• Title/Summary/Keyword: Optimal Synthesis

검색결과 569건 처리시간 0.031초

The SrLiAl3N4:Eu2+ Phosphor Synthesized by the Raw Material Model Obtained by DFT Calculations

  • Park, Woon Bae
    • 한국세라믹학회지
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    • 제54권3호
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    • pp.217-221
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    • 2017
  • Improvement studies of existing phosphors are needed for use in light emitting diodes (LEDs). Among the phosphors discovered recently, the SLA ($SrLiAl_3N_4:Eu^{2+}$) is a phosphor that has a narrow width. It is now known as a good red phosphor that meets the industry's needs for warm white (color temperature ranging from 2700 to 4000 K) and high CRI (> 80). However, SLA phosphors are obtained from difficult synthetic methods. All commercially available phosphors should be derived from the general solid state synthesis method. The phosphors produced by difficult synthetic methods will inevitably fall out of price competitiveness and will be scrapped. This study succeeded in synthesizing SLA ($SrLiAl_3N_4:Eu^{2+}$) phosphors by using a general solid phase synthesis method based on the reaction energy obtained from DFT calculations. As a result, we found an optimal solid state synthesis method for SLA phosphors.

Nonlinear optimal control for reducing vibrations in civil structures using smart devices

  • Contreras-Lopez, Joaquin;Ornelas-Tellez, Fernando;Espinosa-Juarez, Elisa
    • Smart Structures and Systems
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    • 제23권3호
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    • pp.307-318
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    • 2019
  • The frequently excessive vibrations presented in civil structures during seismic events or service conditions may result in users' discomfort, or worst, in structures failure, producing economic and even human casualties. This work contributes in proposing the synthesis of a nonlinear optimal control strategy for semiactive structural control, with the main characteristic that the synthesis considers both the structure model and the semiactive actuator nonlinear dynamics, which produces a nonlinear system that requires a nonlinear controller design. The aim is to reduce the unwanted vibrations in the response of civil structures, by means of intelligent fluid semiactive actuator such as the Magnetorheological Damper (MRD), which is a device with a low level of power consumption. The civil structures for which the proposed control methodology can be applied are those admitting a state-dependent coefficient factorized representation model, such as buildings, bridges, among others. A scaled model of a three storey building is analyzed as a case study, whose dynamical response involves displacement, velocity and acceleration of each one of the storeys, subjected to the North-South component of the September 19th., 2017, Puebla-Morelos (7.1M), Mexico earthquake. The investigation rests on comparing the structural response over time for two different conditions: with no control device installed and with one MRD installed between the first floor and the ground, where a nonlinear optimal signal for the MRD input voltage is determined. Simulation results are presented to show the effectiveness of the proposed controller for reducing the building's dynamical response.

회분식 공정의 최적 합성 (Optimal synthesis of batch processes)

  • 이호경;이인범;양대륙;장근수
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1993년도 한국자동제어학술회의논문집(국내학술편); Seoul National University, Seoul; 20-22 Oct. 1993
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    • pp.607-612
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    • 1993
  • In this paper, a heuristic procedure is presented which first determines the positions of adding storage tank. Then a nonlinear programming is formulated to obtain their optimum size. Flexible utilization(shared equipment) of storage tank is suggested. The effectiveness of this method is verified by solving two literature problems.

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Newly Expanded and Truncated Learning Algorithm for Optimal Synthesis of Binary Neural Network

  • Yun, Ki-Young;Jongwon Jeong;Sangkyu Sung;Lee, Joontark
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2002년도 ICCAS
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    • pp.103.2-103
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    • 2002
  • 1. Introduction 2. Structure of BNN 3. Decision of weight value and threshold value 4. Principle of Extension in the ETL algorithm 5. Approximation problem of one circular region 6. Problem of synthetic image having four class 7. Conclusion

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실험계획법을 이용한 MOF-5 합성공정 최적화 연구 (A Study of the Optimization of the MOF-5 Synthesis Process using Design of Experiments)

  • 이민형;이상민;유계상
    • 공업화학
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    • 제33권4호
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    • pp.402-407
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    • 2022
  • 실험계획법을 이용하여 MOF-5 합성공정의 최적화에 대한 연구를 수행하였다. 먼저 전구체의 농도를 최적화 하기 위하여 혼합물 설계법을 이용하였다. 합성에 사용되는 세 가지 전구체인 terephthalic acid, zinc acetate dihydrate, N,N-dimethylformamide의 농도비를 extreme vertices design methods로 최적화 하였다. MOF-5 합성을 위한 최적의 농도는 1 mol : 2.7 mol : 40 mol로 예측되었다. 이후, 온도, 시간 및 교반 속도와 같은 합성 반응 조건이 합성에 미치는 영향을 분석하기 위해 다단계 요인 설계법을 사용하였다. 수행된 통계 분석에 따라 교반 속도는 후속 연구에서 제외되었다. 합성시간과 온도를 고려한 합성 공정 최적화는 중앙 조성 설계법을 이용하였다. 13번의 합성 실험을 통해 도출된 2차 모델 방정식을 이용하여 결과를 추정하였다. 설계에 사용된 모델에 의하면 119 ℃ 및 10.4 h 조건에서 합성된 MOF-5가 최대의 결정화도를 가지는 것으로 예측되었다.

충돌수를 이용한 파이프라인 데이타패스 합성 스케쥴링 알고리즘 (A Scheduling Algorithm for the Synthesis of a Pipelined Datapath using Collision Count)

  • 유동진;유희진;박도순
    • 한국정보처리학회논문지
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    • 제5권11호
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    • pp.2973-2979
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    • 1998
  • 본 논문은 상위 수준 합성식의 자원 제약 조건하에서 파이프라인 데이타패스 합성을 위한 스케쥴링 알고리즘으로, 제안된 휴리스틱 알고리즘은 자원의 충돌수에 근거한 우선순위 함수를 사용한다. 자원 제약하에서 파이프라인 데이타패스 합성수를 정의하여 스케쥴링 한다. 제안 알고리즘은 실질적인 하드웨어 설계를 위해 체이닝, 멀티사이클링, 구조적 파이프라인이 지원되도록 한다. 제안 알고리즘에 의한 16 포인트 FIR 필터와 5차 엘립틱 웨이브 필터 합성 결과에 의해 다른 시스템들과의 성능을 비교하였으며, 대부분의 경우에 최적의 해를 찾을 수 있었다.

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에틸렌 역확산화염을 열원으로 사용하여 촉매금속 기판 상에 합성한 탄소나노튜브와 탄소나노섬유 (Synthesis of Multi-Walled Carbon Nanotubes and Nanofibers on a Catalytic Metal Substrate Using an Ethylene Inverse Diffusion Flame as a Heat Source)

  • 이교우;정종수;강경태;황정호
    • 대한기계학회논문집B
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    • 제28권9호
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    • pp.1081-1092
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    • 2004
  • The synthesis of Ni-catalyzed multi-walled carbon nanotubes and nanofibers on a catalytic metal substrate, using an ethylene fueled inverse diffusion flame as a heat source, was investigated. When the gas temperature was varied from 1,400K to 900K, approximately, carbon nanotubes with diameters of 20∼60nm were formed on the substrate. In the regions where the gas temperature was higher than 1,400K or lower than 900K, iron nanorods or carbon nanofibers were synthesized, respectively. Based on the quantitative analyses of large amount of SEM and TEM images, the nanotubes formed closer to the flame had a tendency of having larger diameters. HR-TEM images and Raman spectra revealed that carbon nanotubes synthesized had multi-walled structures with some defective graphite layers at the wall. Based on the graphite mode of the Raman spectra, it was believed that the optimal synthesis could be obtained as the substrate was positioned at between 5.5mm and 5.0mm, from the flame axis.

Discovery of D-Stereospecific Dipeptidase from Thermophilic Bacillus sp. BCS-l and Its Application for Synthesis of D-Amino Acid-Containing Peptide

  • Baek, Dae-Heoun;Kwon, Seok-Joon;Park, Jin-Seo;Lee, Seung-Goo;Mheen, Tae-Ick;Sung, Moon-Hee
    • Journal of Microbiology and Biotechnology
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    • 제9권5호
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    • pp.646-649
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    • 1999
  • A thermophilic bacterium producing D-stereospecific dipeptidase was isolated from Korean soil samples. The enzyme hydrolyzed the peptide bond between D-alanyl-D-alanine (D-Ala-D-Ala). The isolated bacterial strain was rod shaped, gram-positive, motile, and formed an endospore. Morphological and physiological characteristics suggested this microorganism a thermophilic Bacillus species, and was named as Bacillus sp. BCS-l. The production of D-stereospecific dipeptidase was growth-associated and optimal at $55^{\circ}C$. The enzyme was applied for the synthesis of D-amino acid-containing peptide, N-benzyloxycarbonyl-L-aspartyl-D-alanine benzyl ester (Z-L-Asp-D-AlaOBzl), as a model reaction. A thermodynamically controlled synthesis of Z-L-Asp-D-AlaOBzl was achieved in an organic solvent.

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Optimized Substrate Concentrations for Production of Long-Chain Isomaltooligosaccharides Using Dextransucrase of Leuconostoc mesenteroides B-512F

  • Lee, Min-Sung;Cho, Seung-Kee;Eom, Hyun-Ju;Kim, So-Young;Kim, Tae-Jip;Han, Nam-Soo
    • Journal of Microbiology and Biotechnology
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    • 제18권6호
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    • pp.1141-1145
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    • 2008
  • Isomaltooligosaccharide (IMO) is a promising dietary component with prebiotic effect, and the long-chain IMOs are preferred to short chain ones owing to the longer persistence in the colon. To establish the optimal process for synthesis of long-chain IMOs, we systematically examined the reaction condition of dextransucrase of Leuconostoc mesenteroides B-512F by changing the ratio of sucrose to maltose (varying as 1:4, 1:2, 1:1, and 2:1) and amount of each sugar (from 2% to 20%). As a result, a ratio of 2:1 (sucrose to maltose, 10:5% or 20:10%, w/v) was determined as an optimal condition for long-chain IMO synthesis (DP3-DP9) with relatively higher yields (70-90%, respectively).