• Title/Summary/Keyword: Organic acid material

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A Comparison to Electrical properties of Fatty Acid System LB Films in Horizontal Direction (포화지방산계 LB막의 수평방향에 대한 전기적 특성 비교)

  • 김도균;최용성;장정수;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.194-197
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    • 1997
  • The LB technique is one of the most powerful fabricating methods of organic ultra-thin film, which deposits a monolayer films in molecular level on the surface of the substrate. We have investigated the electrical characteristics of Myristic acid, Stearic acid and Arachidic acid LB films for horizontal direction to develop for the gas sensor. The optimum conditions for a film deposition were obtained by measurement of $\pi$-A isotherm. The status of the deposited film was confirmed by measurement of UV absorbance. We could distingished the difference of I-V characteristics for the fatty acid for the horizontal direction. The conductivity of fatty acid LB films for horizontal direction was 10$^{-7}$ ~ 10$^{-9}$ [S/cm] that mean like semiconductor.

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A Study on Semi Abrasive Free Slurry including Acid Colloidal Silica for Copper Chemical Mechanical Planarization (구리 CMP 적용을 위한 산성 콜로이드 실리카를 포함한 준무연마제 슬러리 연구)

  • 김남훈;김상용;서용진;김태형;장의구
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.3
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    • pp.272-277
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    • 2004
  • The primary aim of this study is to investigate new semi-abrasive free slurry including acid colloidal silica and hydrogen peroxide for copper chemical-mechanical planarization (CMP). In general, slurry for copper CMP consists of colloidal silica as an abrasive, organic acid as a complex-forming agent, hydrogen peroxide as an oxidizing agent, a film forming agent, a pH control agent and several additives. We developed new semi-abrasive free slurry (SAFS) including below 0.5% acid colloidal silica. We evaluated additives as stabilizers for hydrogen peroxide as well as accelerators in tantalum nitride CMP process. We also estimated dispersion stability and Zeta potential of the acid colloidal silica with additives. The extent of enhancement in tantalum nitride CMP was verified through anelectrochemical test. This approach may be useful for the application of single and first step copper CMP slurry with one package system.

Solution-processed Organic Trilayer Solar Cells Incorporating Conjugated Polyelectrolytes

  • Cha, Myoung Joo;Walker, Bright;Seo, Jung Hwa
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.192.1-192.1
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    • 2014
  • We report solution-processed organic trilayer solar cells consisting of poly (3-hexylthiophene) (P3HT), a conjugated polyelectrolyte (CPE) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM), wherein the effect CPE layer thickness on device properties was investigated. The current-voltage characteristics under illumination and dark as well as photoluminescence were characterized using various concentrations (0.02, 0.1, and 0.3wt%) of to deposit the CPE interlayer between the donor and acceptor layers. We also investigated the influence of molecular dipole moments in the trilayer solar cells by external stimuli. These results provide an experimental approach for investigating the influence of interfacial dipoles on solar cell parameters when placed between the donor and acceptor and allow us to obtaining fundamental information about the donor/acceptor interface in organic solar cells.

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Selection of organic Nitrogen Source and Optimization of Culture Conditions for the Production of Arachidonic Acid from Mortierella alpina (Mortierella alpina를 이용한 아라키돈산의 생산에서 유기질소원의 선정과 배양 조건의 최적화)

  • 유연우;하석진;박장서
    • KSBB Journal
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    • v.19 no.1
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    • pp.78-82
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    • 2004
  • Experiments were carried out to select an organic nitrogen source and optimize the culture conditions for the production of arachidonic acid by Mortierella alpina DSA-12. Corn steep powder(CSP) was selected as an organic nitrogen source based on arachidonic acid production and raw material price. The optimum C/N ratio was in the range of 15 to 17 with the medium containing glucose as carbon source and CSP as nitrogen source. The optimum culture conditions for arachidonic acid production showed 500 rpm agitation and 25$^{\circ}C$ culture temperature at 0.5 vvm aeration. Under the optimum conditions, the concentration of cell, total lipid and arachidonic acid were 21.8 g/L, 10.2 g/L and 3.70 g/L, respectively, from 50 g/L glucose and 18 g/L CSP. In the 500 L fermenter with 0.5 vvm aeration and 200 rpm agitation, the concentration of cell, total lipid and arachidonic acid were 19.8 g/L, 9.1 g/L and 3.67 g/L, respectively, from 50 g/L glucose and 18 g/L CSP. This result showed that an arachidonic acid production could be possible with a bench-scale fermenter using corn steep powder as a nitrogen source.

Nutritional Components and Antioxidant Activities of Various Stachys Sieboldii Miq Parts (초석잠 부위별 영양성분 및 항산화효과)

  • Kim, Yeon-Kyoung;Son, Hee-Kyoung;Lee, Jae-Joon
    • The Korean Journal of Community Living Science
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    • v.28 no.2
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    • pp.203-215
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    • 2017
  • This study was carried out to compare the major nutrient components and antioxidant activities of Stachys sieboldii Miq leaf and root powders. For proximate compositions, crude protein and crude fat contents of leaf powder were higher than those of root powder, whereas contents of crude ash and carbohydrates were lower in leaf powder. The content of glutamic acid was greater in amino acids of leaf and root powders, and contents of total amino acids and essential amino acids were higher in leaf powder compared with root powder. Root powder contained a higher level of total unsaturated fatty acids than leaf powder. Total contents of organic acids were higher in leaf powder; tartaric acid was the major organic acid in leaf powder, and malic acid was the major organic acid in root powder. The content of vitamin A was higher in leaf powder than in root powder. However, vitamin E content was higher in root powder than in leaf powder. Total mineral contents of leaf powder were higher than those of root powder, and mineral contents of leaf and root powders were in the order of K>Ca>Mg. Extract yields of leaf and root powders were 27.21% and 58.51%, respectively. Total polyphenols and total flavonoids of leaf extract were 236.35 mg/g and 1.90 mg/g, respectively, which were higher than those of root extract. The $IC_{50}$ values of leaf and root ethanol extracts based on DPPH hydroxyl scavenging were 0.69 mg/mL and 5934.31 mg/mL, respectively, and antioxidative activities of ethanol extracts from all Stachys sieboldii Miq parts dose-dependently increased. These results suggest that Stachys sieboldii Miq can be recommended as an edible functional food material.

Leaching of Cobalt and Nickel from Metallic Mixtures by Inorganic and Organic Acid Solutions (코발트와 니켈 금속혼합물로부터 무기산 및 유기산에 의한 침출)

  • Moon, Hyun Seung;Song, Si Jeong;Tran, Thanh Tuan;Lee, Man Seung
    • Resources Recycling
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    • v.30 no.2
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    • pp.53-60
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    • 2021
  • Leaching experiments from single metal and metallic mixtures were conducted to develop a process for the recovery of cobalt, copper, and nickel in spent lithium ion batteries. Inorganic and organic acid solutions without oxidizing agents were employed. No copper was dissolved in the absence of an oxidizing agent in the leaching solutions. The leaching condition to completely dissolve single metal of cobalt and nickel was determined based on acid concentration, reaction temperature and time, and pulp density. The leaching condition to dissolve all of cobalt and nickel from the metallic mixtures was also obtained. Leaching of the metallic mixture with methanesulfonic acid led to selective dissolution of cobalt at low temperatures.

Stimulus transfer properties of Au/Arac. acid/Al structure (Au/Arac. acid/Al 구조의 자격전달특성)

  • 송진원;최영일;이경섭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.491-494
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    • 1999
  • We have examined the electrical properties of arachidic acid Langmuir (L) films by using a displacement current measuring technique with pressure stimulation. We give pressure stimulation into organic thin films and detect the Induced displacement current. The structure of manufactured device is Au/arachidic acid/Al, the number of accumulated layers are 17, 19 and 21. Also, we then examined of the MIM device by means of I-V The I-V characteristic of the device is measured from 0 to +1[V]. The insulation property of a thin film is better as the distance between electrodes is larger.

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Effects of the Organic Fatty Acid Salts on the Watertightness Properties of the Cementitious Materials (시멘트 재료의 수밀특성에 미치는 유기 지방산 염의 영향)

  • Na, Seung-Hyun;Kang, Hyun-Ju;Ahn, Kwang-Hoon;Song, Myong-Shin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.529-532
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    • 2008
  • The durability of concrete and the water-tightness properties of cementitous material are closely relation. So, water-tightness materials as natural minerals, organic fatty acid, organic fatty salts inorganic materials use for improvement of concrete durability. But these materials are somehow different in water-tightness mechanism. In this study, we studied on hydration properties and water-tightness properties of cementitous materials with zinc-stearate, a kind of organic fatty acid salts.

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Development of an Oraganic-Inorganic Hybrid Coating Solution for Improvement in Flame Retardant Properties of Wallpapers (벽지의 방염특성을 개선하기 위한 유-무기 하이브리드 코팅 용액 개발)

  • Jeong, Gyu Jin;Kang, Tae Wook;Kim, Jin Ho;Kim, Bong Man;Seo, Eun Kyung;Bae, Byungseo;Kim, Sun Woog
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.2
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    • pp.178-183
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    • 2022
  • For enhancing the flame-retardant properties of wallpapers, we developed an organic-inorganic hybrid solution with ZrSiO4 as a functional ceramic powder, coated on non-woven fabric using dip coating, spray coating, and slot-die coating methods. Their flame retardant properties were characterized by a 45° combustion tester, which is manufactured according to the flame-retardant performance standard (KOFEIS 1001 and KS F 2819). In organic-inorganic hybrid solution, with increasing the concentration of acid-catalyst (acetic acid), the precipitation of ZrSiO4 powders increased, and the flame retardant properties decreased. The highest flame retardant result was obtained for the solution adding 5 wt% acetic acid. The optimization of the coating method and coating number resulted in the most excellent flame-retardant properties being obtained for the non-woven fabric coated for 5 or 7 times by dip coating method, and their flame-retardant properties corresponded to class 2 flame-retardant performance of wallpapers.

A study of dissolving treatment of covered material on metal surface (금속표면 피복물질의 분해처리에 관한 연구)

  • Lee, Cheal-Gyu;Kim, Moon-Chan
    • Analytical Science and Technology
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    • v.18 no.2
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    • pp.112-119
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    • 2005
  • This study reports on the efficiency of cleaning enameled magnet wire using a sulfuric acid $H_2SO_4$ and removal of dissolved organic material using hydrogen peroxide $H_2O_2$ and nitric acid $HNO_3$ at $80^{\circ}C$. The method involves the addition of pure $H_2SO_4$ and $H_2O_2$ or $HNO_3$. Layers of enameled organic material were dissolved by 90% $H_2SO_4$ and the solution was maintained as 35% $H_2O_2$ or 60% $HNO_3$. $H_2O_2$ content in aqueous $H_2O_2$ was maintained as 8.8 : 1.0. An initial concentration of $H_2SO_4$ in dissolution conditions was accomplished within 15 min, with a stripping time of about 2 h. The concentrations of $H_2O_2$ and $HNO_3$ in the processing bath were relatively low, but sufficient enough to produce an effective amount of power in the bath for the removal of the enamel material. The cleaning effect of enameled organic material involves the dehydration by $H_2SO_4$ and the oxidation by $H_2O_2$ or $HNO_3$.