syntheses per-6-substituted ${\beta}$-cyclodextrin derivatives and investigate structures, spectrospcopic properties. The substituted materials are piperidine, piperazin, morphorine. The synthetic compound showed a good solubility than natural ${\beta}$ cyclodextrin in organic solvents such as methylene chloride, methanol, ethanol, etc.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.4
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• pp.373-378
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• 2006

We report on plasma damage free-sputtering technologies for organic light emitting diodes (OLEDs), organic thin film transistor (OTFT) and flexible displays by using a box cathode sputtering (BCS) method. Specially designed BCS system has two facing targets generating high magnetic fields ideally entering and leaving the targets, perpendicularly. This target geometry allows the formation of high-density plasma between targets and enables us to realize plasma damage free sputtering on organic layer without protection layer against plasma. The OLED with Al cathode prepared by BCS shows electrical and optical characteristics comparable to OLED with thermally evaporated Mg-Ag cathode. It was found that OLED with Al cathode layer prepared by BCS has much lower leakage current density ($1{\times}10^{-5}\;mA/cm^2$ at -6 V) than that $(1{\times}10^{-2}{\sim}-10^0\;mA/cm^2)$ of OLED prepared by conventional DC sputtering system. This indicates that BCS technique is a promising electrode deposition method for substituting conventional thermal evaporation and DC/RF sputtering in fabrication process of organic based optoelectronics.