• 제목/요약/키워드: Organic complex

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윤활유 종류에 따른 이륜자동차 PM2.5 및 배출가스 특성 연구 (The Study of PM2.5 and Exhaust Emission Characteristics in the Motorcycles according to Various Lubricants)

  • 임윤성;이종태;박장민;김정수;이장훈
    • 한국자동차공학회논문집
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    • 제21권4호
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    • pp.70-76
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    • 2013
  • Because increased food delivery service and quick delivery service using motorcycle, registration numbers of motorcycles were sharply increased and it could contribute on worsening air quality. In this study, two models(50cc, 125cc) of motorcycle were tested by using three types of engine oil. Two motorcycles were tested with CVS-40 mode for emission characteristics such as CO, THC, NOx, Elemental Carbon(EC), Organic Carbon(OC), sulfate, soot and SOF(soluble organic fraction). Result of according to three types of lubricants which included phosphorus, sulfate ash impacted to particle matters so "C" lubricants is more higher PM than "A", "B" lubricants in this research.

대구성서산업단지 발생원부지경계 대기 중 휘발성유기화합물질의 농도수준 (Concentration level of Volitile Organic Compounds about the Air of Source Boundary Site in Seongseo Industrial Complex)

  • 안상영;최성우
    • 한국환경과학회지
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    • 제14권1호
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    • pp.53-60
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    • 2005
  • The concentrations of volatile organic compounds(VOCs) in the ambient air were measured at various point(Source, source boundary) in Seongseo industrial complex during May to November 2003. Air samples were collected in Silcocan canister $(1{\ell},\;6{\ell})$ and analyzed using a cryogenic preconcentration system and GC/MSD. We identified 37 species by the US EPA(TO-14 method). The result showed a variety distribution of the con­centration, Higher concentrations of BTX, Styrene, 1,3,5-Trimethylbenzene, 1,2,4-Trimethylbenzene were observed at the sampling sites. They seemed to be emitted from the facility of wastewater treatment, reaction tank of chemistry factory and facility of Tenter. The concentrations of VOCs contents in Seongseo industrial complex were generally higher than those in Yeosu complex and Ulsan complex, although those were similar in Sihwa­Banwol complex.

Lithium Complex as a New Electron Injection Layer in Organic Light Emitting Devices

  • Lee, Min-Woo;Lee, Jae-Goo;Kim, Sung-Min;Kim, Bong-Ok;Kwak, Mi-Young;Choi, Kyung-Hoon;Lim, Hyo-Jung;Si, Sang-Man;Sohn, Byung-Chun;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.959-962
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    • 2003
  • This study is the effect of lithium Lithium Complex as an electron injection layer(EIL) on the performance of organic light emitting devices (OLEDs) and optimized the device efficiency by varying thickness of EIL layer. The device with 2nm GDI 101 layer showed significant enhancement of the device performance and device lifetime. We also compared GDI 109 and GDI 117 with GDI 101 as an electron injection layer.

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Fabrication of Organic Nanowire Electronics by Direct Printing Method

  • 박경선;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.563-563
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    • 2012
  • We report a one-step fabrication of single-crystal organic nanowire arrays on substrates using a new direct printing method (liquid-bridge-mediated nanotransfer moulding, LB-nTM), which can simultaneously enable the synthesis, alignment and patterning of the nanowires using molecular ink solutions. Two- or three-dimensional complex structures of various single-crystal organic nanowires were directly fabricated over a large area with a successive process. The position of the nanowires can be aligned easily on complex structures because the mold is movable on substrates before drying the polar liquid layer, which acts as an adhesive lubricant. This efficient manufacturing method can produce a wide range of optoelectronic devices and integrated circuits with single-crystal organic nanowires.

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Preparation of Silver Nanocolloids Using Silver Alkylcarbamate Complex in Organic Medium with PVP Stabilizer

  • Park, Hyung-Seok;Park, Heon-Su;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • 제31권9호
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    • pp.2575-2580
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    • 2010
  • We present a method for chemically reducing silver alkylcarbamate complex with hydrazine to synthesize silver nanocolloids in an organic solvent using polyvinylpyrrolidone (PVP) as the stabilizer. To determine the optimal conditions for preparing stable silver colloids of controlled size and shape, the silver 2-ethylhexylcarbamate (Ag-EHCB) complex, PVP, hydrazine, and 2-propanol solvent concentrations in the reaction mixture were varied. The initial colloid has a mean particle diameter of 5-80 nm, and it exhibits an absorption band with various shapes in the UV region with a maximum near 420 nm. UV-vis spectroscopy, TEM, and X-ray diffraction techniques were used to investigate the formation and growth process of the metallic silver nanocolloids.

Formation of the Polycaprolactam between Layers of the [DEACOOH]-Montmorillonite Intercalations Complex and Its Characterization

  • Cho, Sung-Jun
    • 한국세라믹학회지
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    • 제43권4호
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    • pp.207-212
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    • 2006
  • [ ${\varepsilon}-caprolactam$ ] was polymerized in the layers of the [DEACOOH]-Montmorillonite intercalations complex at high temperatures ranging from 250% to 260% formed from Na-Montmorillonite and 10-Carboxy-n-decyldimethylethylammonium bromide to achieve [DEACOOH]-Polycaprolactam-Montmorillonite, in which an inorganic polymer (montmorillonite) is chemically combined with an organic polymer (polycaprolactam). The results of X-ray and IR analyses for the samples obtained after polymerization showed that the polymerization reaction was successfully accomplished. For the purpose of studying the polymeric reaction product more precisely, the polymerized product was separated from the silicate layers and analyzed with an X-ray diffractometer and an IR-spectrometer. A comparison of the results of the X-ray and IR analyses of the separated polymer and the polymer that was synthesized by the reaction of ${\varepsilon}-caprolactam$ solely with the organic cation without montmorillonite showed that the obtained both polymers are identical compounds.

유기전기발광소자에 사용될 수 있는 백금 착물에 대해 보조리간드 phenyl 기가 발광스펙트럼에 미치는 영향 (Effect of Ancillary Ligand, Phenyl group, on the Emission Spectrum of Pt(II) Complex Useful for Organic Light-Emitting Device)

  • 이승희;이호준
    • 한국응용과학기술학회지
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    • 제25권2호
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    • pp.265-268
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    • 2008
  • Among the efforts to increase the efficiency of organic light-emitting device (OLED), there is a way: doping phosphorescent materials. As a phosphorescent material, complexes of heavy transition metal, platinum, were synthesized. $Cl^-$ ion and phenyl group were used as ancillary ligands with 2-(2-pyridyl)benzimidazole (pbi) as a chromophore. The complexes were analysed by FAB-mass spectrometer and absorption and emission spectra were obtained. A phenyl group was able to shift the emission band of the complex even if it's not a chromorphore.

신 레이저매질 Yb(SOL-D)$_3$착물의 광학적 특성 (Optical Properties of Yb(SOL-D)$_3$ Complex for Laser Material)

  • 김정호;서연호;박용필
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.640-643
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    • 2001
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(SOL-D)$_3$] complexes were synthesized by the keto-enol tautomerism reaction of Yb(SOL-H)$_3$in methanol-d$_4$in order to reduce the radiationless transition to the ligands. The luminescence properties of Yb(SOL-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$_{8}$, PO(O$CH_3$)$_3$and DMSO-d$_{6}$. The intensity, lifetime and quantum efficiency of the luminescence in DMSO-d$_{6}$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$_{6}$ might be the most appropriate solvent for the liquid laser material of Yb(SOL-D)$_3$complex.complex.

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알칼리 금속 전자 주입층을 사용한 유기 전기 발광 소자 (OLED)의 전기적 특성 (Electrical Characteristics of Organic Light Emitting Diodes (OLED) using the Alkali Metal Complex as New Electron Injection Layers)

  • 이현구;김준호;김영관
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.1015-1018
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    • 2004
  • We investigate the influence of the New Electron Injection Layers (EIL) on the performance of the Alkali Metal Complex vapor-deposited Organic Light Emitting Diodes(OLED). Two different Alkali Metal Complex were used; Lithium Quinolate (Liq), and Sodium Quinolate (Naq). In all cases, $Alq_3$ was the Electron Transporting Layer (ETL). We measure and compare the current density-voltage (J-V) and luminance-voltage (L-V) characteristics. We concluded that the turn-on voltage, and luminance efficiency are controlled by the type of EIL material used. We show the longer life-time OLED with Alkali Metal Complex EIL than OLED with LiF EIL. And we show the Optimized Alkali Metal Complex thickness is 3nm. Existent LiF to because is inorganic material, there is trouble to do epitaxy into thin layers but regulates the thickness in case of Alkali Metal Complex matter characteristic that is easy be. Alkali Metal Complex also appeared by sensitive thing in thickness than LiF If utilize this material, It is thought much advantages may be at common use of OLED.

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광주지역 산업단지 대기 중 휘발성유기화합물 분포 특성 및 배출원 추정 (Distribution Characteristics and Source Estimation of Volatile Organic Compounds in the Ambient Air of Industrial Complex in Gwangju)

  • 김민진;박옥현;양윤철;박진환;유지용;정희윤;서광엽;김종민
    • 한국환경과학회지
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    • 제32권6호
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    • pp.403-417
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    • 2023
  • In this study, we investigated the characteristics of Volatile Organic Compounds(VOCs) emission from painting and printing facilities in the Pyeongdong industrial complex in Gwangju. In addition, the objective was to understand the distribution characteristics of VOCs in the ambient air in industrial complexes affected by painting and printing facilities. The painting facility mainly emitted toluene, acetone, butyl acetate, 4-methyl-2-pentanone, ethyl acetate, 1-butanol, methyl ethyl ketone, m,p-xylene, o-xylene, 4-ethyltoluene, ethylbenzene, 3-ethyltoluene, and 1,2,4-trimethylbenzene. The main emission components in printing facilities were methyl ketone, ethyl acetate, acetone, 2-propanol, toluene, heptane, and butyl acetate. Ethyl acetate, toluene, 2-butanone, acetone, butyl acetate, 2-propanol, xylenes, and 4-methyl-2-pentanone were detected in the ambient air of the Pyeongdong industrial complex, consistent with the VOCs emitted by painting and printing facilities. The average concentration of seasonal TVOCs followed an order of winter > fall > spring > summer, whereas the concentrations of daytime and nighttime TVOCs were generally higher at night than those during the day, and the wind speed was greater during the day than it was at night. Based on a factor analysis of VOCs in the ambient air of Pyeongdong industrial complex, it is considered that organic solvents used in coating, printing, and electronics manufacturing facilities, as well as diesel vehicle emissions played a major role.