• Bulletin of the Korean Chemical Society
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• 제30권2호
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• pp.319-322
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• 2009

Gel polymer electrolytes were prepared by immersing a porous poly(vinylidene fluoride-co-hexafluoropropylene) membrane in an electrolyte solution containing small amounts of polymerizable additive (3,4-ethylenedioxythiophene, thiophene, biphenyl). The organic additives were electrochemically oxidized to form conductive polymer films on the electrode at high potential. With the gel polymer electrolytes containing different organic additive, lithium-ion polymer cells composed of carbon anode and LiCo$O_2$ cathode were assembled and their cycling performances were evaluated. Adding small amounts of thiophene or 3,4-ethylenedioxythiophene to the gel polymer electrolyte was found to reduce the charge transfer resistance in the cell and it thus exhibited less capacity fading and better high rate performance.

• 한국자기학회지
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• 제15권3호
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• pp.198-201
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• 2005

전기도금 방법으로 제작된 니켈과 니켈-구리 합금박막에 미치는 유기첨가제(organic additive)의 영향을 조사하였다. 유기첨가제를 가하여 도금하는 니켈 박막의 경우 순수한 전해액만을 이용하여 도금한 박막과는 다른 결정성을 갖는다 도금조건을 일정하게 한 후 니켈-구리의 합금 박막용 전해액에 유기첨가제를 가하면 구리와 니켈의 조성비율이 변화하는데 유기첨가제의 성분과 농도에 따라 니켈의 함유율이 $65\~95\%$ 영역에서 조절이 가능하다. 유기첨가제에 의한 이러한 물성의 변화는 자성의 변화를 유도하여 도금 박막의 자기저항의 증가와 감소에도 기여하는 것으로 나타났다.

• 전기화학회지
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• 제20권1호
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• pp.13-17
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• 2017

본 연구에서는 고전압용 전기화학 커패시터에 응용을 위한 유기 전해액 개발에 관한 연구를 실시하였다. 사용한 기준 전해액으로는 1M의 $SBPBF_4$염이 포함된 EC:DMC(1:1) 복합 전해액을 사용하였으며, 고전압 안정성을 위해 기준 전해액에 첨가제 GBL을 5 wt.% 첨가했다. 0-3.5 V 전압 범위에서 초기 250 사이클까지의 효율이 약 2.5배 향상된 것을 확인할 수 있었으며, 2000 사이클 이후에는 약 3배 이상의 커패시턴스 효율이 유지되는 것을 확인하였다. 고전압에서 GBL이 전해액 보다 먼저 분해를 일으켜 전해액이 분해되는 현상을 억제하며 안정성을 향상시키는 효과가 있는 것으로 판단된다. 또한 분해된 GBL이 전극 표면에 흡착하여 안정한 SEI 층을 형성해줌으로서, 전극 표면을 보호하여 전해질과의 부반응을 억제해주는 역할을 하는 것으로 판단된다.

• Carbon letters
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• 제16권1호
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• pp.51-56
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• 2015

Carbonate-type organic electrolytes were prepared using propylene carbonate (PC) and dimethyl carbonate (DMC) as a solvent, quaternary ammonium salts, and by adding different contents of 1-ethyl-3-methyl imidazolium tetrafluoroborate ($EMImBF_4$). Cyclic voltammetry and linear sweep voltammetry were performed to analyze conducting behaviors. The surface characterizations were analyzed by scanning electron microscopy method and X-ray photoelectron spectroscopy. From the experimental results, increasing the $EMImBF_4$ content increased the ionic conductivity and reduced bulk resistance and interfacial resistance. In particular, after adding 15 vol% $EMImBF_4$ in 0.2 M $SBPBF_4$ PC/DMC electrolyte, the organic electrolyte showed superior capacitance and interfacial resistance. However, when $EMImBF_4$ content exceeded 15 vol%, the capacitance was saturated and the voltage range decreased.

• Tribology and Lubricants
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• 제19권3호
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• pp.159-166
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• 2003

This research for replacement of chlorine or sulfur based EP(extreme pressure) -additives which is restricted materials by environmental regulation. The subject of this study is as follows, 4-ball test and friction coefficient test were experimented in accordance with temperature and velocity, compounding with several organic or inorganic metallic elements. After 4-ball test, wear area of steel ball was analysed by SEM-EDX. As the analysis, organic and inorganic elements make a effect for extreme pressure lubricity. It is shown that the friction coefficient of lubricant which includes chlorine or sulfur additives, the scoring phenomenon is found accord-ing to temperature and the scuffing phenomenon at 200$^{\circ}C$. Applying to Na, P, S, Zn, Ca based on inorganic and organic elements, the result showed that friction coefficient is decreased more and more, as increasing temperature of lubricant. The additive based on S, Cl, P elements is effect far extreme pressure in the sample#1 and Na, P, S, Zn, Ca in sample #2. These elements are environmental contaminants and S, Cl based on EP additives which are very popular in domestic industry, when they are properly composed with non-chlorine based on additives and Na, P, S, Zn, Ca organic or inorganic elements. It is showed that lubricity and excellent anti-wear properties.

• 한국유기농업학회지
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• 제24권4호
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• pp.869-879
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• 2016

The present study was conducted to evaluate the effects of dietary formulated feed additive on growth performance and carcass traits of Hanwoo steers. A formulated feed additive reported to reduce heat load in the rumen in our previous research was used (Cho et al., 2014). Total 32 herds of Hanwoo steers were assigned into two groups of control and treatment. Total mixed ration was provided as basal diet for cattle and 100 g of additive was supplemented on diet for treatment. Feeding trial was performed during 120 days before slaughter. For growth performance, 3 periods (0~90 days; 90~120 days; 0~120 days) were allotted and average daily gain, feed requirement and final body weight were determined. Loin meat between $12^{th}$ and $13^{th}$ rib was used for meat quality analysis after slaughtering. Only $1^{st}$ period showed significantly improved growth performance of treatment (P<0.05) and there were no significant difference in other periods. At $3^{rd}$ periods (overall), a trend of increased average daily gain was found at treatment (P=0.075). Carcass performance and quality did not show significant differences between treatment and control (P>0.05). In meat quality, treatment showed significant increment in all measured meat colors (P<0.05) and significantly less sharing force compared to the control (P<0.05). Although no significant difference in growth performance and carcass yield were found, remarkably improved economic status was detected in treatment group. In conclusion, it could be suggested that application of a formulated feed additive specialized in reduction of heat load in the rumen was able to increase economical balance through enhancing heat stress condition of ruminant and growth.

• 대한화학회지
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• 제48권4호
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• pp.443-446
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• 2004

• Bulletin of the Korean Chemical Society
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• 제35권9호
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• pp.2825-2827
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• 2014

• 한국산업안전학회:학술대회논문집
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• 한국안전학회 2001년도 공동학술대회
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• pp.303-308
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• 2001

Various organic solvents are most commonly using material in various factories, for examples, paint producting process and other industries, actually most of them are toxic materials, If many kinds of organic chemicals are concurrently exposed to workplace, toxidities can be influenced as additive effect or synergistic effect.(omitted)

• 한국자기학회지
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• 제17권3호
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• pp.133-136
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• 2007

퍼말로이 도금용 순수전해액에 유기첨가제(organic additive)를 첨가하여 제작된 박막의 물성과 자성의 변화를 조사하였다. 일정한 도금조건에서 특정한 유기첨가제를 첨가하여 도금한 퍼말로이 박막은 순수한 전해액으로만 제작된 박막과는 결정성과 표면 거칠기가 달라진다. 그 결과로 도금 박막의 보자력 등 자기적 특성이 변화하였다. 유기첨가제에 의한 이러한 특성 변화는 자기임피던스 비율을 최대 20%까지 증가시키는 역할을 하였다.