• Title/Summary/Keyword: Orbital path

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Analysis of Spin Exchange Interactions in (C2N2H10)[Fe(HPO3)F3] on the Basis of Electronic Structure Calculations

  • Koo, Hyun-Joo
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.467-471
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    • 2011
  • Spin exchange interactions of $(C_2N_2H_{10})[Fe(HPO_3)F_3]$ were examined by performing a spin dimer analysis based on extended Huckel tight binding method and a mapping analysis based on first principles density functional theory. Spin exchange interactions occur through the super-superexchange paths $J_1$ and $J_2$ in $(C_2N_2H_{10})[Fe(HPO_3)F_3]$. In the super-superexchange path $J_2$ magnetic orbital interactions between eg-block levels are much stronger than those from $t_{2g}$-block levels. Both electronic structure calculations show that the spin exchange interaction through the super-superexchange path $J_2$ is much stronger than that of $J_1$.

Multi-path simulation for satellite-based positioning systems using 3D digital map of urban area

  • Hakamata, Tomohiro;Suh, Yong-Cheol;Konishi, Yusuke;Shibasaki, Ryosuke
    • Proceedings of the KSRS Conference
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    • 2003.11a
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    • pp.1015-1017
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    • 2003
  • Recently, DGPS or RTK-GPS techniques enable us to use satellite based positioning systems with high accuracy. But in urban area, navigation systems suffer from problems such as signal blockage by high-rise buildings, multi-path problems, and so on. So we have to know numbers of visible satellites and quality of signals received at the ground level in urban area as accurate as possible. In this paper, we developed a simulation system called LoQAS [Location service Quality Assessment System, 2002, the University of Tokyo] which can simulate numbers of visible satellites and DOP values using accurate satellite orbital data and 3-D digital map. In this time, we evaluated this system and extended it to deal with reflected signals to assess multi-path problems.

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Analysis and application of ocean currents information extracted from SAR satellite image (SAR 위성영상 해수유동 정보추출 및 활용)

  • Lee, Moon-Jin;Kim, Hey-Jin;Lee, Seung-Hyun;Hang, Key-Yong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.13 no.4
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    • pp.21-26
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    • 2007
  • A study on analysis and application of ocean currents information extracted from SAR (Synthetic Aperture Radar) satellite image. The current information extracted from SAR satellite image is not real vector information but scalar information in normal direction of orbital path. To correct current information extracted from satellite image, observation of currents in the field is carried out at the same time and area as those of satellite image. In the analysis, current information extracted from satellite image is corrected by using observed ones. By this correction, the speed and the direction of current can be estimated. The extract current information seem to agree well with the observed ones.

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Determination of Strongly Interacting Spin Exchange Path and Spin Lattice Model of (VO)2(H2O){O3P-(CH2)3-PO3}ㆍ2H2O on the Basis of Spin Dimer Analysis

  • Kim, Dae-Hyun;Koo, Hyun-Joo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.6
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    • pp.1665-1668
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    • 2010
  • The spin exchange interactions of $(VO)_2(H_2O){O_3P-(CH_2)_3-PO_3}{\cdot}2H_2O$ were examined by spin dimer analysis based on extended Huckel tight binding method. The strongest spin exchange interaction occurs through the super-superexchange path $J_2$ and the second strongest spin exchange interaction occurs through the superexchange interaction path $J_1$. There are two strongly interacting spin exchange paths in $(VO)_2(H_2O){O_3P-(CH_2)_3-PO_3}{\cdot}2H_2O$. Therefore, magnetic susceptibility curve of $(VO)_2(H_2O){O_3P-(CH_2)_3-PO_3}{\cdot}2H_2O$ can be well reproduced by an alternating onedimensional antiferromagnetic chain model rather than an isolated spin dimer model.

A Study on the Dynamic Behaviors of Engine Bearing with the Consideration of Elastic Deformation in the Con-Rod System (탄성변형을 고려한 엔진베어링의 동적 거동에 대한 연구)

  • Jang Siyoul;Park Gaemin
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.275-282
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    • 2004
  • The engine bearing transmits the powers from cylinder to crankshaft with small clearance between con-rod and crankpin. The minimum oil film thickness is a significant parameter in the operation of bearing. The contact pressure of bearing should be considered for the reason that elastic deformation of bearing be caused by contact pressure of bearing. There are important factors which are maintaining of minimum oil film thickness expecting of the length of maximum and minimum oil film thickness with changing of the loads to keep running normally. Furthermore, this study is very crucial to develop the design of engine bearing and crankshaft system.

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Approach to Frontal Sinus Outflow Tract Injury

  • Kim, Yong Hyun;Kim, Baek-Kyu
    • Archives of Craniofacial Surgery
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    • v.18 no.1
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    • pp.1-4
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    • 2017
  • Frontal sinus outflow tract (FSOT) injury may occur in cases of frontal sinus fractures and nasoethmoid orbital fractures. Since the FSOT is lined with mucosa that is responsible for the path from the frontal sinus to the nasal cavity, an untreated injury may lead to complications such as mucocele formation or chronic frontal sinusitis. Therefore, evaluation of FSOT is of clinical significance, with FSOT being diagnosed mostly by computed tomography or intraoperative dye. Several options are available to surgeons when treating FSOT injury, and they need to be familiar with these options to take the proper treatment measures in order to follow the treatment principle for FSOT, which is a safe sinus, and to reduce complications. This paper aimed to examine the surrounding anatomy, diagnosis, and treatment of FSOT.

SWEEP METHOD IN ANALYSIS OPTIMAL CONTROL FOR RENDEZ-VOUS PROBLEMS

  • Popescu, Mihai
    • Journal of applied mathematics & informatics
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    • v.23 no.1_2
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    • pp.243-256
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    • 2007
  • This paper deals with determining the sufficient conditions of minimum for the class of problems in which the necessary conditions of optimum are satisfied in the strengthened form Legendre-Clebsch. To this paper, we shall use the sweep method which analysis the conditions of existence of the conjugated points on the optimal trajectory. The study we have done evaluates the command variation on the neighboring optimal trajectory. The sufficient conditions of minimum are obtained by imposing the positivity of the second variation. The results that this method offers are applied to the problem o the orbital rendez-vous for the linear case of the equations of movement.

Determination of Reactivity by MO Theory (XX). An MO Theoretical Study on Mechanism of Thiocarbonyl Addition.

  • Lee, IK-Choon;Yang, Ki-Yull
    • Bulletin of the Korean Chemical Society
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    • v.2 no.4
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    • pp.132-138
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    • 1981
  • Ab initio molecular orbital calculations have been performed in an effort to determine which types of chemical interactions play essential roles for the system, , $H_2O+CH_2SH^+$, and $H_2O+ CH_2S$. The most important contribution to the interaction energy in controlling reaction path is the exchange repulsion energy, EX, which is largely responsible for the shape of the total interaction energy curve. In the ion-molecule reaction, prior protonation of thioformaldehyde or prior deprotonation of water leads to formation of the corresponding ionic adducts ($H_2O+CH_2SH$ and $HOCH_2S^-$), with no barrier to reaction, simulating specific acid and base catalysis, respectively, as in the case of formaldehyde. Otherwise, approach of water to thioformaldehyde gives rise to a completely repulsive interaction.

Effects of chemistry in Mars entry and Earth re-entry

  • Zuppardi, Gennaro
    • Advances in aircraft and spacecraft science
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    • v.5 no.5
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    • pp.581-594
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    • 2018
  • This paper is the follow-on of a previous paper by the author where it was pointed out that the forthcoming, manned exploration missions to Mars, by means of complex geometry spacecraft, involve the study of phenomena like shock wave-boundary layer interaction and shock wave-shock wave interaction also along the entry path in Mars atmosphere. The present paper focuses the chemical effects both in the shock layer and on the surface of a test body along the Mars orbital entry and compares these effects with those along the Earth orbital re-entry. As well known, the Mars atmosphere is almost made up of Carbon dioxide whose dissociation energy is even lower than that of Oxygen. Therefore, although the Mars entry is less energized than the Earth re-entry, one can expect that the effects of chemistry on aerodynamic quantities, both in the shock layer and on a test body surface, are different from those along the Earth re-entry. The study has been carried out computationally by means of a direct simulation Monte Carlo code, simulating the nose of an aero-space-plane and using, as free stream parameters, those along the Mars entry and Earth re-entry trajectories in the altitude interval 60-90 km. At each altitude, three chemical conditions have been considered: 1) gas non reactive and non-catalytic surface, 2) gas reactive and non-catalytic surface, 3) gas reactive and fully-catalytic surface. The results showed that the number of reactions, both in the flow and on the nose surface, is higher for Earth and, correspondingly, also the effects on the aerodynamic quantities.

A STUDY ON THE ARMILLARY SPHERE OF TONGCHEON-UI DESCRIBED BY HONG DAE-YONG (홍대용 통천의의 혼천의 연구)

  • MIHN, BYEONG-HEE;YUN, YONG-HYUN;KIM, SANG HYUK;KI, HO CHUL
    • Publications of The Korean Astronomical Society
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    • v.36 no.3
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    • pp.79-95
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    • 2021
  • This study aims to develop a restoration model of an armillary sphere of Tongcheon-ui (Pan-celestial Armillary Sphere) by referring to the records of Damheonseo (Hong Dae-Yong Anthology) and the artifact of an armillary sphere in the Korean Christian Museum of Soongsil University. Between 1760 and 1762, Hong, Dae-Yong (1731-1783) built Tongcheon-ui, with Na, Kyung-Jeok (1690-1762) designing the basic structure and Ann, Cheo-In (1710-1787) completing the assembly. The model in this study is a spherical body with a diameter of 510 mm. Tongcheon-ui operates the armillary sphere by transmitting the rotational power from the lantern clock. The armillary sphere is constructed in the fashion of a two-layer sphere: the outer one is Yukhab-ui that is fixed; and the inner one, Samsin-ui, is rotated around the polar axis. In the equatorial ring possessed by Samsin-ui, an ecliptic ring and a lunar-path ring are successively fixed and are tilted by 23.5° and 28.5° over the equatorial ring, respectively. A solar miniature attached to a 365-toothed inner gear on the ecliptic ring reproduces the annual motion of the Sun. A lunar miniature installed on a 114-toothed inner gear of the lunar-path ring can also replay the moon's orbital motion and phase change. By the set of 'a ratchet gear, a shaft and a spur gear' installed in the solstice-colure double-ring, the inner gears in the ecliptic ring and lunar-path ring can be rotated in the opposite direction to the rotation of Samsin-ui and then the solar and lunar miniatures can simulate their revolution over the period of a year and a month, respectively. In order to indicate the change of the moon phases, 27 pins were arranged in a uniform circle around the lunar-path ring, and the 29-toothed wheel is fixed under the solar miniature. At the center of the armillary sphere, an earth plate representing a world map is fixed horizontally. Tongcheon-ui is the armillary sphere clock developed by Confucian scholars in the late Joseon Dynasty, and the technical level at which astronomical clocks could be produced at the time is of a high standard.