• 한국정밀공학회지
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• 제30권6호
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• pp.589-595
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• 2013

Solution processed conjugated molecules enable to manufacture various electronic devices by unconventional and cost effective patterning methods as screen or gravure printing. Spin-coating is the most popularly used method to form conjugated polymeric film for various electronic devices. The coating method has certain disadvantages such as a large amount of unwanted wastes, difficulty forming a film with a large area, and impossible to apply roll-to-roll manufacturing. We present here a promising alternative coating method, bar-coating for conjugated polymer film and OLED with the bar coated light emitting layer. In this papers, we show atomic force microscope images of spin- and bar-coated Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)] (F8BT) films on substrate. The bar-coated film showed a slight lower RMS roughness (1.058 [nm]) than spin-coated film (1.767 [nm]). It means the bar-coating is suitable method to form light emitting layers in OLEDs. By using bar-coating process, an OLED obtained with 4.7 [cd/A] in maximum current efficiency.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 하계학술대회 논문집 C
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• pp.1527-1529
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• 2001

The physicochemical properties of the LB films were by AFM. We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 2, 10, 30[mN/m]. The stable images are probably due to a s interaction between the monolayer film and substrate. We are unable to obtain molecule res in images of the films but did see a marked co between images of the bare substrate and those the network structure film deposited ont Formation that prevent when gas phase stat liquid phase state measure but Could know o matter that molecules form equal and stable when molecules were not distributed evenly, accumulated in solid state only.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2012년도 춘계학술발표대회
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• pp.67.1-67.1
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• 2012

Graphene has attracted much attention for future nanoelectronics due to its superior electrical properties. Owing to its extremely high carrier mobility and controllable carrier density, graphene is a promising material for practical applications, particularly as a channel layer of high-speed FET. Furthermore, the planar form of graphene is compatible with the conventional top-down CMOS fabrication processes and large-scale synthesis by chemical vapor deposition (CVD) process is also feasible. Despite these promising characteristics of graphene, much work must still be done in order to successfully develop graphene FET. One of the key issues is the process technique for gate dielectric formation because the channel mobility of graphene FET is drastically affected by the gate dielectric interface quality. Formation of high quality gate dielectric on graphene is still a challenging. Dirac voltage, the charge neutral point of the device, also strongly depends on gate dielectrics. Another performance killer in graphene FET is source/drain contact resistance, as the contact resistant between metal and graphene S/D is usually one order of magnitude higher than that between metal and silicon S/D. In this presentation, the key issues on graphene-based FET, including organic-inorganic hybrid gate dielectric formation, controlling of Dirac voltage, reduction of source/drain contact resistance, device structure optimization, graphene gate electrode for improvement of gate dielectric reliability, and CVD graphene transfer process issues are addressed.

• 동력기계공학회지
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• 제18권6호
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• pp.133-139
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• 2014

In this research, the photocatalytic degradation of benzothiophene in $TiO_2$ aqueous suspension has been studied. $TiO_2$ photocatalysts are prepared by a sol-gel method. The dominant anatase-structure on $TiO_2$ particles is observed after calcining the $TiO_2$ gel at $500^{\circ}C$ for 1hr. Photocatalysts with various transition metals (Nd, Pd and Pt) loading are tested to evaluate the effect of transition metal impurities on photodegradation. The photocatalytic degradation in most cases follows first-order kinetics. The maximum photodegradation efficiency is obtained with $TiO_2$ dosage of 0.4g/L. The photodegradation efficiency with Pt-$TiO_2$ is higher than pure $TiO_2$ powder. The optimal content value of Pt is 0.5wt.%. Also we investigate the applicability of $H_2O_2$ to increase the efficiency of the $TiO_2$ photocatalytic degradation of benzothiophene. The optimal concentration of $H_2O_2$ is 0.05. The effect of pH is investigated; we obtain the maximum photodegradation efficiency at pH 9. Hydroxy-benzothiophenes and dihydroxy-benzothiophenes are identified as reaction intermediates. It is proposed that benzothiophene is oxidized by OH radical to sequentially form hydroxyl-benzothiophenes, dihydroxybenzothiophenes, and benzothiophenedione.

• 한국표면공학회지
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• 제27권5호
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• pp.292-302
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• 1994

Alloy deposits of 80Sn-20Pb, electroplated on Cu-based leadframe alloy from an organic sulfonate bath were aged at $150^{\circ}C$ to form intermetallic phases between substrate and deposit, and effects of the deposit morphology, influenced by deposition conditions, on the fracture resistance of the 80Sn-20Pb deposit aged at $150^{\circ}C$ were examined. The growth rate of intermetallic compound layer on aging depended on the microstructure of deposit ; it was fastest in deposit formed using pulse current in bath without grain refining additive, but slowest in deposit formed using dc current in bath containing grain refining additive in spite of similar structure with equivalent grain size. The grain refining additive incorporated in electrodeposit appears to inhibit diffusion of atoms on aging, resulting in slow growth of intermetallic layer in the thickness direction but substantial growth in the lateral one. Density of surface cracks that were occurring when samples were subjected to the $90^{\circ}$-bending test increased with increasing the thickness of intermatallic layer on aging. For the same aged samples, the surface crack density of the sample electrodeposited from a bath containing the grain refining additive was the least due to the inhibiting effect of the additive incorporated into the deposit during electrolysis on atomic diffusion.

• 설비공학논문집
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• 제25권8호
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• pp.432-437
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• 2013

The increase of greenhouse gas emission and decrease of fossil fuel are being caused by the indiscreet consumption of energy by people. Recently, green policy has been globally implemented to reduce energy consumption. This paper studied the research to reduce the energy consumption in buildings, by using the heat storage properties of PCM. PCM has to prevent leakage from the liquid state. Therefore, we prepared form stable PCM, by using the vacuum impregnation method. Three kinds of organic PCMs were impregnated into the structure of porous material. The characteristics of the composites were determined by using SEM, DSC, FTIR and TGA. SEM morphology showed the micro structure of silica fume/PCM. Also, thermal properties were examined by DSC and TGA analyses; and the chemical bonding of the composite was determined by FTIR analysis.

• Archives of Pharmacal Research
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• 제26권12호
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• pp.1047-1054
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• 2003

Molecular chaperones have a crucial role in the folding of nascent polypeptides in endoplasmic reticulum. Some of them are known to be sensitive to the modification by electrophilic metabolites of organic pro-toxicants. In order to identify chaperone proteins sensitive to alkyators, ER extract was subjected to alkylation by 4-acetamido-4 -maleimidyl-stilbene-2,2 -disulfonate (AMS), and subsequent SDS-PAGE analyses. Protein spots, with molecular mass of 160, 100, 57 and 36 kDa, were found to be sensitive to AMS alkylation, and one abundant chaperon protein was identified to be protein disulfide isomerase (PDI) in comparison with the purified PDI. To see the reactivity of PDI with cysteine alkylators, the reduced form ($PDI_{red}$) of PDI was incubated with various alkylators containing Michael acceptor structure for 30 min at $38^{\circ}C$ at pH 6.3, and the remaining activity was determined by the insulin reduction assay. Iodoacetamide or N-ethylmaleimide at 0.1 mM remarkably inactivated $PDI_{red}$ with N-ethylmaleimide being more potent than iodoacetamide. A partial inactivation of $PDI_{oxid}$ was expressed by iodoacetamide, but not N-ethylmaleimide (NEM) at pH 6.3. Of Michael acceptor compounds tested, 1,4-benzoquinone ($IC_{50}, 15 \mu$ M) was the most potent, followed by 4-hydroxy-2-nonenal and 1,4-naphthoquinone. In contrast, 1,2-naphthoquinone, devoid of a remarkable inactivation action, was effective to cause the oxidative conversion of $PDI_{red}$ to $PDI_{oxid}$. Thus, the action of Michael acceptor compounds differed greatly depending on their structure. Based on these, it is proposed that POI, one of chaperone proteins in ER, could be susceptible to endogenous or xenobiotic Michael acceptor compounds in vivo system.

• 한국자원식물학회지
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• 제33권1호
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• pp.1-14
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• 2020

경상북도 울진군에 위치한 천축산 일대 금강소나무림을 중심으로 한 군집구조와 종조성에 대한 분석을 실시하였다. 그 결과 조사지 내 관속식물상은 총 66과 165속 211종 2아종 29변종 6품종으로 248분류군으로 조사되었으며 금강소나무림을 중심으로 신갈나무 군집, 굴참나무 군집, 갈참나무-국수나무 군집으로 3가지 군집으로 분류되었다. 군집 간 토양의 이화학적 성질의 차이는 유기물층 깊이, 연년생장량, 해발고도, 양이온치환용량, 전질소, pH 등의 유의한 차이가 나타났다. 하층식생을 중심으로 한 DCA 분석 결과 P-1, P-2의 조사구가 광범위한 환경에 분포하는 것에 반해 P-3 군집은 두 군집과 비교하여 이질적인 종조성인 것으로 분석되었다. 종다양도와 지표종 분석결과 P-3군집에서 목본층과 하층식생의 종풍부도 및 종다양도 지수가 높은 것으로 분석되었는데, 이는 숲틈에 의한 임내 광량이 다량 유입되어 선구종(pioneer species) 및 여러 식물종이 생육하기 용이한 공간을 마련한 결과로 나타났다(Schnitzer and Carson, 2001). 이에 따른 만경류와 같은 수관열림에 의한 수종 유입에 따른 금강소나무의 피해를 방지하기 위한 장기적인 모니터링을 실시하여 임내 환경과 하층식생의 변화상을 관찰하여야 한다. 특정지역에 대한 생태적 데이터베이스의 구축은 생태계 보전을 위한 기초자료로 활용되며 이는 곧 서식처로 삼고있는 동물들의 보전으로 이어져 생물다양성과 종간 상호작용이 원활하게 이루어져 건전한 생태계를 유지한다. 이를 위한 효율적인 보전방안의 하나는 GIS (Geographic Information System) 데이터를구축하는 것으로 대면적 생태경관보전지역의 경우 공간적 범위가 넓어 인간이 수동적으로 인지하기에 한계가 있기 때문에 효과적인 관리 방법이 될 것이다. 또한 연구대상지 내 수집한 데이터를 정량화 시키고 유기적인 경관보전을 위해 장기적인 모니터링이 요구되며, 이는 왕피천 유역의 시계열적인 생태계를 이해하는 방법이다.

• 디자인학연구
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• 제13권1호
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• pp.111-120
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• 2000

시각예술은 어떤 형식이든지 일정한 공간속에서 이루어지며 작품을 이루는 여러 시각 요소들로 구성되어 있다. 효과적인 커뮤니케이션을 위해서 시각요소들은 서로 유기적인 관계를 맺는 하나의 안정된 구조를 가져야 하는데 여기에는 인간의 시각적인 특성과 심리적인 이해가 필요하다. 왜냐하면 인간의 시각은 생리적, 심리적으로 같은 시각요소에 대해서도 공간속의 위치에 따라 각기 다른 힘과 무게를 느끼기 때문이다. 이러한 힘과 무게를 조절하는 구도는 작품안에 숨겨져 있지만 수평과 수직에 대한 인간의 심리적인 반응을 통해 커뮤니케이션에 실제적인 힘을 발휘하는 작품의 내적 설계이며, 또한 이를 통해 주제와 메시지를 효과적으로 드러나게 하는 시각적 진술방식이기도 하다. 본 논문은 이러한 시각적인 화면, 그 이면에 존재해 있는 힘의 구조로 인한 화면의 특성, 시각적 균형의 원리 등을 미술작품의 분석을 통해 시각적 구조에 관한 연구이다. 그것을 바탕으로 시각적인 이미지작업을 하는 디자이너들이 시각적인 구조와 심리적 인식을 이해하여 구성요소안에 심리적인 힘을 깨달아 화면구성에 실제 응용할 수 있는 바탕을 마련하는데 그 목적이 있다.

• 전기화학회지
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• 제22권4호
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• pp.139-147
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• 2019

고에너지밀도 대용량 리튬이온전지를 채용한 전기자동차 및 에너지저장시스템에서 발생하고 있는 발화사고로 인해, 고안전성 전고체 리튬이차전지(All-solid-state Lithium Secondary Battery, ALSB)에 대한 연구가 국내외에서 활발히 진행되고 있다. 하지만, 단순히 액체전해질을 고체전해질로만 바꾸는 것이 아니라, 이로 인해 수반되는 전극 및 전지 설계와 해석이 크게 달라진다는 점에서 해결해야 될 이슈들이 산재해 있다. 특히, 전지는 전극 설계에 따라 그 성능이 굉장히 상이함에도 불구하고, 실질적인 전고체 전지 실험 구현의 어려움으로 전고체 전극(All-solid-state Electrode, ASSE) 설계에 따른 성능 차이를 체계적으로 비교 분석하여 최적화하는 연구는 매우 제한적이다. 이를 극복하기 위한 방안으로, 가상의 3차원 전고체 전극 구조체를 형성하고, 형성된 구조체를 바탕으로 다양한 성능 결정 파라미터를 도출하며, 더불어 분석 전극을 포함한 전지의 성능까지 예측할 수 있는 기술을 개발하는 연구가 주목을 받기 시작했다. 본 총설에서는 3차원 전고체 전극 구조체 형성부터 전고체 리튬이차전지의 성능을 예측하는 기술까지 각각의 기술들이 갖고 있는 장단점을 폭넓게 다룰 것이며, 나아가 본 기술이 나아갈 최종적인 목표까지 간략히 기술하고자 한다.