• Title/Summary/Keyword: Organic complex

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The Study of PM2.5 and Exhaust Emission Characteristics in the Motorcycles according to Various Lubricants (윤활유 종류에 따른 이륜자동차 PM2.5 및 배출가스 특성 연구)

  • Lim, Yunsung;Lee, Jongtae;Park, Jangmin;Kim, Jeongsoo;Lee, Janghoon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.4
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    • pp.70-76
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    • 2013
  • Because increased food delivery service and quick delivery service using motorcycle, registration numbers of motorcycles were sharply increased and it could contribute on worsening air quality. In this study, two models(50cc, 125cc) of motorcycle were tested by using three types of engine oil. Two motorcycles were tested with CVS-40 mode for emission characteristics such as CO, THC, NOx, Elemental Carbon(EC), Organic Carbon(OC), sulfate, soot and SOF(soluble organic fraction). Result of according to three types of lubricants which included phosphorus, sulfate ash impacted to particle matters so "C" lubricants is more higher PM than "A", "B" lubricants in this research.

Concentration level of Volitile Organic Compounds about the Air of Source Boundary Site in Seongseo Industrial Complex (대구성서산업단지 발생원부지경계 대기 중 휘발성유기화합물질의 농도수준)

  • An Sang-Young;Choi Sung-Woo
    • Journal of Environmental Science International
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    • v.14 no.1
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    • pp.53-60
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    • 2005
  • The concentrations of volatile organic compounds(VOCs) in the ambient air were measured at various point(Source, source boundary) in Seongseo industrial complex during May to November 2003. Air samples were collected in Silcocan canister $(1{\ell},\;6{\ell})$ and analyzed using a cryogenic preconcentration system and GC/MSD. We identified 37 species by the US EPA(TO-14 method). The result showed a variety distribution of the con­centration, Higher concentrations of BTX, Styrene, 1,3,5-Trimethylbenzene, 1,2,4-Trimethylbenzene were observed at the sampling sites. They seemed to be emitted from the facility of wastewater treatment, reaction tank of chemistry factory and facility of Tenter. The concentrations of VOCs contents in Seongseo industrial complex were generally higher than those in Yeosu complex and Ulsan complex, although those were similar in Sihwa­Banwol complex.

Lithium Complex as a New Electron Injection Layer in Organic Light Emitting Devices

  • Lee, Min-Woo;Lee, Jae-Goo;Kim, Sung-Min;Kim, Bong-Ok;Kwak, Mi-Young;Choi, Kyung-Hoon;Lim, Hyo-Jung;Si, Sang-Man;Sohn, Byung-Chun;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.959-962
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    • 2003
  • This study is the effect of lithium Lithium Complex as an electron injection layer(EIL) on the performance of organic light emitting devices (OLEDs) and optimized the device efficiency by varying thickness of EIL layer. The device with 2nm GDI 101 layer showed significant enhancement of the device performance and device lifetime. We also compared GDI 109 and GDI 117 with GDI 101 as an electron injection layer.

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Fabrication of Organic Nanowire Electronics by Direct Printing Method

  • Park, Gyeong-Seon;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.563-563
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    • 2012
  • We report a one-step fabrication of single-crystal organic nanowire arrays on substrates using a new direct printing method (liquid-bridge-mediated nanotransfer moulding, LB-nTM), which can simultaneously enable the synthesis, alignment and patterning of the nanowires using molecular ink solutions. Two- or three-dimensional complex structures of various single-crystal organic nanowires were directly fabricated over a large area with a successive process. The position of the nanowires can be aligned easily on complex structures because the mold is movable on substrates before drying the polar liquid layer, which acts as an adhesive lubricant. This efficient manufacturing method can produce a wide range of optoelectronic devices and integrated circuits with single-crystal organic nanowires.

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Preparation of Silver Nanocolloids Using Silver Alkylcarbamate Complex in Organic Medium with PVP Stabilizer

  • Park, Hyung-Seok;Park, Heon-Su;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2575-2580
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    • 2010
  • We present a method for chemically reducing silver alkylcarbamate complex with hydrazine to synthesize silver nanocolloids in an organic solvent using polyvinylpyrrolidone (PVP) as the stabilizer. To determine the optimal conditions for preparing stable silver colloids of controlled size and shape, the silver 2-ethylhexylcarbamate (Ag-EHCB) complex, PVP, hydrazine, and 2-propanol solvent concentrations in the reaction mixture were varied. The initial colloid has a mean particle diameter of 5-80 nm, and it exhibits an absorption band with various shapes in the UV region with a maximum near 420 nm. UV-vis spectroscopy, TEM, and X-ray diffraction techniques were used to investigate the formation and growth process of the metallic silver nanocolloids.

Formation of the Polycaprolactam between Layers of the [DEACOOH]-Montmorillonite Intercalations Complex and Its Characterization

  • Cho, Sung-Jun
    • Journal of the Korean Ceramic Society
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    • v.43 no.4 s.287
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    • pp.207-212
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    • 2006
  • [ ${\varepsilon}-caprolactam$ ] was polymerized in the layers of the [DEACOOH]-Montmorillonite intercalations complex at high temperatures ranging from 250% to 260% formed from Na-Montmorillonite and 10-Carboxy-n-decyldimethylethylammonium bromide to achieve [DEACOOH]-Polycaprolactam-Montmorillonite, in which an inorganic polymer (montmorillonite) is chemically combined with an organic polymer (polycaprolactam). The results of X-ray and IR analyses for the samples obtained after polymerization showed that the polymerization reaction was successfully accomplished. For the purpose of studying the polymeric reaction product more precisely, the polymerized product was separated from the silicate layers and analyzed with an X-ray diffractometer and an IR-spectrometer. A comparison of the results of the X-ray and IR analyses of the separated polymer and the polymer that was synthesized by the reaction of ${\varepsilon}-caprolactam$ solely with the organic cation without montmorillonite showed that the obtained both polymers are identical compounds.

Effect of Ancillary Ligand, Phenyl group, on the Emission Spectrum of Pt(II) Complex Useful for Organic Light-Emitting Device (유기전기발광소자에 사용될 수 있는 백금 착물에 대해 보조리간드 phenyl 기가 발광스펙트럼에 미치는 영향)

  • Lee, Seung-Hee;Lee, Ho-Joon
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.2
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    • pp.265-268
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    • 2008
  • Among the efforts to increase the efficiency of organic light-emitting device (OLED), there is a way: doping phosphorescent materials. As a phosphorescent material, complexes of heavy transition metal, platinum, were synthesized. $Cl^-$ ion and phenyl group were used as ancillary ligands with 2-(2-pyridyl)benzimidazole (pbi) as a chromophore. The complexes were analysed by FAB-mass spectrometer and absorption and emission spectra were obtained. A phenyl group was able to shift the emission band of the complex even if it's not a chromorphore.

Optical Properties of Yb(SOL-D)$_3$ Complex for Laser Material (신 레이저매질 Yb(SOL-D)$_3$착물의 광학적 특성)

  • 김정호;서연호;박용필
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.640-643
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    • 2001
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(SOL-D)$_3$] complexes were synthesized by the keto-enol tautomerism reaction of Yb(SOL-H)$_3$in methanol-d$_4$in order to reduce the radiationless transition to the ligands. The luminescence properties of Yb(SOL-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$_{8}$, PO(O$CH_3$)$_3$and DMSO-d$_{6}$. The intensity, lifetime and quantum efficiency of the luminescence in DMSO-d$_{6}$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$_{6}$ might be the most appropriate solvent for the liquid laser material of Yb(SOL-D)$_3$complex.complex.

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Electrical Characteristics of Organic Light Emitting Diodes (OLED) using the Alkali Metal Complex as New Electron Injection Layers (알칼리 금속 전자 주입층을 사용한 유기 전기 발광 소자 (OLED)의 전기적 특성)

  • Lee, Hyun-Koo;Kim, Jun-Ho;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1015-1018
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    • 2004
  • We investigate the influence of the New Electron Injection Layers (EIL) on the performance of the Alkali Metal Complex vapor-deposited Organic Light Emitting Diodes(OLED). Two different Alkali Metal Complex were used; Lithium Quinolate (Liq), and Sodium Quinolate (Naq). In all cases, $Alq_3$ was the Electron Transporting Layer (ETL). We measure and compare the current density-voltage (J-V) and luminance-voltage (L-V) characteristics. We concluded that the turn-on voltage, and luminance efficiency are controlled by the type of EIL material used. We show the longer life-time OLED with Alkali Metal Complex EIL than OLED with LiF EIL. And we show the Optimized Alkali Metal Complex thickness is 3nm. Existent LiF to because is inorganic material, there is trouble to do epitaxy into thin layers but regulates the thickness in case of Alkali Metal Complex matter characteristic that is easy be. Alkali Metal Complex also appeared by sensitive thing in thickness than LiF If utilize this material, It is thought much advantages may be at common use of OLED.

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Distribution Characteristics and Source Estimation of Volatile Organic Compounds in the Ambient Air of Industrial Complex in Gwangju (광주지역 산업단지 대기 중 휘발성유기화합물 분포 특성 및 배출원 추정)

  • Min-Jin Kim;Ok-Hyun Park;Yoon-Cheol Yang;Jin-Hwan Park;Ji-Yong Yu;Hee-Yun Jung;Gwang-Yeob Seo;Jong-Min Kim
    • Journal of Environmental Science International
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    • v.32 no.6
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    • pp.403-417
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    • 2023
  • In this study, we investigated the characteristics of Volatile Organic Compounds(VOCs) emission from painting and printing facilities in the Pyeongdong industrial complex in Gwangju. In addition, the objective was to understand the distribution characteristics of VOCs in the ambient air in industrial complexes affected by painting and printing facilities. The painting facility mainly emitted toluene, acetone, butyl acetate, 4-methyl-2-pentanone, ethyl acetate, 1-butanol, methyl ethyl ketone, m,p-xylene, o-xylene, 4-ethyltoluene, ethylbenzene, 3-ethyltoluene, and 1,2,4-trimethylbenzene. The main emission components in printing facilities were methyl ketone, ethyl acetate, acetone, 2-propanol, toluene, heptane, and butyl acetate. Ethyl acetate, toluene, 2-butanone, acetone, butyl acetate, 2-propanol, xylenes, and 4-methyl-2-pentanone were detected in the ambient air of the Pyeongdong industrial complex, consistent with the VOCs emitted by painting and printing facilities. The average concentration of seasonal TVOCs followed an order of winter > fall > spring > summer, whereas the concentrations of daytime and nighttime TVOCs were generally higher at night than those during the day, and the wind speed was greater during the day than it was at night. Based on a factor analysis of VOCs in the ambient air of Pyeongdong industrial complex, it is considered that organic solvents used in coating, printing, and electronics manufacturing facilities, as well as diesel vehicle emissions played a major role.