• Title/Summary/Keyword: Organic chemistry

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Rheological Properties of Dough and Quality Characteristics of Bread Containing Whey Ferment Cultured by L. acidophilus KCCM 32820 and P. freudenreichii KCCM 31227 (L. acidophilus KCCM 32820과 P. freudenreichii KCCM 31227로 배양한 유청발효물을 첨가한 반죽 레올로지 및 식빵의 품질특성)

  • Lee, Jeong-Hoon;Choi, Mi-Jung;Chung, Koo-Chun;Lee, Si-Kyung
    • Food Science of Animal Resources
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    • v.32 no.6
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    • pp.803-809
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    • 2012
  • This study was carried out to evaluate the effects of whey ferment containing L. acidophilus KCCM 32820 and P. freudenreichii KCCM 31227 on the quality characteristics of white pan bread. Instrumental analysis such as alveograph, gelatinization temperature, texture analysis, retrogradation rate was determined. In an alveograph test, $P_{max}$ value in the treatment was higher than that in the control, but extensibility of dough in the control showed to be higher than in the treatment, so test dough showed more strength than the control. In terms of DSC analysis for gelatinization, temperature there were no significant differences of $T_p$ and ${\Delta}H$ between the control and the treatment. In hardness analysis by rheometer, dough containing whey ferment revealed lower values than the control. From the analysis of the organic acid contents, propionic acid was not detected in the control, however 1.13 mg/g of propionic acid was detected in the treatment. In the retrogradation analysis by DSC, the test delayed slightly compared to the control.

Degradation Characteristics of Non-degradable Dye in Aqueous Solution by Ozonation (고도산화공정인 오존처리에 의한 난분해성 염료 수용액의 분해특성)

  • Hwang, Se-Wook;Park, Jong-Hwan;Lee, Su-Lim;Eom, Ju-Hyun;Ryu, Sung-Ki;Choi, Ik-Won;Kim, Seong-Heon;Kang, Se-Won;Cho, Ju-Sik;Seo, Dong-Cheol
    • Korean Journal of Environmental Agriculture
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    • v.39 no.1
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    • pp.58-64
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    • 2020
  • BACKGROUND: Most of the researches on the dye removal using ozonation have been focused on the removal efficiency. However, the research on their removal characteristics and mechanism according to the reaction time has been still insufficient. METHODS AND RESULTS: In this study, the effects of initial pH and dye concentration with reaction time on the degradation characteristics of methyl orange (MO) and methylene blue (MB) by ozonation were evaluated. The degradation efficiency of MB by ozonation increased with increasing pH. On the other hand, the degradation efficiency of MO by ozonation did not show a significant difference with varing pH. The both MO and MB by ozonation were decomposed within 30 min irrespective of the dye concentration, but the decomposition rates of dyes were faster at lower initial dye concentration. The decomposition efficiency of total organic carbon (TOC) in each dye solution by ozonation was low, which was found to be effective for partial decomposition such as decolorization rather than complete degradation of the dye. CONCLUSION: Overall, ozonation was an effective method for removing nondegradable dyes. However, it is necessary to study the optimization of dye degradation under various environmental conditions for ozonation.

Optical Diagnostics of Nanopowder Processed in Liquid Plasmas

  • Bratescu, M.A.;Saito, N.;Takai, O.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.17-18
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    • 2011
  • Plasma in liquid phase has attracted great attention in the last few years by the wide domain of applications in material processing, decomposition of organic and inorganic chemical compounds and sterilization of water. The plasma in liquid is characterized by three main regions which interact each - other during the plasma operation: the liquid phase, which supply the plasma gas phase with various chemical compounds and ions, the plasma in the gas phase at atmospheric pressure and the interface between these two regions. The most complex region, but extremely interesting from the fundamental, chemical and physical processes which occur here, is the boundary between the liquid phase and the plasma gas phase. In our laboratory, plasma in liquid which behaves as a glow discharge type, is generated by using a bipolar pulsed power supply, with variable pulse width, in the range of 0.5~10 ${\mu}s$ and 10 to 30 kHz repetition rate. Plasma in water and other different solutions was characterized by electrical and optical measurements. Strong emissions of OH and H radicals dominate the optical spectra. Generally water with 500 ${\mu}S/cm$ conductivity has a breakdown voltage around 2 kV, depending on the pulse width and the repetition rate of the power supply. The characteristics of the plasma initiated in ultrapure water between pairs of different materials used for electrodes (W and Ta) were investigated by the time-resolved optical emission and the broad-band absorption spectroscopy. The deexcitation processes of the reactive species formed in the water plasma depend on the electrode material, but have been independent on the polarity of the applied voltage pulses. Recently, Coherent anti-Stokes Raman Spectroscopy method was employed to investigate the chemistry in the liquid phase and at the interface between the gas and the liquid phases of the solution plasma system. The use of the solution plasma allows rapid fabrication of the metal nanoparticles without being necessary the addition of different reducing agents, because plasma in the liquid phase provides a reaction field with a highly excited energy radicals. We successfully synthesized gold nanoparticles using a glow discharge in aqueous solution. Nanoparticles with an average size of less than 10 nm were obtained using chlorauric acid solutions as the metal source. Carbon/Pt hybrid nanostructures have been obtained by treating carbon balls, synthesized in a CVD chamber, with hexachloro- platinum acid in a solution plasma system. The solution plasma was successfully used to remove the template remained after the mesoporous silica synthesis. Surface functionalization of the carbon structures and the silica surface with different chemical groups and nanoparticles, was also performed by processing these materials in the liquid plasma.

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Ridge Formation by Dry-Etching of Pd and AlGaN/GaN Superlattice for the Fabrication of GaN Blue Laser Diodes

  • Kim, Jae-Gwan;Lee, Dong-Min;Park, Min-Ju;Hwang, Seong-Ju;Lee, Seong-Nam;Gwak, Jun-Seop;Lee, Ji-Myeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.391-392
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    • 2012
  • In these days, the desire for the precise and tiny displays in mobile application has been increased strongly. Currently, laser displays ranging from large-size laser TV to mobile projectors, are commercially available or due to appear on the market [1]. In order to achieve a mobile projectors, the semiconductor laser diodes should be used as a laser source due to their size and weight. In this presentation, the continuous etch characteristics of Pd and AlGaN/GaN superlattice for the fabrication of blue laser diodes were investigated by using inductively coupled $CHF_3$ and $Cl_2$ -based plasma. The GaN laser diode samples were grown on the sapphire (0001) substrate using a metal organic chemical vapor deposition system. A Si-doped GaN layer was grown on the substrate, followed by growth of LD structures, including the active layers of InGaN/GaN quantum well and barriers layer, as shown in other literature [2], and the palladium was used as a p-type ohmic contact metal. The etch rate of AlGaN/GaN superlattice (2.5/2.5 nm for 100 periods) and n-GaN by using $Cl_2$ (90%)/Ar (10%) and $Cl_2$ (50%)/$CHF_3$ (50%) plasma chemistry, respectively. While when the $Cl_2$/Ar plasma were used, the etch rate of AlGaN/GaN superlattice shows a similar etch rate as that of n-GaN, the $Cl_2/CHF_3$ plasma shows decreased etch rate, compared with that of $Cl_2$/Ar plasma, especially for AlGaN/GaN superlattice. Furthermore, it was also found that the Pd which is deposited on top of the superlattice couldn't be etched with $Cl_2$/Ar plasma. It was indicating that the etching step should be separated into 2 steps for the Pd etching and the superlattice etching, respectively. The etched surface of stacked Pd/superlattice as a result of 2-step etching process including Pd etching ($Cl_2/CHF_3$) and SLs ($Cl_2$/Ar) etching, respectively. EDX results shows that the etched surface is a GaN waveguide free from the Al, indicating the SLs were fully removed by etching. Furthermore, the optical and electrical properties will be also investigated in this presentation. In summary, Pd/AlGaN/GaN SLs were successfully etched exploiting noble 2-step etching processes.

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Retention Behavior and Separation of Phenol Derivatives through Cyclodextrin Complexes in Reversed-Phase Liquid Chromatography (역상 액체 크로마토그래피에서 씨클로덱스트린 착물을 이용한 페놀유도체들의 머무름 거동 및 분리)

  • Moon, Young-Ja;Kang, Sam-Woo
    • Analytical Science and Technology
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    • v.11 no.3
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    • pp.179-188
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    • 1998
  • The capacity factor of fifteen phenol derivatives was determined with respect to the concentration of ${\alpha}$- or ${\beta}$-cyclodextrin [CD], the type as well as the content of organic solvent in the mobile phase, and the temperature. The effect of the inclusion complex formation between solutes and ${\alpha}$- or ${\beta}$-cyclodextrin on their retention and selectivity has been investigated. The inclusion effect of ${\beta}$-cyclodextrin was the most effective in aqueous methanol, whereas only a poor effect was observed in aqueous tetrahydrofuran and aqueous acetonitrile. A plot of the reciprocal of the capacity factor against $[CD]_T$ gives a straight line and the dissociation constant, $K_D$ of the inclusion complex can be calculated from the slope. It was possible to estimate the $k_D$ values in 100% water from a linear plot of $pK_D$ vs. water content in the solution by extrapolation. The separation factor, ${\alpha}$, of two compounds has been found to be affected not only by the $[CD]_T$ but also by their $K_D$ values. Under optimum conditions, some mixtures of phenol derivatives were able to separate successfully.

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Tertiary Treatment of Municipal Wastewater Using Unsaturated Sandy Soil (불포화 사질토양을 이용한 도시하수의 3차 처리)

  • Kim, Seung-Hyun;Chung, Jong-Bae;Ha, Hyun-Soo;Prasher, Shiv O.
    • Korean Journal of Environmental Agriculture
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    • v.22 no.2
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    • pp.111-117
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    • 2003
  • Treatment of secondary effluent was investigated using sandy soil as a possible alternative to the tertiary treatment of municipal wastewater. Secondary effluent was applied with three different flow rates to the surface of pilot scaled lysimeters, which were filled with sandy soil. Some of the lysimeters were covered with osd, while others were kept bare in order to investigate the role of plantation on the treatment. The concentration changes in COD and nitrogen were measured along the unsaturated soil depth. The same set of experiment as with the secondary effluent was performed using tap water to investigate the dissolution of the contaminants from the soil. from the results it was found that when sandy soil was used for tertiary treatment of municipal wastewater COD removal efficiency reached about 70% regardless of the application rate. The soil depth needed to obtain such efficiency increased along with the application rate, which was about 60 cm at the application rate of 50 L/day. Results also showed that nitrification occurred rapidly. The process was completed in soil depth of first $10{\sim}20\;cm$. Nitrogen removal efficiency was as low as about 20% regardless of the application rate. Some supplementary means should be considered to improve the efficiency. Sod on the soil surface had no significant influence on the contaminant treatment but was helpful to keep the infiltration rate undiminished. Finally, the organic soil was found to release significant amount of contaminants when it was in contact with soil water.

Comparison of Reservoir Sediment in Kum River Basin

  • Hwang, Jong Yeon;Han, Eui Jung;Kim, Tae Seung;Kim, Tae Keun;Yu, Soon Ju;Kim, Shin Jo;Yoon, Young Sam;Chung, Yong Soon
    • Journal of Environmental Impact Assessment
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    • v.8 no.1
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    • pp.107-120
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    • 1999
  • This study was performed to survey the general feature of reservoir sediment in Daecheong, Sapkyo and Kumkang reservoir. For investigations, sediments were sampled at four sites in Dae-Cheong and two sites in SapKyo and Kumkang in June and October. The items for investigation are as follows; water content, loss on ignition(IG), porosity of sediment, contents of element such as hydrogen, nitrogen, carbon, phosphorus contents and nutrient release rates. Loss on ignition was measured to determine the contents of organic substance. And its ranges were determined 2.4~16.2% in Daecheong reservoir, 5.6~27.9% in Sapkyo and 4.8~18.7% in Kumkang reservoir. And, total phosphorus contents in sediments were measured $677{\sim}5,238{\mu}g/g$ in Daecheong, $780{\sim}1,417{\mu}g/g$ in Sapkyo and $604{\sim}1,452{\mu}g/g$ in Kumkang reservoir. And release rates of nutrients were calculated $0.05{\sim}8.63mgP/m^2day$ and $4.99{\sim}36.56mgN/m^2day$ in Daecheong, $1.83{\times}10^{-3}{\sim}3.23{\times}10^{-2}mgP/m^2day$ and $1.97{\sim}.22mgN/m^2day$ in Sapkyo, $8.31{\times}10^{-3}{\sim}6.51{\times}10^{-2}mgP/m^2day$ and $0.89{\sim}4.42mgN/m^2day$ in Kumkang reservoir, respectively. And this study attempted to determine the humus level of sediments. As a result of elemental analysis, C/N ratio was determined 3.0~13.1 in Daecheong reservoir, 6.5~13.0 in Sapkyo and 3.6~12.6 in Kumkang reservoir, respectively. From the elemental analysis, humus levels of reservoirs were changed from mesohumic to oligohumic state in all reservoirs.

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Waterquality Characteristics and Ecosystem Health Assessments Using a LEHA Fish Model in Shingu Reservoir (신구저수지의 수질특성 및 LEHA 어류모델을 이용한 생태건강도 평가)

  • Lee, Jae-Yon;Lee, Sang-Jae;Han, Jung-Ho;Lee, Eui-Hang;Choi, Ji-Woong;Hwang, Soon-Jin;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.41 no.spc
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    • pp.42-49
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    • 2008
  • For this study, we collected fishes of four times at the four site during June 2006 ${\sim}$ September 2007. In the result, the tolerance and omnivore species like a Carassius auratus and Pseudorasbora parva were largely dominated over all, and the sensitive species was not appeared at all except S4 in Shingu reservoir. This reservoir was appeared the simplified of trophic guild was shown in Shingu reservoir. Demonstrating that the omnivore species was occupied 78% of whole. According to the water chemistry data set obtained from the Korea Rural community & Agriculture corporation during $2002{\sim}2005$, the Shingu reservoir showed severe eutrophication and water pollution, therefore the increase of primary production and frequent algal blooms had been occurred. On the other hand, ecosystem health of reservoir was appeared "Fair${\sim}$Poor", and we judged that eutrophication and water pollution were due to this. Consequently, we thought that interception of nutrients and organic matters from the farmland and village and management of reservoir would be need, after this.

Changes of Rice Yields and Soil Chemical Properties in 5-Year Direct Seeding on Dry Paddy after Barley (보리후작 벼 다년건답직파시 수량 및 토양 화학성 변화)

  • Park, Sung-Tae;Hwang, Dong-Yong;Moon Byeong-Chul;Kim, Soon-Chul;Oh, Yun-Jin
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.40 no.5
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    • pp.562-568
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    • 1995
  • Changes in rice yield and soil chemistry of dry seeded rice in double cropping of rice and barley were investigated at National Yeongnam Agricultural Experiment Station during 5 years (1990-1994). Barley straw added or removed dry seeding had safe rice seedling stand for good rice production. However, the coefficient of variation of seedling stand by year was higher than dry seeding in rice single crop. Rice seedling height was slightly reduced by barley straw incorporation. However, it recovered soon as rice growing progressed. Heading time delayed 4 days in flat seeding method but not in high-ridged seeding method which imply that. this is more safe seeding technology than flat seeding method. Comparing to rice single crop, barley straw added dry seeding increased rice yield by 2∼19%(Average of 5 years: 8%) from second year due to higher panicle and spikelet number. Contents of organic matter was 2.71% in 1990. In 1994, it decreased 2.61% for rice single crop, while increased 3.02% and 3.41% for barley straw removed or added field, respectively. Rice grain quality was not significantly different among cropping patterns.

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Fabrication of Nano $Y_{2}O_{3}-CeO_{2}$ Sintered Body Using Dispersion Stability (분산 안정성을 이용한 나노 $Y_{2}O_{3}-CeO_{2}$ 소결체의 제조)

  • Kim, Eun-Jung;Lee, Sang-Hoon;Choi, Sung-Churl
    • Journal of the Korean Ceramic Society
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    • v.38 no.9
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    • pp.853-859
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    • 2001
  • The dispersion stability of nano $Y_2O_3-CeO_2$ system was investigated using colloid surface chemistry. Green body of $Y_2O_3$ doped $CeO_2$ was prepared by slip casting in and aqueous system. The dispersion stability of suspension between powders and organic additive was accomplished through electrokinetic behavior of suspension, which was done by ESA apparatus. The dynamic mobility of particles was enhanced when the anionic dispersant of the amount of 1wt% was added. The dissolution of $Y^{3+}$ ion in suspension occurred in the acidic region so that pH value in slurries did not move to below 7.0. In the $CeO_2-Y_2O_3$ system, optimal preparation of suspension was made after adding the anionic dispersant as the amount of 1wt% and pH value of 11.0, and then slip-cast and sintered at 1400$^{\circ}$C, 2 hrs. It appeared relative density of >98% and homogeneous distribution of Y element in depth direction as well as in the microstructure of surface.

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