• Title/Summary/Keyword: Organic Copper (II) phthalocyanine

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Photocurrent Multiplication Process in OLEDs Due to a Crystalline of Hole Injection Layer of Copper(II)-phthalocyanine and a Light Irradiation (유기발광소자내 정공주입층 Copper(II)-phthalocyanine의 결정 및 광원에 따른 Photocurrent 증폭 연구)

  • 임은주;박미화;윤순일;이기진;차덕준;김진태
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.7
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    • pp.622-626
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    • 2003
  • We report the electrical properties of organic light emitting diodes (OLEDs) depending on the crystal structure of hole injection layer of copper(II)-phthalocyanine(CuPc) and the light irradiation the carrier mobility of copper(II)-phthalocyanine(CuPc) of light source. OLEDs were constructed with indium tin oxide(ITO)/CuPc/triphenyl-diamin(TPD)/tris-(8-hydroxyquinoline)aluminum(Alq$_3$)/Al.Photocurrent multiplication of OLEDs was varied by the heat-treatment condition of CuPc thin film and the light irradiation.

Characterization of thin film properties of Copper(II)-Phthalocyanine using a near-field scanning microwave microscope (근접장 마이크로파 현미경을 이용한 Copper(II)-phthalocyanine 박막의 특성 연구)

  • Park, Mie-Hwa;Lee, Kie-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.460-463
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    • 2003
  • We report the microwave reflection coefficient $S_{11}$ of copper(II)-phthalocyanine(CuPc) using a near-field microwave microscope(NSMM) in order to understand the intrinsic electromagnetic properties of organic materials. For a NSMM system, a high-quility microstip resonator coupled with a dielectric resonator was used. The reflection coefficient $S_{11}$ was changed by the preparation conditions of CuPc thin films. We compared the reflection coefficient with crystal phase, surface morphology, UV absorption spectra and x-ray diffraction results.

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Hole transport properties of organic EL devices using a copper(II)-phthalocyanine (Copper(II)-phthalocyanine을 이용한 유기 EL 소자의 정공 전송 특성)

  • 한우미;임은주;이정윤;김명식;이기진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.927-930
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    • 2001
  • We studied the electrical properties of Copper(II)-phthalocyanine (Cu-Pc) as a hole transport layer in organic light emitting devices (OLEDs). OLEDs were constructed with ITO/CU-Pc/triphenyl-diamine (TPD)/tris-(8-hydroxyquinoline) aluminum ( Alq$_3$) + 4- (Dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM)/Al. It was consisted of a thin DCM in Alq$_3$emission layer. We observed that the change of recombination zone was moved toward the cathode as the hole mobility increased due to the heat-treatment temperature of Cu-Pc layer increased.

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Study of space charge of metal/copper(II)-phthalocyanine interface (금속/copper(II)-phthalocyanine interface에서의 space charge 연구)

  • Park, Mie-Hwa;Lim, Eun-Ju;Yoo, Hyun-Jun;Lee, Kie-Jin;Cha, Deok-Joon;Lee, Young-San
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.526-530
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    • 2004
  • We report the space charge and the surface potential of the interface between metal and CuPc according to isotropic property and different metal by measuring the microwave reflection coefficients $S_{11}$ of copper(II)-phthalocyanine(CuPc) thin films by using a near-field microwave microscope(NSMM) in order to understand. CuPc thin films were prepared on gold and aluminium substrates using a thermal evaporation method. Two kinds of CuPc thin films were prepared. One was deposited on preheated substrate at $150^{\circ}C$ and the other was annealed after deposition by using thermal evaporation methods. The microwave reflection coefficients $S_{11}$ of CuPc thin films were changed by the dependence on the heat treatment conditions. By comparing reflection coefficient $S_{11}$ we measured electrical conductivity of CuPc thin films and studied this results with respect to the surface potential and space charge of the interface between metal and CuPc thin films.

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EL Properties of OLEDs with Different Crystal Structures of Hole Injection Layers of Copper(II)-phthalocyanine (정공 주입층 Copper(II)-phthalocyanine의 결정 변화에 따른 유기발광소자의 발광특성연구)

  • 임은주;이기진;한우미;이정윤;차덕준;이용산;김진태
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.2
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    • pp.113-119
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    • 2003
  • We report the electrical properties of copper(II)-phthalocyanine(Cu-Pc) as a hole injaction layer in organic light-emitting diode (OLED). OLEDs were constructed by the following material structure : indium tin oxaide (ITO)/ CuPc/ triphenyl-diamine (TPD)/ tris-(8-hydroxyquinoline)aluminum (Alq3)/4-(Dicyanomethlene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM)/ Al. we observed that the change of recombination zone by using a DCM detection thin layer (6 ${\AA}$) in a Alq$_3$ emitting layer. layer. Recombination zone was moved toward the cathode as the hole mobility increased due to the heat-treatment temperature of cupc layer increased.

Tunneling Spectra in Organic Cu-Pc/$Bi_2Sr_2CaCu_2O_{8+\delta}$ Tunnel Junctions

  • Kim, Sunmi;E, Jungyoon;Lee, Kiejin;Ishbas, Takayuki;Lee, Yang-San
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.41-44
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    • 2001
  • We report the current transport properties of a normal metal/organic conductor/ superconductor tunnel junction as a novel high- $T_{c}$ superconducting three terminal device. The organic copper (II) phthalocyanine (Cu-Pc) layer was used far a polaronic quasiparticle (QP) injector. The injection of polaronic QP from the Cu-Pc interlayer into a superconductor $Bi_2$$Sr_2$$CaCu_2$ $O_{8+}$ $\delta$/(BSCCO) thin film generated a substantially larger nonequilibrium effect as compared to the normal QP injection current. The tunneling spectroscopy of an Au/cu-PC/BSCCO junction exhibited a zero bias conductance peak which may be due to Andreev reflection at a Cu-Pc/d-wave superconductor junction.n..

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Temperature and the Interfacial Buffer Layer Effects on the Nanostructure in the Copper (II) Phthalocyanine: Fullerene Bulk Heterojunction

  • Kim, Hyo Jung;Kim, Jang-Joo;Jeon, Taeyeol;Kong, Ki Won;Lee, Hyun Hwi
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.275.1-275.1
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    • 2014
  • The effects of the interfacial buffer layer and temperature on the organic bulk heterojunction (BHJ) nanostructures of copper phthalocyanine (CuPc) and fullerene (C60) systems were investigated using real time in-situ x-ray scattering. In the CuPc:C60 BHJ structures, standing-on configured ${\gamma}$-CuPc phase was formed by co-deposition of CuPc and C60. Once formed ${\gamma}$-phase was thermally stable during the annealing upon $180^{\circ}C$. Meanwhile, the insertion of CuI buffer layer prior to deposition of the CuPc:C60 BHJ layer induced lying-down configured CuPc crystals in the BHJ layer. The lying CuPc peak intensity and the lattice parameter were increased by the thermal annealing. This increment of the intensity seemed to be related to the strain at the interface between CuPc:C60 and CuI, which was proportional to the enhancement of the power conversion efficiency of the device.

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Tunneling effect due to UV irradiation in organic Cu-Pc/$Bi_2$$Sr_2$Ca$Cu_2$$O_{8+$\delta$}$ tunnel junction

  • Kim, Sunmi;Lee, Kiejin;Deokjoon Cha;Takayuki Ishibashi
    • Progress in Superconductivity
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    • v.4 no.2
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    • pp.99-103
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    • 2003
  • We studied the nonequilibrium superconductivity due to tunnel injection of polaronic quasiparticle (QP) from organic photoconductor. The transport properties of an organic copper (II) phthalocyanine (Cu -Pc)/d-wave superconductor were investigated in dark and under ultraviolet (UV) radiation for performance of a novel $high -T_{c}$ superconducting three terminal device. We observed that the injection of polaronic QP from the organic Cu -Pc film into the $Bi_2$S $r_2$$CaCuO_{8+{\delta}}$ film generated a substantially larger nonequilibrium effect as compared to the normal QP injection current. We could increase the current gain by UV excitation of the organic photoconductor injector. The tunneling spectroscopy of a Cu -Pc/BSCCO junction exhibited a small enhancement of the zero bias conductance peak under the W excitation. The above phenomena are of importance in developing optically controlled three terminal superconducting device.e.

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Photocurrent multiplication process in OLEDs due to light irradiation and crystalline hole transporting layer (유기발광소자의 결정구조에 따른 Photocurrent 발광효율특성 연구)

  • Lim, Eun-Ju;Lee, Kie-Jin;Han, Woo-Mi;E, Jung-Yoon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1026-1029
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    • 2002
  • We report the electric properties of organic light emitting diodes (OLEDs) by controlling the carrier density according to the crystalline of copper(II) phthalocyanine(CuPc) and the irradiation light intensity. OLEDs were constructed with indium tin oxaide (ITO)/CuPc/triphenyl-diamin (TPD)/tris-(8-hydroxyquinoline)aluminum (Alq3)/Al. The transport properties of OLEDs were changedby the heat-treatments of CuPc. The irradiation of red and blue light exciting CuPc, TPD and Alq3. And then we observed the carrier density of OLEDs.

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