• Title/Summary/Keyword: Organic binder

Search Result 213, Processing Time 0.024 seconds

Effect of Organic Additive Composition on Isostatic Thermocompression Behavior of Alumina Tapes (유기물 조성에 따른 알루미나 테이프의 열간 가압 거동)

  • 이명현;박일석;김대준;이득용
    • Journal of the Korean Ceramic Society
    • /
    • v.37 no.8
    • /
    • pp.824-831
    • /
    • 2000
  • Alumina tapes, having various ratios of alumina to alumina+binder+plasticizer (a/(a+o)) and binder to binder+plasticizer(b/(b+p)), were prepared by the tape casting method. The tapes were thermocompressed varying the thermocompression parameters such as temperature, pressure, and duration time. Among the parameters, the pressure was the most influential to the tape packing density. The packing density varied in two different ways depending on the a/(a+o) ratio. For the tapes having low a/(a+o) ratio, a saturation density was reached by applying very a low pressure of 1 MPa. For tapes with high a/(a+o), on the contrary, the saturation density was obtained at a relatively high pressure. These different responses to the pressure are attributed to the fact that the rearrangement of alumina particles by the pressure becomes easy as an organic content in the tapes is high.

  • PDF

Basic Properties of Waste Wood-Plastic Composite Panels by Hot Press Molding Method (열압 성형법에 의한 폐목재-플라스틱 복합패널의 기초적 성질)

  • Choi, Nak-Woon;Mun, Kyoung-Ju;Choi, San-Ho
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.12 no.4
    • /
    • pp.95-104
    • /
    • 2004
  • A styrene solution of waste expanded polystyrene with a crosslinking agent and an initiator was used as a binder for waste wood-plastic composite panels. The waste wood-plastic composite panels are prepared with various binder contents and filler-binder ratios by using a hot press molding method. The apparent density of the composite panels is increased with increasing binder content and filler-binder ratio, while their water absorption and expansion in thickness are decreased with increasing binder content and filler-binder ratio. The maximum flexural strength and wet flexural strength of the composite panels are obtained at a binder content of 35% and a filler-binder ratio of 0.8. Decreases in the flexural strengths of the composite panels due to water immersion at 20 and $100^{\circ}C$ are hardly recognized at binder contents of 30% or more.

  • PDF

Analysis of Optical Properties with Photopolymers for Holographic Application

  • Kim Nam;Hwang Eun-Seop;Shin Chang-Won
    • Journal of the Optical Society of Korea
    • /
    • v.10 no.1
    • /
    • pp.1-10
    • /
    • 2006
  • Optical transparency and high diffraction efficiency are two essential factors for high performance of the photopolymer. Optical transparency mainly depends on the miscibility between polymer binder and photopolymerized polymer, while diffraction efficiency depends on the refractive index modulation between polymer binder and photopolymerized polymer. For most of organic materials, the large refractive index difference between two polymers accompanies large structural difference that leads to the poor miscibility and thus poor optical quality via light scattering. Therefore, it is difficult to design a high-performance photopolymer satisfying both requirements. In this work, first, we prepared a new phase-stable photopolymer (PMMA) with large refractive index modulation and investigated the optical properties. Our photopolymer is based on modified poly (methyl methacrylate) as a polymer binder, acryl amide as a photopolymerizable monomer, triethanolamine as initiator, and yellow eosin as a photosensitizer at 532 nm. Diffraction efficiency over 85% and optical transmittance over 90% were obtained for the photopolymer. Second, Organic-inorganic nanocomposite films were prepared by dispersing an aromatic methacrylic monomer and a photo- initiator in organic-inorganic hybrid sol-gel matrices. The film properties could be controlled by optimizing the content of an organically modified silica precursor (TSPEG) in the sol-gel matrices. The photopolymer film modified with the organic chain (TSPEG) showed high diffraction efficiency (> 90%) under an optimized condition. High diffraction efficiency could be ascribed to the fast diffusion and efficient polymerization of monomers under interference light to generate refractive index modulation. The TSPEG modified photopolymer film could be successfully used for holographic memory.

Influence of the Binder Types on the Electrochemical Characteristics of Si-C Composites Electrode in LIBs (Si-C 복합체 전극의 바인더 종류에 따른 전기화학적 특성 변화)

  • Jung, Sung-Hun;Ji, Mijung;Park, Geunyeong;Hong, Jongill;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
    • /
    • v.50 no.2
    • /
    • pp.168-172
    • /
    • 2013
  • This work presents the effects of binders on the electrochemical performance of Si-C composites as the anode of lithium ion batteries. PAI (polyamide-imide) was used as an organic binder, and PAN (polyacrylonitrile), PAA (polyacrylic acid) and CMC + SBR (carboxymethyl cellulose + styrene-butadiene rubber) were used as aqueous binders. As a result, stabilization time for the cell with a Si-C composite anode synthesized using aqueous binders became shorter than an organic binder. Particularly in the case of the cell using PAA binder, better performance was observed in terms of adhesion strength, initial efficiency, the volume expansion ratio, Coulombic efficiency, and capacity retention.

Effects of Binder on the Mechanical Properties of Preform and MMCs (예비성형체 및 금속복합재료에 미치는 바인더의 영향에 관한 연구)

  • Nam, Hyun-Wook;Min, Byung-Ryoul;Lee, Jong-Hae;Han, Kyung-Seop
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.23 no.6 s.165
    • /
    • pp.952-960
    • /
    • 1999
  • The effects of binder on the mechanical properties of the preforms and metal matrix composites (MMCs) were studied. Fibers were $9Al_2O_3{\cdot}2B_2O_3(Alborex)$, HTZ and $Al_2O_3$ fibers(Saffil) and binders were organic binder, inorganic binder, polyacrylamide under various PH conditions. Compressive strength of the preform increased with the addition of inorganic binder. The polyacrylamide did not improve the permeability of the preforms. PH of the slurry should be controlled because it affects the viscosity of the slurry. Good preforms were obtained under following conditions : 3 wt% inorganic binder, 0.1 wt% organic binder, 0.1 wt% polyacrylamide and PH 9. Tensile tests of MMCs were conducted at $20^{\circ}C,\;150^{\circ}C,\;250^{\circ}C,\;350^{\circ}C$ using MTS(100KN USA). Wear tests were conducted under various sliding speeds. High temperature($250^{\circ}C$) tensile strengths of Alborex/Saffil/AC8A and HTZ/AC8A are 80% and 75% of the room temperature tensile strengths respectively. The tensile and wear properties of the Alborex/Saffil/AC8A are superior to that of the HTZ/AC8A. The wear behavior of HTZ/AC8A shows more orthotropic characteristic than that of Alborex/Saffil/AC8A.

Effect of $BaTiO_3$ Dispersion on the Properties of Cast Tapes in Processing of Multilayer Ceramic Capacitor(MLCC) (적층 세라믹콘덴서 제조공정에서 $BaTiO_3$의 분산이 테이프캐스팅 성형체의 물성에 미치는 영향)

  • 김봉호;김병관;김명호;백운규
    • Journal of the Korean Ceramic Society
    • /
    • v.33 no.2
    • /
    • pp.214-222
    • /
    • 1996
  • The effect of physicochemical properties of organic solvent and dispersant among organic solvent dispersant binder and plasticizer which are used as processing additives in MLCC fabrication process on the dispersion of BaTiO3 was studied. The steric and electrostatic stabilization mechanisms in dispersion of BaTiO3 in organic media were evaluated respectively. The sttability of BaTiO3 achieved bysteric stabilization was dependent on the fraction of surface coverage of dispersant adsorption on BaTiO3. The electrostatic repulsive forces of BaTiO3 particles dispersed in orgainc media was found to be appreciabley great and dependent mainly on the kinds of organic solvent used. The mechanism affecting the stability of BaTiO3 was studied by the method of rheologi-cal behaviors of BaTiO3 suspension.

  • PDF

Fabrication and Evaluation of a Total Organic Carbon Analyzer Using Photocatalysis

  • Do Yeon Lee;Jeong Hee Shin;Jong-Hoo Paik
    • Journal of Sensor Science and Technology
    • /
    • v.32 no.3
    • /
    • pp.140-146
    • /
    • 2023
  • Water quality is crucial for human health and the environment. Accurate measurement of the quantity of organic carbon in water is essential for water quality evaluation, identification of water pollution sources, and appropriate implementation of water treatment measures. Total organic carbon (TOC) analysis is an important tool for this purpose. Although other methods, such as chemical oxygen demand (COD) and biochemical oxygen demand (BOD) are also used to measure organic carbon in water, they have limitations that make TOC analysis a more favorable option in certain situations. For example, COD requires the use of toxic chemicals, and BOD is time-consuming and can produce inconsistent and unreliable results. In contrast, TOC analysis is rapid and reliable, providing accurate measurements of organic carbon content in water. However, common methods for TOC analysis can be complex and energy-intensive because of the use of high-temperature heaters for liquid-to-gas phase transitions and the use of acid, which present safety risks. This study focuses on a TOC analysis method using TiO2 photocatalysis, which has several advantages over conventional TOC analysis methods, including its low cost and easy maintenance. For TiO2, rutile and anatase powders are mixed with an inorganic binder and spray-coated onto a glass fiber substrate. The TiO2 powder and inorganic binder solutions are adjusted to optimize the photocatalytic reaction performance. The TiO2 photocatalysis method is a simple and low-power approach to TOC analysis, making it a promising alternative to commonly used TOC analysis methods. This study aims to contribute to the development of more efficient and cost-effective approaches for water quality analysis and management by exploring the effectiveness and reliability of the developed equipment.

Characteristics of CIGS film fabricated by non-vacuum process (비 진공으로 제작한 CIGS 박막 특성)

  • Park, Myoung-Guk;Ahn, Se-Jin;Yoon, Jea-Ho;Gwak, Ji-Hye;Kim, Dong-Hwan;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2009.06a
    • /
    • pp.19-22
    • /
    • 2009
  • A non-vacuum process for fabrication of $CuIn_xGa_{1-x}Se_2$ (CIGS) absorber layer from the corresponing Cu, In, Ga solution precursors was described. Cu, In, Ga precursor solution was prepared by a room temperature colloidal route by reacting the starting materials $Cu(NO_3)_2$, $InCl_3$, $Ga(NO_3)$ and methanol. The Cu, In, Ga precursor solution was mixed with ethylcellulose as organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of Cu, In, Ga solution with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents and to burn the organic binder material. Subsequently, the resultant CIG/Mo/glass sample was selenized in Se evaporation in order to get a solar cell applicable dense CIGS absorber layer. The CIGS absorber layer selenized at $530^{\circ}C$ substrate temperature for 1h with various metal organic ratio.

  • PDF

Fabrication of CIGS Thin Film Solar Cell by Non-Vacuum Nanoparticle Deposition Technique (비진공 나노입자 코팅법을 이용한 CIGS 박막 태양전지 제조)

  • Ahn, Se-Jin;Kim, Ki-Hyun;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2006.06a
    • /
    • pp.222-224
    • /
    • 2006
  • A non-vacuum process for $Cu(In,Ga)Se_2$ (CIGS) thin film solar cells from nanoparticle precursors was described in this work CIGS nanoparticle precursors was prepared by a low temperature colloidal route by reacting the starting materials $(CuI,\;InI_3,\;GaI_3\;and\;Na_2Se)$ in organic solvents, by which fine CIGS nanoparticles of about 20nm in diameter were obtained. The nanoparticle precursors were mixed with organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of CIGS with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents ud to burn the organic binder material. Subsequently, the resultant (porous) CIGS/Mo/glass simple was selenized in a two-zone Rapid Thermal Process (RTP) furnace in order to get a solar ceil applicable dense CIGS absorber layer. Complete solar cell structure was obtained by depositing. The other layers including CdS buffer layer, ZnO window layer and Al electrodes by conventional methods. The resultant solar cell showed a conversion efficiency of 0.5%.

  • PDF