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http://dx.doi.org/10.5338/KJEA.2020.39.1.8

Degradation Characteristics of Non-degradable Dye in Aqueous Solution by Ozonation  

Hwang, Se-Wook (Division of Applied Life Science (BK21 Plus) & Institute of Agriculture and Life Science, College of Agriculture and Life Sciences, Gyeongsang National University)
Park, Jong-Hwan (Division of Applied Life Science (BK21 Plus) & Institute of Agriculture and Life Science, College of Agriculture and Life Sciences, Gyeongsang National University)
Lee, Su-Lim (Division of Applied Life Science (BK21 Plus) & Institute of Agriculture and Life Science, College of Agriculture and Life Sciences, Gyeongsang National University)
Eom, Ju-Hyun (Division of Applied Life Science (BK21 Plus) & Institute of Agriculture and Life Science, College of Agriculture and Life Sciences, Gyeongsang National University)
Ryu, Sung-Ki (Agricultural Chemistry, Graduate Schoools, Gyeongsang National University)
Choi, Ik-Won (Water Environmental Engineering Research Division, Water Environment Research Department, National Institute of Environmental Research)
Kim, Seong-Heon (Soil and Fertilizer Division, Department of Agricultural Environment, National Institute of Agricultural Sciences, Rural Development Administration)
Kang, Se-Won (Red River Research Station, Louisiana State University Agricultural Center)
Cho, Ju-Sik (Department of Bio-Environmental Sciences, College of Life Sciences Industry, Sunchon National University)
Seo, Dong-Cheol (Division of Applied Life Science (BK21 Plus) & Institute of Agriculture and Life Science, College of Agriculture and Life Sciences, Gyeongsang National University)
Publication Information
Korean Journal of Environmental Agriculture / v.39, no.1, 2020 , pp. 58-64 More about this Journal
Abstract
BACKGROUND: Most of the researches on the dye removal using ozonation have been focused on the removal efficiency. However, the research on their removal characteristics and mechanism according to the reaction time has been still insufficient. METHODS AND RESULTS: In this study, the effects of initial pH and dye concentration with reaction time on the degradation characteristics of methyl orange (MO) and methylene blue (MB) by ozonation were evaluated. The degradation efficiency of MB by ozonation increased with increasing pH. On the other hand, the degradation efficiency of MO by ozonation did not show a significant difference with varing pH. The both MO and MB by ozonation were decomposed within 30 min irrespective of the dye concentration, but the decomposition rates of dyes were faster at lower initial dye concentration. The decomposition efficiency of total organic carbon (TOC) in each dye solution by ozonation was low, which was found to be effective for partial decomposition such as decolorization rather than complete degradation of the dye. CONCLUSION: Overall, ozonation was an effective method for removing nondegradable dyes. However, it is necessary to study the optimization of dye degradation under various environmental conditions for ozonation.
Keywords
AOP (Advance oxidation process) Dye degradation; Methylene Blue; Methyl Orange; Ozonation;
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