• 한국표면공학회지
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• 제42권5호
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• pp.246-249
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• 2009

Cu-Ti alloys with titanium in the range of 0.5-6.0 wt% were developed to evaluate the effect of the titanium content and heat treatment on microstructure, hardness, and electrical conductivity. The hardness of the Ti-added copper alloys generally increased with the increase in titanium content and hardening was effective up to the 2.5 wt%-Ti addition. Microstructural examination showed that the second phase of $Cu_4Ti$ started to precipitate out from the 3.0 wt% Ti-addition, and the precipitate size and volume fraction increased with further Ti addition. Aging of the present Cu-Ti alloys at $450^{\circ}C$ for 1 h increased the hardness; however, the further aging up to 10 h did not much change the hardness. In the present study, it was inferred that in optimal Ti addition and aging condition Cu-Ti alloy could have the hardness and electrical conductivity values which are comparable to those of commercial Cu-Be alloy.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1990년도 하계학술대회 논문집
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• pp.183-186
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• 1990

The lattice mismatch between ZnS and Si is negligible because of its value being 0.39%. In this study, $ZnS/_{(P)}Si$ solar cell were fabricated as a layer of ZnS is epitaxially grown on a silicon substrate by PVD method and its photovoltaic properties were measured and discussed. The heat treatment was done after deposition. As the temperature increased up to a certain value, the film has better perfection in crystal structure and electrical characteristics. Measurments of the change that occur in the ZnS films were made by SEM., X-ray diffraction. The optimal thickness of film showned $0.6{\mu}m$, being measured by SEM. The great improvement of the grain growth ZnS film came out after heat-treatment. The result obtained from the $ZnS/_{(P)}Si$ solar cell as follows:short circuit current; $I_{sc}=54mA/cm^2$,open voltage; $V_{oc}=400mV$, fill factor FF=0.72, conversion efficiency; ${\eta}=15.6%$ under the irradiation of 100 ($mW/cm^2$) focused by solar energy. And these are discussed in comparison with other kinds.

• Corrosion Science and Technology
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• 제22권2호
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• pp.131-136
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• 2023

The aim of this study was to investigate effects of microstructure control on hydrogen diffusivity, trap activation energy, and cracking behaviors of high-strength steel using a range of experimental techniques. Results of this study showed that susceptibility to hydrogen induced cracking (HIC) was significantly associated with hydrogen diffusivity and trap activation energy, which were primarily influenced by the microstructure. On the other hand, microstructural modifications had no significant impact on electrochemical polarization behavior on the surface at an early corrosion stage. To ensure high resistance to HIC of the steel, it is recommended to increase the cooling rate during normalizing to avoid formation of banded pearlite in the microstructure. However, it is also essential to establish optimal heat treatment conditions to ensure that proportions of bainite, retained austenite (RA), and martensite-austenite (MA) constituents are not too high. Additionally, post-heat treatment at below A₁ temperature is desired to decompose locally distributed RA and MA constituents.

• 대한기계학회논문집A
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• 제41권3호
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• pp.219-224
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• 2017

본 연구는 수송기계 축 등에 이용되는 캠 형상 부분만을 기존의 단조품인 SF45와 축 부분은 일반기계구조용 탄소강재인 SM45C를 직경 20 mm를 이용하여 이종 마찰용접을 수행하였다. 최적조건을 규명하기 위해 인장시험 등 용접품질과의 상관관계를 고찰하였고, 또한 최적조건에서 마찰용접 후 열처리를 시행하여 용접재(As-welded)와 후열처리재(PWHT)에 대한 회전굽힘 피로시험을 시행하였다. 결과적으로 두 이종재가 강한 혼합으로 계면에서도 개재물 및 산화막이 플래시로 토출되어 양호한 접합상태임을 확인하였다. 더욱이 모재(SF45)와 후열처리재의 피로한도 각각 180 MPa, 250 MPa로 나타났다. 이는 후열처리재가 SF45 모재에 비해 약 40 %의 피로수명이 향상되었음을 확인하였다.

• 한국산학기술학회논문지
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• 제19권2호
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• pp.660-667
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• 2018

본 연구에서는 천안시 병천 하수종말처리장의 '열건조물'로 고형연료를 제조하기 위하여 유중건조 공정의 최적 조건을 선정하는 연구를 수행하였다. 연구결과물의 특성을 평가하기 위하여 $130^{\circ}C$, $160^{\circ}C$, $190^{\circ}C$의 온도조건에서 '유증발량 측정실험' 및 '열건조물의 유중건조 실험'을 수행하였으며, 칼로리미터와 TGA 장비를 이용하여 고형연료의 성능을 측정하였다. 또한 휴대용 복합악취측정기를 이용하여 유중건조 중 복합악취, 암모니아, 황화수소 및 총 휘발성 유기화합물의 발생농도를 측정하고, EDS 장비를 이용하여 성분분석 연구를 수행하였다. 대량생산을 고려하여 기름과 열건조물의 무게비를 임의의 비율인 4:1로 고정하였고, $130^{\circ}C$에서는 일부 내부수의 순간적인 건조 이후 기름과 열건조물의 물리적인 혼합만이 진행된다고 판단된다. 환경 친화적인 측면을 고려하였을 때, $160^{\circ}C$와 $190^{\circ}C$의 건조효율에 큰 차이가 없으므로 $160^{\circ}C$의 건조온도에서 5분 이내로 처리하는 것을 최적 조건으로 선정하였다. 본 연구에서 재조한 고형연료의 신뢰성을 확보하기 위해 화력발전소 현장연료와의 성능비교 연구를 진행한 결과 발열량 4,449kcal/kg, 함수율 2%, 회분함량 34%로 현재 사용 중인 현장연료보다 대체로 우수한 성능을 나타내었으므로 기존의 목재펠릿 뿐만 아니라 석탄에너지 또한 충분히 대체할 수 있을 것이라 판단된다.

• Restorative Dentistry and Endodontics
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• 제22권1호
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• pp.254-266
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• 1997

This study was to know the usefulness of argon laser for composite resin, to prove the polymerized effect of heat treatment of composite resin inlay and to get the curing method for optimal physical properties of composite resin inlay. In this study we used four light curing units and one heat curing unit: Visilux $II^{TM}$, a visible light gun: $SPECTRUM^{TM}$, an argon laser: Unilux AC$^{(R)}$ and Astorn XL$^{(R)}$, visible light curing unit: CRC-$100^{TM}$ for heat treatment. Compared to a control group, we divided the experemental groups into five as follows: Control group: Light curing(Visilux $II^{TM}$) Experimental group 1 : Light curing(Visilux $II^{TM}$) + Light curing(Unilux AC$^{(R)}$) Experimental group 2: Light curing(Visilux $II^{TM}$) + Light curing(Astron XL$^{(R)}$) + Heat treatment(CRC-$100^{TM}$) Experimental group 3 : Laser curing($SPECTRUM^{TM}$) Experimental group 4 : Laser curing($SPECTRUM^{TM}$) + Light curing(Unilux AC$^{(R)}$) Experimental group 5 : Laser curing($SPECTRUM^{TM}$) + Light curing(Astron XL$^{(R)}$) + Heat treatment (CRC-$100^{TM}$) According to the above classification, we made samples through the curing of Clearfil CR Inlay$^{(R)}$, which is a composite resin for inlay, in a separable cylindrical metal mold and polycarbonate plate. And then, we measured and compared the value of compressive strength, diametral tensile strength and the surface micro hardness of each sample. The results were as follows : 1. Among the experimental groups, group 5 showed the highest value of compressive strength, $157.50{\pm}10.24$ kgf and control group showed the lowest value of compressive strength, $103.93{\pm}21.93$ kgf. Control group showed significant difference with the experimental groups(p<0.001). Group 2 which was treated by the heat showed higher compressive strength than that of group 1 which was not, and there was significant difference between group 1 and group 2(p<0.001). Group 5 which was treated by heat showed higher compressive strength than group 4 which was not, and there was significant difference group 4 and group 5(p<0.001). 2. Among the experimental groups, group 5 showed the highest value of diametral tensile strength, $95.84{\pm}1.97$ kgf and control group showed the lowest value of diametral tensile strength, $81.80{\pm}2.17$ kgf. Control group which was cured by visible light showed higher diametral tensile strength than group 3 which was cured Argon Laser. Group 2 which was treated by heat showed higher compressive strength than that of group 1 which was not, and there was significant difference between group 1 and group 2(p<0.001). Group 5 which was treated by heat showed higher compressive strength than group 4 which was not, and there was a significant difference group 4 and group 5(p<0.001). 3. Among the experimental groups, group 5 showed the highest value of microhardness of top surface, $148.42{\pm}9.57$ kgf and control group showed the lowest value of microhardness, $111.43{\pm}7.63$ kgf. In the case of bottom surface, group 5 showed the highest value of $146.19{\pm}7.62$ kgf, and control group showed the lowest, $104.03{\pm}11.05$ kgf. Group 3 which was cured by Argon Laser showed higher diametral tensile strength than control group which was cured only with a visible light gun. Group 2 which was treated by heat showed higher compressive strength than that of group 1 which was not, and there was a significant difference between group 1 and group 2(p<0.001). Group 5 which was treated by heat showed higher compressive strength than group 4 which was not, and there was a significant difference group 4 and group 5(p<0.001). 4. According to the above results, we took a conclusion that argon laser can be used as a useful unit for curing the composite resin and heat treatment can improve the physical properties of the composite resin inlay.

• 한국해양공학회지
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• 제30권1호
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• pp.51-56
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• 2016

In this study, for the tube-to-tube friction welding of hose nipple materials, the main parameters of friction welding were investigated using tensile tests, Vickers hardness surveys of the bond area (HAZ), and observations of the microstructure to increase the quality of friction welding based on visual examination. As-welded and post weld heat treated (PWHT) specimens were tested. The optimal welding conditions were found to be n = 1000 rpm, HP = 10 MPa, UP = 15 MPa, HT = 9 s, and UT = 5 s when the metal loss (Mo) was 7.5 mm. Furthermore, the peak of the hardness distribution of the friction welded joints could be eliminated by PWHT. Moreover, the two materials of the friction weld were thoroughly mixed with a well-combined structure of micro-particles, without any molten material, particle growth, or defects.

• 한국해양공학회지
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• 제26권1호
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• pp.64-69
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• 2012

Dissimilar friction welds were produced using 15-mm diameter solid bars of chrome molybdenum steel (KS SCM440) and carbon steel (KS SM20C) to investigate their mechanical properties. The main friction welding parameters were selected to ensure good quality welds on the basis of visual examination, tensile tests, Vickers hardness surveys of the bond area and HAZ, and macro-structure investigations. The specimens were tested as-welded and post-weld heat treated (PWHT). The tensile strength of the friction welded steel bars was increased to 100% of the SM20C base metal under the condition of a heating time of more than four seconds. Optimal welding conditions were n = 2,000 (rpm), HP = 60 (MPa), UP = 100 (MPa), HT = 5 (s),and UT = 5 (s), when the total upset length was 7.8 (mm). The hardness distribution peak of the friction welded joints could be eliminated using PWHT. The two different kinds of materials were strongly mixed to show a well-combined structure of macro-particles, with no molten material, particle growth, or defects.

• 한국염색가공학회지
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• 제35권4호
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• pp.231-238
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• 2023

Microporous gel films of 29 m were prepared by the gel drawing of UHMWPE/soybean oil blend (4:6, w/w) up to 800%. The stretched films containing the optimal photoinitiator concentration, depending on the film thickness, was cross-linked under 365 nm LED-UV irradiation and the oil was extracted with n-hexane, resulting in a gel fraction of 95 % or more. With the formation of the cross-linked structure, the melt-down temperature and melt-down elongation increased by 16 ℃ and by 63% respectively. Also the thermal stability of the crosslinked UHMWPE was proved by the area shrinkage under the heat treatment decreased to 3.8 % compared to 17.4 % for the pristine film, and by the reductions in the combustion heat. The enhanced thermal stability of the crosslinked UHMWPE microporous membranes can be used for various industrial applications such as filters, electric vehicles and energy storage systems.

• Journal of Microbiology and Biotechnology
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• 제34권5호
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• pp.1119-1125
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• 2024

Phytase increases the availability of phosphate and trace elements by hydrolyzing the phosphomonoester bond in phytate present in animal feed. It is also an important enzyme from an environmental perspective because it not only promotes the growth of livestocks but also prevents phosphorus contamination released into the environment. Here we present a novel phytase derived from Turicimonas muris, TmPhy, which has distinctive structure and properties compared to other previously known phytases. TmPhy gene expressed in the Pichia system was confirmed to be 41 kDa in size and was used in purified form to evaluate optimal conditions for maximum activity. TmPhy has a dual optimum pH at pH3 and pH6.8 and exhibited the highest activity at 70℃. However, the heat tolerance of the wildtype was not satisfactory for feed application. Therefore, random mutation, disulfide bond introduction, and N-terminal mutation were performed to improve the thermostability of the TmPhy. Random mutation resulted in TmPhyM with about 45% improvement in stability at 60℃. Through further improvements, a total of three mutants were screened and their heat tolerance was evaluated. As a result, we obtained TmPhyMD1 with 46.5% residual activity, TmPhyMD2 with 74.1%, and TmPhyMD3 with 66.8% at 80℃ heat treatment without significant loss of or with increased activity.