• Title/Summary/Keyword: Order effect

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Effect of Solvent on Some Excited States Processes of Mg- and Zn-Phthalocyanines$^\dag$

  • Kim, Dong-Ho
    • Bulletin of the Korean Chemical Society
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    • v.7 no.6
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    • pp.416-421
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    • 1986
  • The solvent coordination effect on the excited state processes of Mg(II)- and Zn(II)-phthalocyanines has been described. The triplet state of these compounds decays with mixed first and second order kinetics or mainly second order kinetics depending on the solvents used. The first order component of the rate constants decrease along with the series, dimethylsulfoxide (5-coordinated), 1-chloronaphthalene (4-coordinated) and piperidine (6-coordinated), while the second order rate constant is dependent on the diffusion rate constant of the solvents. The excited state quenching by methylviologen or p-benzoquinone is discussed. And ion recombination rate constant is given.

The Effect of Test Anxiety,Intelligence, and Item Arrangement Order on Test Performance in Earth Science (시험불안(試驗不安) 지능(知能) 및 문항배렬(問項配列) 방식(方式)이 지구과학(地球科學) 의험수행(議驗遂行)에 미치는 효과(效果))

  • Kim, Sang-Dal;Yi, Hyang-Sun;Hwang, In-Ho
    • Journal of The Korean Association For Science Education
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    • v.11 no.2
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    • pp.161-178
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    • 1991
  • This study was designed to investigate the effect of test anxiety, intelligence, and item arrangement order on test performance in Earth Science. The main purposes in this study were to investigate (1) (2) (3) (4) on test performance.: (1) the effect of test anxiety components on test performance in Earth Science. (2) the effect of item arrangement order on test performance in Earth Science. (3) the effect of test anxiety This study was designed to investigate the effect of test anxiety, intelligence, and item arrangement order on test performance in Earth Science. The main purposes in this study were to investigate (1) (2) (3) (4) on test performance.: (1) the effect of test anxiety components on test performance in Earth Science. (2) the effect of item arrangement order on test performance in Earth Science. (3) the effect of test anxiety components on test performance in Earth Science according to learner's intelligence levels. (4) test effect of item arrangement order on learner's intelligence. The hypothesis was that there is difference among test achievements scores according to (1) test anxiety-worry levels. (2) item arrangement orders. (3) item arrangement orders on test anxiety-worry levels. (4) test anxiety-worry levels on intelligence levels. (5) test anxiety-emotionality levels. (6) item arrangement orders on test anxiety-emotionality levels. (7) test anxiety-emotionality levels on intelligence levels. (8) item arrangement orders on intelligence levels. The test items selected for this study were derived from the text Science (part 1) first grade of high school. The subjects of this study were 164 of high school first grade boy students in Pusan. They were assigned to one of the three groups, according to test anxiety levels.: (1) upper 25% of total subjects designated to high group (2) middle 50% (3) low group, lower 25% of total subjects And according to LQ. (1) upper 25% of total subjects designated to high group. (2) middle 50%. (3) low group, lower 25% of total subjects Analysis of variance was used in this study for hypothesis examination. The dependent variable was the achievement scores of Earth Science test and independent variables were test anxiety(worry, emotionality) level, LQ. level, item arrangement orders. The principal findings of the present study are as follows: (1)Test achievement score trend decreases as the test anxiety (worry, emotionality) increases although the result is not statistically significant. (2)There is no significant difference among test achievement scores according to item arrangement orders. (3)The higher the LQ. is, the more effective test anxiety. And the LQ. has significant interaction effect with test anxiety. (4)There is significant interaction effect between the LQ. levels and itemqr arrangement orders.

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Effect of Flow Liners on Ship′s Wake Simulation in a Cavitation Tunnel

  • Lee, Jin-Tae;Kim, Young-Gi
    • Journal of Hydrospace Technology
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    • v.1 no.1
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    • pp.41-56
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    • 1995
  • Flew control devices, such as flow liners, are frequently introduced in a cavitation tunnel in order to reduce the tunnel blockage effect, when a three-dimensional wake distribution is simulated using a complete ship model or a dummy model. In order to estimate the tunnel wall effect and to evaluate the effect of flow liners on the simulated wake distribution, a surface panel method is adopted for the calculation of the flow around a ship model and flow liners installed in a rectangular test section off cavitation tunnel. Calculation results on the Sydney Express ship model show that the tunnel wall effect on the hull surface pressure distribution is negligible for less than 5% blockage and can be appreciable for more than 20% blockage. The flow liners accelerate the flow near the afterbody of the ship model, so that the pressure gradient there becomes more favorable and accordingly the boundary layer thickness would be reduced. Since the resulting wake distribution is assumed to resemble the full scale wake, flow liners can also be used to simulate an estimated full scale wake without modifying the ship model. Boundary taper calculation should be incorporated in order to correlate the calculated wake distribution with the measured one.

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Flexure of cross-ply laminated plates using equivalent single layer trigonometric shear deformation theory

  • Sayyad, Atteshamuddin S.;Ghugal, Yuwaraj M.
    • Structural Engineering and Mechanics
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    • v.51 no.5
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    • pp.867-891
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    • 2014
  • An equivalent single layer trigonometric shear deformation theory taking into account transverse shear deformation effect as well as transverse normal strain effect is presented for static flexure of cross-ply laminated composite and sandwich plates. The inplane displacement field uses sinusoidal function in terms of thickness coordinate to include the transverse shear deformation effect. The cosine function in thickness coordinate is used in transverse displacement to include the effect of transverse normal strain. The kinematics of the present theory is much richer than those of the other higher order shear deformation theories, because if the trigonometric term (involving thickness coordinate z) is expanded in power series, the kinematics of higher order theories (which are usually obtained by power series in thickness coordinate z) are implicitly taken into account to good deal of extent. Governing equations and boundary conditions of the theory are obtained using the principle of virtual work. The closed-form solutions of simply supported cross-ply laminated composite and sandwich plates have been obtained. The results of present theory are compared with those of the classical plate theory (CPT), first order shear deformation theory (FSDT), higher order shear deformation theory (HSDT) of Reddy and exact three dimensional elasticity theory wherever applicable. The results predicted by present theory are in good agreement with those of higher order shear deformation theory and the elasticity theory.

Effect of Neutral Salts on the Reactive Dyeing of Silk (II) - Effect of Anions - (중성염이 견의 반응염색에 미치는 영향 (II) - 음이온의 영향 -)

  • 도성국;박찬헌;권지윤
    • Textile Coloration and Finishing
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    • v.13 no.2
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    • pp.114-119
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    • 2001
  • Four kinds of neutral sodium salts with different anions, NaF, NaCl, NaBr, and NaI, were added to the dye bath to accurately understand the effect of anions on the reactive dyeing of silk with C. I. Reactive Black 5. The sodium cation towered the negative surface potential of the silk and increased the dye-uptake on fille fabric as reported previously. However, because of the discrepancy in the anions'inhibition power from cation's lowering: the surface negative potential the amount of the dye on the silk fiber was different from each other in the order of $F^->Cl^-> Br^-I^-$. The activation energy(E$_{a}$) lot the dyeing was in the order of $F^->Cl^-> Br^-I^-$ but the dye-uptake on the fabric and the activation free energy$(\Delta{G}^*)$, the real energy barrier fort the reaction, were in the order of $F^->Cl^-> Br^-I^-$ because the strength of the interaction of the anions with sodium cations was the salute as the order of the latter. In other words F$^{[-1000]}$ exerted the weakest electrostatic force on $Na^+$ and competed with the dyestuff anions least of all. The decrease in $\Delta{S}^*$ may be due to the looesly bonded activated complex of dyestuff anions, sodium cations and fiber molecules at transition state. It was clarified from the Brёnsted equation that sodium salts with different anions also had fille ionic strength effect and the specific salt effect on the reactive dyeing.g.

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THE EFFECT OF THICKNESS OF THE PROVISIONAL CROWN AND FIXED PARTIAL DENTURE MATERIALS ON THE TRANSLUCENCY AND MASKING EFFECT

  • Jae, Hyun-Jee;Kim, Sung-Hun;Lee, Seok-Hyung;Pae, Ahran
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.6
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    • pp.724-734
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    • 2007
  • Statement of problem. Translucency and masking effect of provisional crown and fixed partial denture materials is an important esthetic consideration. But, provisional resin materials differ substantially in their ability to mask underlying colors. Purpose. The purpose of this study was to evaluate the translucency differences of provisional resin materials at various thicknesses and the correlation between the translucency and the masking efficiency. Material and methods. Two polymethyl methacrylate resins (Jet Tooth Shade, Alike) and three resin composites (Protemp 3 Garant, Luxatemp and Revotek LC) were used. Specimens (n=6) were fabricated from each material in 0.3, 0.5, 0.8, 1.0, 1.5, 2.0 and 3.0 mm thickness. The CIELAB parameters of each specimens were measured using a spectrophotometer. The translucency parameter (TP) values and the masking effect $({\Delta}ME^*{_{ab}})$ values were computed and all data were statistically analyzed by one-way ANOVA and the multiple comparisons Scheffe test. The correlation between the thickness and the TP values and the correlation between the thickness and the ${\Delta}ME^*{_{ab}}$ values were also evaluated by correlation analysis and regression analysis. Results. The TP values and the ${\Delta}ME^*{_{ab}}$ values were significantly related to the thickness in all specimens. The TP values were more sensitive to the change of thickness than the ${\Delta}ME^*{_{ab}}$ values. The order of the translucency by brand was different from the order of the masking effect by brand in all thickness groups. Conclusion. Within the limitations of this study, the translucency and masking effect of the provisional resin materials investigated were significantly related to their thickness. The masking effect of provisional resin was correlated with the translucency parameter, but the order of the masking effect by brand was different from the order of the translucency parameter.

Numerical Prediction of Open Water Performance of Flapped Rudders

  • Pyo, S.W.;Suh, J.C.
    • Journal of Ship and Ocean Technology
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    • v.4 no.1
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    • pp.1-10
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    • 2000
  • A low-order potential based boundary element method is applied for the prediction of the performance of flapped rudders as well as all-movable rudders in steady inflow. In order to obtain a reasonable solution at large angles of attack, the location of the trailing wake sheet is determined by aligning freely with the local flow. The effect of the wake sheet roll-up is also included with use of a high order panel method. The flow in the gap of a flapped rudder is modeled as Couette flow and its effect is introduced into the kinematic boundary conditions for flux at both the inlet and the outlet of the gap. In order to validate the present method, the method is applied for a series of rudders and the computational results on forces and moments are compared with experimental data. The effect of the gap size on the forces and moments is also presented.

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Effect of hall current in Transversely Isotropic magneto thermoelastic rotating medium with fractional order heat transfer due to normal force

  • Lata, Parveen;Kaur, Iqbal
    • Advances in materials Research
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    • v.7 no.3
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    • pp.203-220
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    • 2018
  • This investigation is focused on the study of effect of hall current in transversely isotropic magneto thermoelastic homogeneous medium with fractional order heat transfer and rotation. As an application the bounding surface is subjected to normal force. The research becomes more interesting due to interaction of Hall current with the effect of rotation as it has found various applications. Laplace and Fourier transform is used for solving field equations. The analytical expressions of temperature, displacement components, stress components and current density components are computed in the transformed domain. The effects of hall current and fractional order parameter at different values are represented graphically.

Inclined load effect in an orthotropic magneto-thermoelastic solid with fractional order heat transfer

  • Lata, Parveen;Himanshi, Himanshi
    • Structural Engineering and Mechanics
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    • v.81 no.5
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    • pp.529-537
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    • 2022
  • The present research is to study the effect of inclined load in a two-dimensional homogeneous orthotropic magneto-thermoelastic solid without energy dissipation with fractional order heat transfer in generalized thermoelasticity with two-temperature. We obtain the solution to the problem with the help of Laplace and Fourier transformations. The field equations of displacement components, stress components and conductive temperature are computed in transformed domain. Further the results are computed in physical domain by using numerical inversion method. The effect of fractional order parameter and inclined load has been depicted on the resulting quantities with the help of graphs.

Meta-Analysis of Cognitive and Affective Effects of Arduino-Based Educational Programs

  • Bong Seok Jang
    • Journal of information and communication convergence engineering
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    • v.22 no.2
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    • pp.153-158
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    • 2024
  • This study aims to summarize the effects of Arduino-based educational programs through a meta-analysis. Eleven eligible primary studies were obtained through a systematic literature review and coded accordingly. The results are as follows: The meta-analysis revealed that the overall effect size for all the studies was 0.518. Analysis of the moderator variables indicated statistically significant differences between them. Regarding the learning domains, the results were ranked in descending order of the cognitive and affective domains. Within the cognitive domain, the effect sizes were ranked in descending order as follows: logical thinking, content knowledge, convergence competency, self-efficacy, computational thinking, and creative problem-solving skills. In terms of subject areas, the descending order of effect sizes was agriculture, STEAM, environmental science, practical arts, artificial intelligence, informatics, and computers. Regarding school level, the results were ranked in the following descending order: college, elementary school, middle school, and high school.