• Title/Summary/Keyword: Organic EL

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Systematic Approaches for Blue Light-emitting Polymers by Introducing Various Naphthalene Linkages into Carbazole Containing PPV Derivatives

  • Ahn, Taek
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.5
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    • pp.258-262
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    • 2013
  • Poly(2,3-naphthalenevinylene-alt-N-ethylhexyl-3,6-carbazolevinylene), 2,3-PNCPV, poly(2,6-naphthalene vinylenealt- N-ethylhexyl-3,6-carbazolevinylene), 2,6-PNCPV, and poly(1,4-naphthalenevinylene-alt-N-ethylhexyl-3,6- carbazolevinylene), 1,4-PNCPV were synthesized through the Wittig polycondensation reaction. The conjugation lengths of the polymers were controlled by differently linked naphthalenes in the polymer main chain. The resulting polymers were completely soluble in common organic solvents, and exhibited good thermal stability at up to $400^{\circ}C$. The synthesized polymers showed UV-visible absorbance and photoluminescence (PL) in the ranges of 357-374 nm and 487-538 nm, respectively. The carbazole and 2,3-linked naphthalene containing 2,3-PNCPV showed a blue PL peak at 487 nm. A single-layer light-emitting diode was fabricated with an ITO/polymer/Al configuration. The electroluminescence (EL) emission of 2,3-PNCPV was shown at 483 nm.

Improved EL efficiency and operational lifetime of top-emitting white OLED with a co-doping technology

  • Lee, Meng-Ting;Tseng, Mei-Rurng
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1411-1414
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    • 2007
  • We have developed a top-emitting white organic electroluminescent device (TWOLED) incorporating a low-reflectivity molybdenum (Mo) anode and doped transport layers as well as a dual-layer architecture of doped blue and yellow emitters with the same blue host. The EL efficiency and operational lifetime of TWOLED can be enhanced by a factor of 1.2 and 3.4 than that of standard TWOLED, respectively, with a co-doping technology in yellow emitter by doping another blue dopant. The enhancement in device performances can be attributed to improve the energy transfer efficiency from blue host to yellow dopant through a blue dopant as medium in yellow emitter.

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Study of White Light Emission with Three or Two color in Multi Organic Emitting Layers with DCJTB, DPVBi and Coumarin6

  • Yoo, Seok-Jun;Lee, Chan-Jae;Kim, Dong-Won;Han, Jeong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1433-1436
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    • 2007
  • Using a blue emitting DPVBi material and red dopant DCJTB, WOLEDs with and without green emitter C6 added in ETL or HTL have been fabricated. The chromaticity color index of WOLEDs without C6 depends strongly on the doping concentration. In addition, manipulating thickness of emitting layer is similar effect such as controlling weight concentration of dopant. While the white color of WOLEDs with C6 added in ETL or HTL depend on position of C6. WOLED of three colors added green dye have been shown turn-on voltage of 3.25V, and EL efficiency 3.05cd/A @9V, $8102\;cd/m^2$, CIE coordinates (0.30, 0.32).

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Blue Light Emitting Electroluminescence Diode (Coronene을 이용한 청색 유기전계 발광 소자의 개발)

  • Lim, Sung-Taek;Shin, Dong-Myung;Roh, Suk-Won
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1377-1378
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    • 1998
  • Blue light emitting electroluminescence(EL) diodes were fabricated utilizing Coronene and some organic materials. Coronene showed photoluminescence(PL) peak at 450nm in solution with high quantum efficiency. Multi layer system was applied to fabricate EL diode utilizing Coronene. The device showed didode-like applied voltage-current relationship. And blue light emitting was observed. The decay time of device was in a scale of some seconds. The trun-on voltage of device was about 9 V.

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Characteristics of Organic Light Emitting diodes with DCM derivatives (DCM-A 유도체를 이용한 유기 광전 변환 소자의 특성)

  • Mun, Soo-San;Lee, An-Sung;Han, Mi-Eun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.168-168
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    • 2010
  • DCM derivatives were newly synthesized. The OLEDs with a DCM-A as an emitting layer was fabricated and analyzed their opto-electrical properties. The structures of OLEDs were I) ITO/DCM-A/Al, II) ITO/-NPD/DCM-A/LiF/Al, and III) ITO/-NPD/DCM-A/Alq3/LiF/Al. The EL peak of the DCM-A shows the red emission in the range of 700 nm. The structure I) shows that 1050 nW/cm2 at 510 mA/cm2. The structure II) shows that takes the most excellent luminance about 39,000 nW/cm2 at 290 mA/cm2. The EL structure ill shows luminance about 13,000 nW/cm2 at 6 mA/cm2.

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Synthesis and Antihypertensive Activity of Certain Mannish Bases of 2- Ethoxycarbonylindoles and 5H-Pyridazino [4,5-b] indoles

  • El Gendy, Adel A.;El Banna, Hosny A.
    • Archives of Pharmacal Research
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    • v.24 no.1
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    • pp.21-26
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    • 2001
  • This manuscript reports the synthesis of two series of Mannich Bases 3-12 and 21-40 obtained respectively by the reaction of either 2- ethoxycarbonylindoles 1-2 or 5H-pyridazino [4,5-b]indoles 17-20 as a substrate with formalin and the appropriate $2^{\circ}C$amines under the suitable Mannich conditions. fourteen of the synthesized Mannich basese were screened as antihypetensive agents in normotensive anesthetized rats. The effect of compound 4 in normotensive anesthetized dogs was also studied.

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Various Color Long Life EL materials based on a new fused aromatic ring

  • Kojuji, Takeki;Iwakuma, Toshihiro;Arakane, Takashi;Hironaka, Yoshio;Fukuoka, Kenichi;Funahashi, Masakazu;Ikeda, Hidetsugu;Hosokawa, Chishio;Kusumoto, Tadashi
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.331-335
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    • 2002
  • Excellent organic electroluminescent materials are needed to realize color EL devices with high performance. We have succeeded in realizing bright and efficient devices with long lifetime in red and white color regions, based on a new fused aromatic ring derivative.

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Study on a large-size glass substrate handler for new generation OLED (차세대 유기 EL 디스플레이를 위한 기판 조작에 관한 연구)

  • Kim Soak-Han;Lee Dong-Eun;Kim Jun-Chul;Lee Eung-Ki
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.79-80
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    • 2006
  • In order to raise productivity of the OLED and realization of the OLED TV, it is required to improve the design of the board size glass panel. The large-size glass substrate has some difficulties regarding its deflection during handling operation due to its small thickness (0.7t) which is not even enough to stand its mass itself. This paper is demonstrating a new solution of this difficult through clamping and bending end condition, which helps to minimize the deflection of the glass substrate.

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Synthesis and Luminescent Properties of Blue Light Emitting Polymers Containing a 4,4' or 3,3'-Linked Biphenyl Unit

  • Ahn, Taek
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.6
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    • pp.317-321
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    • 2012
  • Poly[4,4'(3,3')-biphenylenevinylene-alt-2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene-vinylene], 4,4'(3,3')-PBPMEH-PPV, and poly[4,4'(3,3')-biphenylenevinylene-alt-N-ethylhexyl-3,6-carbazolevinylene], 4,4'(3,3')-PBPCAR-PPV, of varying effective conjugation lengths, were synthesized by the well-known Wittig condensation polymerization between the appropriate biphenyl diphosphonium salts and dialdehyde monomers such as carbazole or dialkoxyphenyl dialdehyde. The conjugation lengths of the polymers were controlled by biphenyl linkages (4,4' or 3,3'). The resulting polymers were highly soluble in common organic solvents and exhibited good thermal stability up to $300^{\circ}C$. The synthesized polymers showed UV-visible absorbance and photoluminescence (PL) in the ranges of 314-400 nm and 430-507 nm, respectively. Carbazole and 3,3'-biphenyl containing 3,3'-PBPCAR-PPV showed a blue PL peak at 430 nm. A single-layer light-emitting diode was fabricated in a configuration of ITO/polymer/Al. Electroluminescence (EL) emission of 3,3'-PBPCAR-PPV was shown at 455 nm.

Preparation and characterization of $Alq_3$/TPD EL devices ($Alq_3$/TPD EL소자의 제작과 그 특성에 관한 연구)

  • Chai, Su-Gil;Kim, Tae-Wan;Kang, Dou-Yol
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1469-1471
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    • 1997
  • In this study, Organic electroluminescent(EU devices with multilayer structures were fabricated using tris (8-hydroxy quinolinate) aluminum($Alq_3$) as an electron-tran sporting emitting layer and TPD(N,N'-diphenyl-N,N'-bis(3-methylphenyl)-[1,1'-biphenyl]-4,4'-diamine : aromatic diamine) as a hole-transporting layer. A cell with a structure of glass substrate/indium-tin-oxide(ITO)/$Alq_3$/TPD/Mg:In exhibited bright green electroluminescence from the TPD layer. The peak intensity of TPD and $Alq_3$ different from spin coating and vacuum evaporation. The peak emission energy shifts to a higher energy with deposition technique. An emission peak at 500nm was achieved at a driving voltage of 30V.

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