• Title/Summary/Keyword: Organic electroluminescence

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Molecular Design of New Organic Electroluminescence Materials: DCM Derivatives

  • Seong, See-Yearl;Park, Sung-Soo;Seo, Jeong-In;No, Kyoung-Tai;Hong, Jong-In;Park, Su-Jin;Choi, Seung-Hoon;Lee, Han-Yong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.178-180
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    • 2003
  • We performed semiempirical (AMl and ZINDO) and ab initio (HF and DFT) calculations, to investigate molecular structures and optical properties of DCM and its derivatives. DCM and its derivatives are used as a red fluorescent dopant of the organic electroluminescent host materials, $Alq_3$. We have studied the relationship between the molecular structure and the optical properties of these molecules for the improvement of EL efficiencies. Wavelength at the absorption maximum was found to be red-shifted when the molecule is substituted with both strong electron donating and withdrawing functional groups. A new red fluorescent dye was predicted by QSPR study based on calculations and experimental data.

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Effects of Electron Transport Layers on Electrical and Optical Characteristics of Blue Phosphorescent Organic Light Emitting Diodes (전자수송층이 청색 인광 OLED의 전기 및 광학적 특성에 미치는 영향)

  • Suh, Won-Gyu;Moon, Dae-Gyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.4
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    • pp.323-326
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    • 2009
  • We have developed blue-emitting phosphorescent organic light emitting diodes (OLEDs) using 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) and tris (8-quinolinolato)aluminum ($Alq_3$) electron transport layers. As blue dopant and host materials, bis[(4,6-di-fluorophenyl)-pyridinate-N,C2']picolinate (FIrpic) and N,N'-dicarbazolyl-3,5-benzene (mCP) were used, respectively. The driving voltage, current efficiency and emission characteristics of devices were investigated. While the driving voltage was about $1{\sim}2$ V lower in the device with an $Alq_3$ layer, the current efficiency was about 66 % higher in the device with BCP electron transport layer. the blue phosphorescent OLED with BCP layer exhibited higher purity of color, resulting from a relatively weak electroluminescence intensity at 500 nm.

Characteristics of matrix OEL devices that fabricated by side-by-side methode (side by side 방법으로 제작한 matrix 유기 발광 소자의 발광특성)

  • Son, Chul-Ho;Yeo, Cheol-Ho;Shin, Kyung;Lee, Young-Jong;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.366-369
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    • 2001
  • In this study, the matrix Organic Electroluminescence (OEL) device, that was consisted of R,G,B pixels. We fabricated OEL devices by side by side methode and, used organic material Alq3 as green, DCM as red and Butyl PBD as blue ETL. We investigated the characteristic of brightness and current density for matrix OEL device. As the results, each color devices has minimum about $100cd/m^{2}$ brightness and maximum luminescence was $2500cd/m^2$ in green OEL device.

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Temporal Response of the Organic Electroluminescent Device with a Vacuum-Deposited Poly(p-phenylene) Thin Film

  • Kang, G.W.;Lee, C.H.;Song, W.J.;Seoul, C.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.207-208
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    • 2000
  • The temporal response of the electroluminescence (EL) has been studied in the organic electroluminescent devices fabricated with a vacuum-deposited poly(p-phenylene) (PPP) thin film upon the application of a rectangular driving voltage. The blue EL emission arises with a delay time of several hundred nanoseconds and then saturates with the rise time of less than microsecond. The EL delay time is considered as the transit time of holes in the PPP thin film since the hole mobility is much larger than the electron mobility in PPP. The hole mobility is estimated to be ${\sim}$ $1{\times}10^{-5}$ $cm^2/Vs$ in the vacuum-deposited PPP film.

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Electroluminescence properties of white organic light-emitting devices fabricated utilizing a $CaAl_{12}O_{19}:Mn^{4+}$ phosphor layer acting as a color conversion layer

  • Ahn, S.D.;Choo, D.C.;Kim, T.W.;Lee, J.Y.;Park, J.H.;Kwon, M.S.;Chu, C.;Ha, J.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.697-699
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    • 2009
  • Optical properties of white organic light-emitting devices (WOLEDs) fabricated utilizing a phosphor layer acting as a color conversion layer were investigated. The WOLEDs were achieved due to the enhancement in the color conversion efficiency of the phosphor layer, and the chromaticity coordinates of WOLEDs were (0.29, 0.33).

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Characteristics of matrix OEL devices that fabricated by side-by-side methode (side by side 방법으로 제작한 matrix 유기 발광 소자의 발광특성)

  • Son, Chul-Ho;Yeo, Cheol-Ho;Shin, Kyung;Lee, Young-Jong;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.366-369
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    • 2001
  • In this study, the matrix Organic Electroluminescence (OEL) device, that was consisted of R,G,B pixels. We fabricated OEL devices by side by side methode and, used organic material Alq3 as green, DCM as red and Butyl PBD as blue ETL. We investigated the characteristic of brightness and current density for matrix OEL device. As the results, each color devices has minimum about 100 cd/㎡ brightness and maximum luminescence was 2500cd/㎡ in green OEL device

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Fabrication and Properties of OLEDs using PECCP Langmuir-Blodgett(LB) Films (PECCP LB 박막을 이용한 유기 발광 타이모드의 제작과 이의 특성)

  • Lee, Ho-Sik;Lee, Won-Jae;Park, Myung-Gyu;Songe, Min-Jeng;Park, Jong-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.831-834
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    • 2000
  • Characteristics of organic light-emitting diodes(OLEDs) were studied with devices made by PECCP[poly(3,6-N-2-ethylhexyl carbazolyl cyanoterephthalidene)] Langmuir-Blodget(LB) films. The emissive organic material was synthesized and named PECCP, which has a strong electron donor group and an electron accepter group in main chain repeated unit. The LB technique was employed to investigate the identification of the recombination zone in the ITO/PECCP LB films/Alq$_3$/Al structure by varying the LB film thickness. PECCP was considered as an emissive layer and Alq$_3$was used as an electron-transport layer. We measured current-voltage(I-V) characteristics, UV/visible absorption, PL spectrum, and EL spectrum of those devises.

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Red Electrophosphorescent Organic Light-emitting Diodes Based on New Iridium Complexes. (새로운 이리듐 화합물을 이용한 적색 인광 유기 발광 다이오드)

  • Gong, Doo-Won;Kim, Jun-Ho;Lee, Kum-Hee;Yoon, Seung-Soo;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.73-74
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    • 2006
  • New iridium complexes that have carbonyl group were synthesized and demonstrated various red light emission in organic light-emitting diodes (OLEDs). The maximum luminance of $57000{\sim}15300\;cd/m^2$ at 15 V and the luminance efficiency of 22.8~5.6 cd/A at $20\;mA/cm^2$ were achieved respectively. The peak wavelength of the electroluminescence were at 570~604 nm and the device also showed a stable color chromaticity with various voltages.

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Synthesis of Hole Transport Materials for Organic Light Emitting Device (유기발광디바이스용 정공수송재료의 합성)

  • Chung, Pyung-Jin;Cho, Min-Ju
    • Korean Journal of Materials Research
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    • v.15 no.7
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    • pp.448-452
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    • 2005
  • This study was based on organic electroluminescence display. Especially, TPD and $\alpha-NPD$ for the hole transport materials were synthesized by Ullmann reaction. This reaction was conducted between 3­methylphenylamine, 1-naphthylamine and 4,4'-diiodobiphenyl in toluene containing CuCl catalyst and KOH base. The structural property of reaction products were analyzed by FT-IR, $^1H-NMR$ spectroscopy, and thermal stability, reactivity and PL property were analyzed by melting point, yield and emission spectrum, respectively. The photoluminescence spectra of a pure TPD and $\alpha-NPD$ were observed at approximately 416nm and 438nm respectively. In this study, it was known that the melting point, yield, PL properties of TPD and $\alpha-NPD$ were changed by substituent group of amines.

Electroluminescent Properties of BECCP/Alq3 Organic Light-emitting Diode (BECCP/Alq3 이중층을 이용한 전기 발광 소자의 특성 연구)

  • Lee, Ho-Sik;Yang, Ki-Sung;Shin, Hoon-Kyu;Park, Jong-Wook;Kim, Tae-Wan;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1050-1053
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    • 2004
  • Many organic materials have been synthesized and extended efforts have been made to obtain high performance electroluminescence(EL) devices, since the first report of the light-emitting diodes based on Alq3. BECCP[bis(3-N-ethylcarbazolyl)cyanoterephthalidene] is a new luminescent material having cyano as an electron acceptor part and carbazole moiety as an electron donor part. The BECCP material shows blue PL and EL spectra of the device at about 480nm and in the ITO/BECCP/Al device shows typical rectifying diode characteristics. We have introduced Alq3 between the electrode and BECCP, and obtained more intensive rectifying diode characteristics in forward and reverse bias.

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