• 접착 및 계면
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• 제1권1호
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• pp.47-55
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• 2000

In this article, the characterization of the interface of hybrid composites was discussed. Interfacial interaction in organic/inorganic hybrid composites, especially silica-containing hybrids can be characterized by fluorescence spectroscopy, small angle X-ray scattering (SAXS), scanning electron microscopy (SEM), atomic force microscopy (AFM), and $^{29}Si$ NMR spectroscopy measurements.

• Fibers and Polymers
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• 제2권3호
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• pp.135-140
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• 2001

Organic-inorganic hybrid composites consisting of poly(vinylidene fluoride) (PVDF) and SiO$_2$ were prepared through a sol-gel process and the crystallization behavior of PVDF in the presence of $SiO_2$ networks was investigated by spectroscopic, thermal and x-ray diffraction measurements. The hybrid composites obtained were relatively transparent, and brittleness increased with increasing content of tetraethoxysilane (TEOS). It was regarded from FT-lR and DSC thermal analyses that at least a certain interaction existed between PVDF molecules and the $SiO_2$ networks. X-ray diffraction measurements showed that all of the hybrid samples had a crystal structure of PVDF ${\gamma}$-phase. Fresh gel prepared from the sol-gel reaction showed a very weak x-ray diffraction peak near 2$\theta$=$21^{\circ}$ due to PVDF crystallization, and Intensity increased grade-ally with time after gelation. The crystallization behavior of PVDF was strongly affected by the amount of $SiO_2$ networks. That is, $SiO_2$ content directly influenced preference and disturbance fur crystallization. In polymer-rich hybrids, $SiO_2$ networks had a favorable effect on the extent of PVDF crystallization. In particular, the maximum portent crystallinity of PVDF occurred at the content of 3.7 wt% $SiO_2$ and was higher than that of pure PVDF. However. beyond about 10 wt% $SiO_2$, the crystallization of PVDF was strongly confined.

• 공업화학
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• 제16권5호
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• pp.628-634
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• 2005

Zirconia-alumina 고분자 전구체가 유기물-무기물 용액 방법으로 zirconium acetylacetonate (ZA), aluminium nitrate (AN), polyethylene glycol (PEG), 그리고 에탄올을 이용하여 제조되었다. 고분자 전구체의 열적 특성 및 점도를 시차주사열용량분석기(DSC), 열중량분석기(TGA), 그리고 동적유변측정기를 이용하여 측정하였다. 부피 팽창을 동반하는 강렬한 발열반응이 $140^{\circ}C$에서 일어났다. 고분자 전구체의 부피팽창은 금속물질중에 유기물의 분해반응과 금속양이온과 PEG 사이의 반응에 의한 것이다. 이들 분해반응과 금속양이온과 PEG 사이의 반응에 대한 여부를 적외선분광기(FT-IR)와 $^{13}C$ solid-NMR 결과로부터 확인하였다. 고분자 전구체의 온도가 증가함에 따라 N-O, O-H, 그리고 C=C에서의 피이크 강도가 감소하였다. 이 결과는 강렬한 발열반응시 금속 물질의 분해반응과 PEG와 금속양이온의 반응이 일어났음을 나타내는 것이다. 다공성 파우더는 $800^{\circ}C$에서 2 h 동안 소결과정을 거쳐 결정성 $ZrO_2-Al_2O_3$ 복합체가 되었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.45-45
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• 2008

$SrTiO_3$/Organic composites 는 Inorganic/organic 복합재료로, 유전 특성이 우수하고, 저온하여 제조단가의 감소가 가능하다. 이를 바탕으로 $SrTiO_3$/Organic composites 복합재를 이용한 가능성을 확인하기 위해 Multilayer 구조의 Coupler를 설계, 제작 후 특성을 분석하였다. Coupler 는 RF signal을 분기하기 위한 목적으로 평행한 한 쌍의 Conductor line 구조를 가진다. 2개의 Line 의 길이를 특정주파수 $f_0$의 wavelength $\lambda$/4 로 설계하여 서로 근접 시켰을 때 $f_0$를 중심으로 RF 신호 분기 현상이 나타난다. 보다 넓은 대역에 걸쳐서 신호분기를 하기 위해서는 두 line 간의 간격을 좁혀 Signal coupling 효과를 증가 시킨다. single layer conductor 구조에서는 물리적인 한계가 있으므로, multilayer 구조를 사용하면 보다 넓은 대역의 Coupled line coupler 로서 기능하게 된다.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2002년도 봄 학술발표회 논문집
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• pp.321-324
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• 2002

Recently, organic-inorganic nanocomposites have attracted great interest from researchers since they frequently exhibit unexpected hybrid properties synergistically derived from two components[1]. The addition of highly dispersed inorganic nano-sized fillers permits improvement of certain properties of polymers as compared with conventional particulate composites; increase of modulus and strength, improved barrier properties, increase in solvent and heat resistance, and good optical properties[2]. (omitted)

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 추계총회 및 연구발표회 초록집
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• pp.224.1-224
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• 2003

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1175-1176
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• 2006

Influences of machining on magnetic properties of soft magnetic composites (SMC's) with addition of two kinds of binder, i.e., organic binder and inorganic one, were investigated. Machining does not affect DC magnetic properties of the SMC compacts. This can be ascribed to their particular structure in which the ironpowder particles are highly isolated by the binder. On the other hand, decrease in resistivity and resultant increase in eddy current loss was confirmed in the machined compacts containing inorganic binder. It is supposed that the brittleadditive binder existing between the iron particles is partly broken, and iron-to-iron contact is formed on the machined surface.

• Carbon letters
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• 제26권
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• pp.74-80
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• 2018

The South Korean Ministry of the Environment has revised the laws relating to the management of interior air quality for multiple use facilities, and recommends maintaining carbon dioxide ($CO_2$) concentration in passenger vehicles below 1000 ppm during operation in urban areas of large cities. However, the interior $CO_2$ concentration of passenger vehicles can rapidly increase and exceed 5000 ppm within 30 min, as observed when two passengers are traveling in urban areas of the South Korean city of Jeonju with the air conditioner blower turned off and the actuator mode set to internal circulation mode. With four passengers, $CO_2$ concentration can reach up to 6000 ppm within 10 min. To counter this, when the actuator is set to external mode, $CO_2$ concentration can be maintained below 1000 ppm, even after a long period of running time. As part of the air conditioning system, alkali-treated activated carbon fiber filters are considered to be far superior to the commercial non-woven filters or combination filters currently commonly in use.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 추계학술대회 논문집
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• pp.350-354
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• 2009

In this work, polymer - inorganic composites have prepared using polymer such as polyethylene glycol (PEG)/poly (methyl methacrylate, PMMA) and inorganic nanofillers materials such as TiO2 nanotubes (TiNTs)/carbon nanotubes (CNTs). The extensive structural, morphological and ionic properties revealed that the high surface area and tubular feature of nanofillers improved the interaction and cross-linking to polymer matrix which is significantly enhanced the ionic conductivity and electrical properties of composite electrolytes. Comparably high conversion efficiency ~4.5% has been observed by using the newly prepared PEG-TiNTs composite solid electrolyte as compared with PMMA-CNTs electrolyte based DSSCs (~3%). The detailed comparative properties would be discussed in term of their structural, morphology, ionic and photovoltaic properties.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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• pp.852-854
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• 2003

CNT paste was fabricated by mixture of multi-walled carbon nanotubes (MWNT) powder, organic vehicles and inorganic binder. Then firing process was performed at different temperature under air and $N_{2}$ atmosphere. It was found that emission property of CNT paste was changed by firing temperature and time due to interaction between remained resins and CNT powder. We obtained good emission property from CNT paste treated at $350^{\circ}C$ for 10 min.