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Fabrication and Characterization of Zirconia-Alumina Composites by Organic-Inorganic Solution Technique  

Kim, Youn Cheol (Division of Chemical Engineering, Kongju National University)
Bang, Moon-Soo (Division of Chemical Engineering, Kongju National University)
Lee, Sang Jin (Department of Advanced Materials Science and Engineering, Mokpo National University)
Publication Information
Applied Chemistry for Engineering / v.16, no.5, 2005 , pp. 628-634 More about this Journal
Abstract
Zirconia-alumina polymer precursor was prepared from zirconium acetylacetonate (ZA). paluminium nitrate (AN), polyethylene glycol (PEG), and ethyl alcohol via an organic-inorganic solution technique. The thermal properties and viscosity of the polymer precursor were measured by differential scanning calorimetry (DSC), thermograbimetric analyzer (TGA), and dynamic viscometer. The vigorous exothermic reaction with volume expansion occurred at $140^{\circ}C$. The volume expansion was caused by abrupt decomposition of the organic group in metal compounds and the metal ions-PEG reaction. The evidences for these reactions were confirmed by FT-IR and $^{13}C$ solid NMR results. The peak intensity at N-O, O-H and C=C decreased with increasing temperature. This indicated that the decomposition of metal compounds and the metal ions-PEG reaction occurred during the vigorous exothermic reaction. At $800^{\circ}C$ for 2 h, the porous powders transformed to the crystalline $ZrO_2-Al_2O_3$ composites.
Keywords
zirconia-alumina; polymer precursor; organic-inorganic solution technique;
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1 A. H. Heuer, J. Am. Ceram Soc., 70, 689 (1987)   DOI   ScienceOn
2 S. Bhaduri, S. B. Bhaduri, and E. Zhou, J. Mater. Res., 13, 136 (1998)
3 R. N. Viswanath and S. Ramasamy, NanoStructured Mater., 12, 1085 (1999)   DOI   ScienceOn
4 Z. Chen, K. K. Chawla, and M. Koopman, Mater. Sci. Eng., 367, 24 (2004)   DOI
5 M. Sternitzke, J. Eur. Ceram. Soc., 17, 1061 (1997)   DOI
6 S. T. Buljan, J. G. Baldoni, and M. L. Huckabee, Am. Ceram. Soc. Bull., 66, 347 (1987)   DOI
7 R. D. Sisson and B. M. Smyser, NanoStructured Mater., 10, 829 (1998)   DOI   ScienceOn
8 S. J. Lee and W. M. Kriven, J. Am. Ceram. Soc., 81, 2605 (1998)   DOI   ScienceOn
9 J. J. Clark, T. Takeuchi, N. Ohtori, and D. C. Sinclair, J. Mater. Chem., 9, 83 (1999)   DOI   ScienceOn
10 C. Laurent, A. Rousset, P. Bonnefond, D. Oquab, and B. Lavelle, J. Eur. Ceram. Soc., 16, 937 (1996)   DOI   ScienceOn
11 J. G. Liu and D. J. Wilkox, J. Mater. Res., 10, 84 (1995)   DOI   ScienceOn
12 J. Dusza, P. Sajgalik, and M. Steen, J. Am. Ceram Soc., 82, 3613 (1999)   DOI   ScienceOn
13 M. Chattezjee, M. K. Naskar, and D. Ganguli, J. Sol-Gel Sci. Technol., 28, 217 (2003)   DOI   ScienceOn
14 S. J. Lee, Y. C. Kim, and J. H. Hwang, J. Ceram. Proc. Res., 5, 223 (2004)
15 M. Balasubramanian, S. K. Malhotra, and C. V. Gokulrathnam, J. Mater. Sci., 30, 3515 (1995)   DOI   ScienceOn
16 S. J. Lee, E. A. Benson, and W. M. Kriven, J. Am. Ceram Soc., 82, 2049 (1999)   DOI
17 S. J. Lee and Y. C. Kim, J. Kor. Ceram. Soc., 40, 837 (2003)   DOI
18 S. J. Lee, M. D. Biegalski, and W. M. Kriven, J. Mater. Res., 14, 3001 (1999)   DOI
19 M. Herrmann, C. Schuber, A. Rendtel, and H. Hubner, J. Am. Ceram Soc., 81, 1095 (1998)   DOI   ScienceOn
20 M. K. Naskar, M. Chatterjee, and N. S. Lakshmi, J. Mater. Sci., 37, 343 (2002)   DOI   ScienceOn
21 A. C. Faro, K. R. Souza, V. Lucia, D. J. Camorim, and M. B. Cardoso, Phys. Chem. Chem. Phys., 5, 1932 (2003)   DOI   ScienceOn
22 D. J. Green, J. Am. Ceram Soc., 65, 610 (1982)   DOI   ScienceOn
23 C. Li, Y. W. Chen, and T. M. Yen, J. Sol-Gel Sci. Technol., 4, 205 (1995)   DOI
24 X. Wu, J. Zou, S. Yang, and D. Eang, J. Colloid & Interface Sci., 239, 369 (2001)   DOI   ScienceOn
25 K. Niihara, J. Ceram. Soc. Jpn., 99, 974 (1991)   DOI
26 M. P. Pechini, U. S. Patent, 3,330,697 (1967)
27 S. W. Lu, B. J. Lee, and J. A. Mann, Mater. Left., 43, 102 (2000)
28 J. D. Tsay, T. T. Fang, T. A. Gubiotti, and J. Y. Ying, J. Mater. Sci., 33, 3721 (1998)   DOI   ScienceOn
29 P. Duran, D. Gutierrez, J. Tartaj, M. A. Banares, and C. Moure, J. Eur. Ceram. Soc., 22, 797 (2002)   DOI   ScienceOn
30 J. J. Koenig, Spectroscopy of Polymers, ACS, 197 (1992)