• 제목/요약/키워드: Organic Carbon

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낙동강 하구 갯벌 사질 퇴적물에서 생지화학적 유기탄소순환 (Biogeochemical Organic Carbon Cycles in the Intertidal Sandy Sediment of Nakdong Estuary)

  • 이재성;박미옥;안순모;김성길;김성수;정래홍;박종수;진현국
    • 한국해양학회지:바다
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    • 제12권4호
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    • pp.349-358
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    • 2007
  • 투수성이 큰 낙동강 하구 사질 갯벌 퇴적물에서 유기탄소의 생지화학적 순환을 이해하기 위해 현장과 실험실에서 유기탄소 생산 및 소비에 대한 정보를 추정했다. 퇴적물 상부층의 Chl-a 농도와 공극수의 영양염 농도는 니질 퇴적물에 비해 낮았다. 반면, 사질 퇴적물의 산소소모율은 유기물 함량이 높은 연안 니질 퇴적물 보다 높아 이류에 의한 유기탄소의 분해와 물질의 이동이 큰 것을 의미했다. 간단한 유기탄소의 물질수지는 퇴적물에서 유기탄소의 주 공급원이 퇴적물 표층에 서식하는 저서미세조류와 수생식물의 쇄설성 유기물로 나타났다. 해수 여과율에 낙동강 전체 면적을 외삽한 일당 자연 생촉매 여과양은 부산시 7개 주요 하수종말처리장의 최대 처리량 보다 한 자리수 이상 크게 나타나 연안환경에서 사질퇴적물이 생지화학적 정화와 물질의 재분배에 매우 큰 기여를 할 것으로 판단된다.

Global Increases in Dissolved Organic Carbon in Rivers and Their Implications

  • Kang, Ho-Jeong;Jang, In-Young;Freeman, Chris
    • 생태와환경
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    • 제43권4호
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    • pp.453-458
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    • 2010
  • DOC (Dissolved Organic Carbon) is an operational terminology for organic carbon molecules dissolved in natural waters. DOC has been studied by ecologists extensively, because it plays a key role in various ecological functions such as substrates for secondary production and the carbon cycle. DOC also represents a substrate for microbial growth within potable water distribution systems, and can react with disinfectants (e.g., chloride) to form harmful disinfection by-products. In addition, residual DOC may carry with it organically bound toxic heavy metals. DOC in aquatic ecosystems may ultimately be transported to the oceans, or released back to the atmosphere by heterotrophic respiration, which can accelerate global climate change. There is evidence that DOC concentrations in aquatic ecosystems are increasing in many regions of the world including Europe, North America, and even in Korea. Land use changes, elevated temperature, elevated $CO_2$, recovery from acidification, and nitrogen deposition have been proposed as mechanisms for the trend. However, the key driving mechanism is yet to be conclusively determined. We propose that more extensive and longer-term observations, research of chemical properties of DOC, impacts of elevated DOC on environmental issues and interdisciplinary approaches are warranted as future studies to fill the gaps in our knowledge about DOC dynamics.

Impacts of temperature variations on soil organic carbon and respiration at soil erosion and deposition areas

  • Thet Nway Nyein;Dong Kook Woo
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2023년도 학술발표회
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    • pp.447-447
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    • 2023
  • Soil organic carbon (SOC) is a critical indicator of soil fertility. Its importance in maintaining ecological balance has received widespread attention. However, global temperatures have risen by 0.8℃ since the late 1800s due to human-induced greenhouse gas emissions, resulting in severe disruptions in SOC dynamics. To study the impacts of temperature variations on SOC and soil respiration, we used the Soil Carbon and Landscape co-Evolution (SCALE) model, which was capable of estimating the spatial distribution of soil carbon dynamics. The study site was located at Heshan Farm (125°20'10.5"E, 49°00'23.1"N), Nenjiang County in Heilongjiang Province, Northeast China. We validated the model using observed soil organic carbon and soil respiration in 2015 and achieved excellent agreement between observed and modeled variables. Our results showed considerable influences of temperature increases on SOC and soil respiration rates at both erosion and deposition areas. In particular, changes in SOC and soil respiration at the deposition area were greater than at the erosion area. Our study highlights that the impacts of temperature elevations are considerably dependent on soil erosion and deposition processes. Thus, it is important to implement effective soil conservation strategies to maintain soil fertility under global warming.

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회귀식을 사용한 하수처리장 방류수 CODMn 농도의 총 유기탄소 및 난분해성 물질 농도 전환 (Conversion of CODMn into TOC and Refractory Organic Matter Concentrations for Treated Sewage using Regression Equations)

  • 이태환;이보미;허진;정명숙;강태구
    • 한국물환경학회지
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    • 제26권6호
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    • pp.969-975
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    • 2010
  • Estimating the organic matter loadings from individual treated sewage has become important for establishment of effective management strategies to control refractory organic matter (R-OM) in watersheds. For this study, regression equations were constructed using treated sewage data to convert the chemical oxygen demand (COD) concentrations, which are mostly available from open database, into total organic carbon (TOC) and R-OM concentrations. Effluent samples were collected from five major sewage treatment plants (STPs) located upstream of the lake Paldang. Variations in the OM concentrations were not associated with either the location of the STP or the sampling season. The effluent investigated were characterized by higher ratio of R-OM with respect to biodegradable organic matter (B-OM) and higher presence of dissolved organic matters (DOM) versus particulate organic matter (POM). Compared to $COD_{Mn}$, $COD_{Cr}$ exhibited higher oxidation efficiencies and greater variations in the concentrations. The concentrations of $COD_{Mn}$ were positively correlated with dissolved organic carbon (DOC), total organic carbon (TOC), and R-OM concentrations. There was nearly no seasonal and annual variation in the regression equations between $COD_{Mn}$ and TOC or R-OM concentrations. The constructed regression equations for TOC and R-OM were $0.650({\pm}0.071){\times}COD_{Mn}+1.426({\pm}0.575)$ and $0.340({\pm}0.083){\times}COD_{Mn}+2.054({\pm}0.670)$, respectively. The established equations are expected to contribute to estimating OM loadings from the STPs into the lake Paldang and also to compensating for the deficiency of the data for effluent OM concentrations in STP.

논토양에서 퇴비시용 및 경운이 토양탄소 축적과 안정화에 미치는 영향 (Effect of Compost and Tillage on Soil Carbon Sequestration and Stability in Paddy Soil)

  • 홍창오;강점순;신현무;조재환;서정민
    • 한국환경과학회지
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    • 제22권11호
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    • pp.1509-1517
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    • 2013
  • So far, most studies associated with soil carbon sequestration have been focused on long term aspect. However, information regarding soil carbon sequestration in short term aspect is limited. This study was conducted to determine changes of soil organic carbon content and stability of carbon in response to compost application rate and tillage management during rice growing season(150 days) in short term aspect. Under pot experiment condition, compost was mixed with an arable soil at rates corresponding to 0, 6, 12, and 24 Mg/ha. To determine effect of tillage on soil carbon sequestration, till and no-till treatments were set up in soils amended with application rate of 12 Mg/ha. Compost application and tillage management did not significantly affect soil organic carbon(SOC) content in soil at harvest time. Bulk density of soil was not changed significantly with compost application and tillage management. These might result from short duration of experiment. While hot water extractable organic carbon(HWEOC) content decreased with compost application, humic substances(HS) increased. Below ground biomass of rice increased with application of compost and till operation. From the above results, continuos application of compost and reduce tillage might improve increase in soil organic carbon content and stability of carbon in long term aspect.

유기이차전지를 위한 Poly(Styrenesulfonate)-Carbon 복합 음극의 전기화학적 특성 (Electrochemical Properties of Poly(Styrenesulfonate)-Carbon Composite Anode for Organic Rechargeable Battery)

  • 임지은;강동원;김재광
    • 전기화학회지
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    • 제19권4호
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    • pp.129-133
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    • 2016
  • 본 연구에서는 고분자와 탄소 물질을 복합화시켜 친환경의 유기 음극을 제조하였다. Poly(styrenesulfonate)(PSS)-carbon 복합 음극은 탄소 입자를 PSS이 둘러싸고 있는 core-shell 형태를 보이며 $524mAh\;g^{-1}$의 이론용량과 0.6 V 이하의 낮은 전압을 가진다. PSS-carbon 복합 음극은 0.1, 0.5, 1, 10C에서 각각 용량 $519.6mAh\;g^{-1}$, $461.2mAh\;g^{-1}$, $411.8mAh\;g^{-1}$, $315.9mAh\;g^{-1}$의 첫 번째 방전 용량을 가지면 30사이클까지 안정적인 주기 특성을 보여준다. Polystyrene 구조와 sulfonate 기능 기를 갖는 PSS와의 탄소 복합 전극은 유기 이차전지의 전기화학적 특성을 향상 시키기 적합한 음극활 물질로 여겨 진다.

월악산 소나무림의 유기탄소 분포 및 수지 (Organic Carbon Distribution and Budget in the Pinus densiflora Forest at Mt. Worak National Park)

  • 이지영;김덕기;원호연;문형태
    • 한국환경생태학회지
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    • 제27권5호
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    • pp.561-570
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    • 2013
  • 월악산국립공원 송계계곡에 발달되어 있는 소나무림에서 2011년 5월부터 2012년 4월까지 지상부와 지하부 생물량, 낙엽생산량, 낙엽층의 낙엽량, 그리고 토양의 유기탄소 분포를 조사하였으며, 탄소수지를 파악하기 위해 토양호흡량을 측정하였다. 지상부와 지하부 생물량에 분포되어 있는 유기탄소량은 각각 52.25, 14.52 ton C $ha^{-1}$ 이었으며, 낙엽층과 토양의 유기탄소량은 각각 4.71 ton C $ha^{-1}$, 58.56 ton C $ha^{-1}$ 50cm-$depth^{-1}$ 로 조사되었다. 조사지 소나무림의 전체 유기탄소량은 130.04 ton C $ha^{-1}$ 이었으며, 이중 51.4%가 식물체에 분포하는 것으로 나타났다. 본 소나무림에서 연간 광합성을 통하여 식물체에 고정된 유기탄소량은 4.26 ton C $ha^{-1}yr^{-1}$이었고, 층위별로는 교목층, 관목층, 초본층에 각각 4.12, 0.10 및 0.04 ton C $ha^{-1}yr^{-1}$의 유기탄소가 고정되었다. 조사기간 동안 낙엽생산을 통해 임상으로 유입되는 유기탄소량은 1.62 ton C $ha^{-1}$ 이었으며, 토양호흡을 통하여 방출되는 탄소량은 6.25 ton C $ha^{-1}yr^{-1}$으로 이중 미생물호흡과 뿌리호흡을 통해 방출되는 탄소량은 각각 3.19, 3.06 ton C $ha^{-1}yr^{-1}$이었다. 유기탄소 순 생산량과 미생물호흡량의 차이로 추정했을 때 본 소나무림에서 연간 대기로부터 순 흡수하는 유기탄소는 1.07 ton C $ha^{-1}yr^{-1}$ 로 조사되었다.

유기농자재의 탄소배출량 산정을 위한 전과정평가(LCA) -참숯, 목초액, 미생물제재를 중심으로- (Life Cycle Assessment (LCA) for Calculation of the Carbon Emission Amount of Organic Farming Material -With Emphasis on Hardwood Charcoal, Grass Liquid and Microbial Agents-)

  • 윤성이;손보홍
    • 한국유기농업학회지
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    • 제20권3호
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    • pp.297-311
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    • 2012
  • Since 1997, Korean Ministry of Knowledge Economy and Ministry of Environment have established data on some 400 basic raw and subsidiary materials and process like energy, petro-chemical, steel, cement, glass, paper, construction materials, transportation, recycling and disposal etc by initiating establishment of LCI database. Regarding agriculture, Rural Development Administration has conducted establishment of LCI database for major farm products like rice, barley, beans, cabbage and radish etc from 2009, and released that they would establish LCI database for 50 items until 2020 later on. The domestic LCI database for seeds, seedling, agrochemical, inorganic fertilizer and organic fertilizer etc is only at initial stage of establishment, so overseas LCI databases are brought and being used. However, since the domestic and overseas natural environments differ, they fall behind in reliability. Therefore, this study has the purpose to select organic farming materials, survey the production process for various types of organic farming materials and establish LCI database for the effects of greenhouse gas emitted during the process in order to select carbon basic units for agricultural production system compliant in domestic situation instead of relying on overseas data and apply life cycle assessment of greenhouse gas emitted by each crop during the process. As for selecting methods, in this study organic farming materials were selected in the method of direct observation of material and bottom-up method a survey method with focus on the organic farming materials admitted into rice production. For the basic unit of carbon emission amount by the production of 1kg of organic farming material, the software PASS 4.1.1 developed by Korea Accreditation Board under Ministry of Knowledge Economy was used. The study had the goal to ultimately provide basic unit to calculate carbon emission amount in executing many institutions like goal management system and carbon performance display system etc in agricultural sector to be conducted later on. As a result, emission basic units per 1kg of production were calculated to be 0.0088kg-$CO_2$ for charcoal, 0.1319kg-$CO_2$ for grass liquid, and 0.2804kg-$CO_2$ for microbial agent.

국내 주요 하구역 표층퇴적물의 입도와 유기탄소 함량 관계 (Relationship between Grain Size and Organic Carbon Content of Surface Sediments in the Major Estuarine Areas of Korea)

  • 김부근;양주연;최혁;박광규;신경훈
    • 한국해양학회지:바다
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    • 제28권4호
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    • pp.158-177
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    • 2023
  • 하구역은 강과 하천을 통해 육상과 해양을 연결하는 전이수역으로 해양으로 공급되는 많은 물질들은 연안환경의 일차 생산성을 결정하는 중요한 역할을 담당하며, 이러한 연안생태계는 생물량에 의해 제거되는 탄소인 블루카본의 탄소 저장소로서 기후변화를 완화시키는 역할을 한다. 우리나라의 서-남해 하구역(한강, 금강, 영산강, 섬진강, 낙동강)과 동해 용승해역에서 지난 6년간 표층퇴적물의 평균입도와 유기탄소 함량의 변화와 두 인자들 사이의 상관관계를 분석하였다. 조사기간(2015-2020년) 동안 서-남해 하구역과 동해 용승해역 표층퇴적물의 평균입도와 유기탄소 함량은 계절적 변화가 관찰되지 않았으며, 전반적으로 각 해역의 다양한 해양환경 및 수리역학적 조건에 의해 두 인자들이 조절되는 것으로 해석된다. 조사된 모든 시료채취의 동시성이 없는 문제점에도 불구하고 연구지역에서 분석된 모든 퇴적물 평균입도들의 평균값과 유기탄소 함량의 평균값은 양의 상관관계를 보이며 각 하구역과 동해 용승해역을 구분한다. 동일한 양의 상관관계를 보이는 각 하구역에서는 아마도 같은 과정에 의한 퇴적물 점토입자의 퇴적이 유기탄소 축적에 중요한 역할을 담당한다. 그러나 동해 용승해역은 하구역과 다르게 추가적인 유기탄소 축적의 요인이 나타난다. 국내 주요 하구역들이 연안환경에서 중요한 탄소저장소로서 평가되기 위해서는 탄소 저장량 계산을 위한 추가적인 자료(퇴적률, 전밀도 등)가 요구된다.

고농도 고형 유기물질을 포함하는 가축 분뇨의 TOC 분석방법 평가 (Assessment of TOC Analysis Method for Livestock Manure including High Strength Solid Organics)

  • 이윤희;어성욱;김용석;박지형
    • 한국물환경학회지
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    • 제30권5호
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    • pp.512-516
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    • 2014
  • Two different methods for TOC (Total Organic Carbon) analysis of livestock manure including high strength solid organics were evaluated. Firstly, an analyzing method by dilution after pre-treated by Ultrasonicator and 100 mesh sieve for homogenization was defined as TOC 1; and secondly method divided by particulate organic carbon (POC) and dissolved organic carbon (DOC) was defined as TOC 2. 116 samples collected from 56 farms were analyzed in TOC1, TOC2, BOD and VSS. TOC1 method showed higher accuracy at less than 30,000 mg/L of TOC while TOC2 method presented significant reliability at over that concentration. Regarding to the sample with the same VSS concentration, the correlation between TOC 2 and VSS (${\rho}$: 0.806) was slightly higher than that between TOC 1 and VSS (${\rho}$: 0.784), resulted from a relatively low loss of solids and a low error probability (dilution and homogenization effects) in the analyzing procedures. In addition, the reliability between POC and VSS in TOC2 was high and the POC was about 4.4 fold that of the VSS. Consequently, TOC 2 without dilution effect was assessed as a proper method to increase the analyzing accuracy of swine manure including high solid organics.