• Title/Summary/Keyword: Organic chemicals

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Determination of Malodor-causing Chemicals Produced by Microorganisms Inside Automobile (차량 내 미생물에 의해 생성되는 악취유발 화학물질의 분석)

  • Park, SangJun;Kim, EuiYong
    • KSBB Journal
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    • v.29 no.2
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    • pp.118-123
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    • 2014
  • It was confirmed that malodor connected with an air-conditioner in an automobile is caused by microbial volatile organic compounds (MVOCs) produced by microorganisms getting into an air-conditioner when it is operating. Chemicals such as hydrogen sulfide, dimethyl sulfide, nbutyric acid, n-valeric acid, iso-valeric acid, n-octanol and toluene were detected above the odor threshold inside the automobile. The characteristics of a funky odor in the air blown into the automobile were due to detected sulfur compounds (hydrogen sulfide and dimethyl sulfide). Dimethyl sulfide was produced by microorganisms such as Aspergillus versicolor, Methylobacterium aquaticum, Herbaspirillum sp. and Acidovorax sp. In addition, the characteristics of a sour odor in the air blown into the automobile were due to detected organic acids (n-butyric acid, n-valeric acid and iso-valeric acid). N-valeric acid and iso-valeric acid were generated from Aspergillus versicolor, while iso-valeric acid was produced by Methylobacterium aquaticum. In addition, the odor intensity of the air blown into the automobile was affected by the concentration of detected sulfur compounds and organic acids. On the other hand, it is estimated that chemicals such as hydrogen sulfide, n-octanol and n-butyric acid detected in the air blown into the automobile were produced by non-identified species of microorganisms.

Early-life exposure to endocrine disrupting chemicals associates with childhood obesity

  • Yang, Chunxue;Lee, Hin Kiu;Kong, Alice Pik Shan;Lim, Lee Ling;Cai, Zongwei;Chung, Arthur C.K.
    • Annals of Pediatric Endocrinology and Metabolism
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    • v.23 no.4
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    • pp.182-195
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    • 2018
  • Increasing prevalence of childhood obesity poses threats to the global health burden. Because this rising prevalence cannot be fully explained by traditional risk factors such as unhealthy diet and physical inactivity, early-life exposure to endocrine disrupting chemicals (EDCs) is recognized as emerging novel risk factors for childhood obesity. EDCs can disrupt the hormone-mediated metabolic pathways, affect children's growth and mediate the development of childhood obesity. Many organic pollutants are recently classified to be EDCs. In this review, we summarized the epidemiological and laboratory evidence related to EDCs and childhood obesity, and discussed the possible mechanisms underpinning childhood obesity and early-life exposure to non-persistent organic pollutants (phthalates, bisphenol A, triclosan) and persistent organic pollutants (dichlorodip henyltrichloroethane, polychlorinated biphenyls, polybrominated diphenyl ethers, per- and polyfluoroalkyl substances). Understanding the relationship between EDCs and childhood obesity helps to raise public awareness and formulate public health policy to protect the youth from exposure to the harmful effects of EDCs.

Swelling and Drug Release Behavior of Tablets Coated with Aqueous Hydroxypropyl Methylcellulose Phthalate (HPMCP) Nanoparticles

  • Kim, Il-Hyuk;Baek, Hyon-Ho;Kim, Jung-Hyun
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.297.1-297.1
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    • 2003
  • Organic solvent-based enteric coating technology using hydroxypropyl methylcellulose phthalate (HPMCP) has been developed for many years due to low water solubility of HPMCP. In this work, aqueous HPMCP nanoparticles (HPMCP-NPs) were prepared by neutralization emulsification method using HPMCP powder and ammonium hydroxide (NH40H) in the absence of any organic solvent and emulsifier. (omitted)

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Decomposition of Dye Chemicals by Electrolytic Oxidation Method (전기분해법을 이용한 염료분해에 관한 연구)

  • Lee, Tae-Jin;Chun, Byoung Chul;Chung, Yong-Chan
    • Clean Technology
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    • v.12 no.3
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    • pp.145-150
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    • 2006
  • Electrolysis of aqueous solution produces hydroxide ions and proton ions for the hydrolysis of reactive organic compounds, and oxidizing agent such as hypochlorite ions for the oxidative decomposition of organic chemicals. Electrolytic decomposition of dying chemicals was tested with our custom made system, and analyzed by HPLC and UV-VIS spectrophotometer. The electrolytic system could decompose dying chemicals with very high reactivity and low cost. Disposal of byproduct and refill of reactant during electrolysis was not necessary. Decomposition time of dying chemicals is compared under similar conditions, and application to water purification is discussed.

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Bioaccumulation and Baseline Toxicity of Hydrophobic Chemicals: Molecular Size Cutoff, Kinetic Limitations, and Chemical Activity Cut-off (소수성화학물질의 생물축적과 기저독성: 분자크기, 반응속도, 화학적 활성도에 따른 제약)

  • Kwon, Jung-Hwan
    • Environmental Analysis Health and Toxicology
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    • v.23 no.2
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    • pp.67-77
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    • 2008
  • It has been observed that the linear relationship between the logarithm of bioconcentration factor (log BCF) of highly hydrophobic chemicals and their log $K_{ow}$ breaks when log $K_{ow}$ becomes greater than 6.0. Consequently, super hydrophobic chemicals were not thought to cause baseline toxicity as a single compound. Researchers often call this phenomenon as "hydrophobicity cutoff" meaning that bioconcentration or corresponding baseline toxicity has a certain cutoff at high log $K_{ow}$ value of hydrophobic organic pollutants. The underlying assumption is that the increased molecular size with increasing hydrophobicity prohibits highly hydrophobic compounds from crossing biological membranes. However, there are debates among scientists about mechanisms and at which log $K_{ow}$ this phenomenon occurs. This paper reviews three hypotheses to explain observed "cutoff": steric effects, kinetic or physiological limitations, and chemical activity cutoff. Although the critical molecular size that makes biological membranes not permeable to hydrophobic organic chemicals is uncertain, size effects in combination with kinetic limitation would explain observed non-linearity between log BCF and log $K_{ow}$. Chemical activity of hydrophobic chemicals generally decreases with increasing melting point at their aqueous solubility. Thus, there may be a chemical activity cutoff of baseline toxicity if there is a critical chemical activity over which baseline effects can be observed.

Synthesis and Characterization of Water-borne Pressure Sensitive Adhesives Polymerized using Styrenated Phenol Type Surfactants (스티렌페놀계 계면활성제 기반 친환경 수계 점착제 합성 및 특성 분석)

  • Song, Young Kyu;Lee, Sang-Ho;Park, Young Il;Kim, Jin Chul
    • Journal of Adhesion and Interface
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    • v.21 no.4
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    • pp.156-161
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    • 2020
  • Waterborne pressure sensitive adhesives (PSA) has been received much attentions from both academia and industries as an environmental friendly-technology because it can significantly reduce use of hazardous organic volatile solvents. However, in the process of the mass production of waterborne PSAs, hazardous phenol type amphiphilic compounds have essentially been used as surfactants for the emulsion polymerization. For the reason, tremendous research efforts have been made to develop environment-friendly organic surfactant which can replace the phenol type surfactants. In this study, we verify the potential of a new class of surfactants based on the styrenated phenol derivatives as an alternative to the phenol type surfactants.

Improving the Fading of Reusable Surgical Gown by Repeated Severe Laundering and Sterilization Condition (반복되는 고온 세탁 및 멸균 환경에 대한 Reusable 수술가운 원단의 퇴색 저항성 개선 연구)

  • Kim, Ji Yeon;Min, Mun Hong;Yeum, Jeong Hyun
    • Textile Coloration and Finishing
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    • v.25 no.3
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    • pp.215-222
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    • 2013
  • The purpose of this study is to minimize fading fabrics of surgical gown by repeated severe laundering and sterilization condition. The study showed that the best conditions were reduction cleaning using sulphinic acid derivatives or glucose organic chemicals at $98^{\circ}C$ alkaline solutions. In these conditions, color difference values(dE) were below 1.0 that means unrecognizable color change by repeated laundering and sterilization. If it treated with only laundering, reduction cleaning conditions may adjust over $80^{\circ}C$ alkaline solution. In conclusion, it is needed to select the high-washing fastness dye and reduction cleaning using sulphinic acid derivatives or glucose organic chemicals at $98^{\circ}C$ alkaline solutions for removal unfixed dyes.

The Environmental Effects of Agrochemical and Fertilizer Applied in Golf Courses in Korea (국내 골프 코스에서 시용되는 농약 및 비료의 환경적 영향)

  • 이상재;허근영;사공영보
    • Asian Journal of Turfgrass Science
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    • v.15 no.2
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    • pp.87-104
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    • 2001
  • This Study was carried out to investigate on the environmental effects of golf courses and to find a solution to the negative effects in Korea. The results were ai follows. 1. There were 152 golf courses opened in December 2000. 113 golf courses were member-ship and 39 golf courses were public. Users (golfer) were over 12,000,000 in 2000. 2. Total area of golf courses was 0.8% as compared with total area of farmland in 1999. Total amount of agricultural chemicals used in golf courses was 0.3% of total amount of agricultural chemicals used in Korea. The remaining amount of agricultural chemicals in golf courses tested were almost below the permitted limits. 3. Recently, total amount of fertilizers in green decreased 5~7g/$m^2$/year as compared with the recommended. 4. The control by antagonistic microorganisms and the fertilizing of the organic matter or the organic fertilizer were effective to decrease the amount of agricultural chemicals used. To success the control of microorganisms, active antagonistic microorganisms had to be applied over the recommended dose eve교day. Though fertilizing of organic fertilizer, slow release fertilizer, was effective to suppress dollar spot, necrotic ring spot. fungicides were required as a supplementary means when disease symptom was very heavy. 5. Zoysiagrass was fertilized intensively from May to August. Cool-season grasses were fertilized intensively from March to May and September to October. The fall fertilizing of Zoysiagrass was carried out to the begining of October. The fall fertilizing of cool-season grasses were carried out to the end of November or the begining of December. The fertilizing amount of Zoysiagrass was 10g/$m^2$/year. The fertilizing amount of bentgrass was 25~27g/$m^2$/year.

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Selection of Candidate Materials and their Prioritization for Chronic Inhalation and Carcinogenicity Test (흡입노출에 의한 만성·발암성시험 대상물질 및 우선순위 선정 연구)

  • Rim, Kyung-Taek;Lim, Cheol-Hong;Ahn, Byung-Joon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.4
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    • pp.587-612
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    • 2014
  • Objectives: There is requirement to select candidate materials for chronic inhalation/carcinogenicity testing, so we would like to set the priority of candidate materials. Methods and Results: We recommend the priorities for candidate materials based on the chemicals stipulated in the Occupational Safety and Health Act(OSHAct) and the Toxic Chemicals Control Act(TCCA) in Korea. Conclusions: We presented candidate chemicals consisting of solids(powders), gases and liquids(Such as organic solvents) with priorities.

Potential Application of Environmental Tracer in Hydrogeochemistry Using Sorption Properties (환경 추적자의 흡착 특성을 이용한 수리지화학적 활용 가능성 고찰)

  • Choung, Sungwook;Chang, Seeun;Kim, Minkyung;Kim, Sungpyo;Um, Wooyong
    • Journal of Soil and Groundwater Environment
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    • v.17 no.6
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    • pp.59-68
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    • 2012
  • This study provided sorption properties of chlorofluorocarbons (CFCs), and elucidated potential application of CFC sorption data in hydrogeochemistry. Prior sorption studies were reviewed for hydrophobic organic compounds similar to the CFCs, because there were only few CFC sorption studies. The CFCs are regarded as relatively conservative chemicals in groundwater environments based on their moderate hydrophobicity. However, thermally altered carbonaceous matter (TACM) can significantly increase sorption capacity and nonlinearity for hydrophobic organic compounds such as CFCs, compared to general soil organic matter. CFC sorption behavior are close to the sorption for reviewed organic chemicals. Therefore, the CFC sorption data can be used for determining hydrogeochemical properties and predicting transport of organic contaminants in TACM-containing aquifer environments.