• Title/Summary/Keyword: Optical pH sensor

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Spectroscopic study on the development of fiber-optic pH sensor (광섬유 pH 센서 개발을 위한 분광학적 연구)

  • Yoo, Wook-Jae;Heo, Ji-Yeon;Cho, Dong-Hyun;Jang, Kyoung-Won;Seo, Jeong-Ki;Lee, Bong-Soo;Cho, Young-Ho;Moon, Joo-Hyun;Park, Byung-Gi
    • Journal of Sensor Science and Technology
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    • v.18 no.5
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    • pp.365-371
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    • 2009
  • In this study, we have fabricated a fiber-optic pH sensor which is composed of a light source, plastic optical fibers and a spectrometer. As an indicator, a phenol red is used, and a pH liquid solution is prepared by mixing of phenol red and various kinds of pH buffer solutions in these experiments. The emitting light from a light source is guided by plastic optical fibers to the pH liquid solution, and the optical characteristic of a light is changed in the pH liquid solution according to its color change. Therefore, we have measured the intensities and wavelength shifts of the modulated lights, which are changed due to the color variations of phenol red at different pH values, by using of a spectrometer for spectral analysis. Also, the relationships between the pH values of liquid solutions and the optical properties of modulated light according to the change of color of phenol red are obtained.

Development of a Fiber-optic Noncontact Temperature Sensor for Measuring the Temperature of Cooled Secondary Water in a Nuclear Power Plant (냉각된 원전 2차계통수의 온도측정을 위한 비접촉식 광섬유 온도센서의 개발)

  • Yoo, Wook-Jae;Lee, Bong-Soo;Park, Byung-Gi;Cho, Young-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1730-1734
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    • 2010
  • Generally, a pH value of secondary water in a nuclear power plant should be estimated after sampling and cooling down. In this process, the measurement of temperature is very important because a pH value is varied according to the temperature of secondary water. In this study, a noncontact fiber-optic temperature sensor using a silver halide optical fiber is fabricated to measure the temperature of cooled secondary water. And we have measured an infrared radiation, which is transferred by a silver halide optical fiber from a heat source, using a thermopile sensor. The relationships between the temperature of a heat source and the output voltage of the fiber-optic temperature sensor according to the change of distance and angle are determined. The measurable temperature range of the fiber-optic temperature sensor is from 25 to $60^{\circ}C$. Based on the results of this study, a noncontact temperature sensor using a silver halide optical fiber can be developed for the temperature measurement of the pH sample in the secondary water system.

Study on Optical Characteristics of pH Indicators in the Immobilized Film for Fiber-Optic pH Sensor (광학적 pH 센서를 위한 지시염료가 고정된 필름의 광학적 특성 연구)

  • Kim, Beom Kyu;Park, Byung Gi
    • Journal of Sensor Science and Technology
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    • v.26 no.6
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    • pp.414-419
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    • 2017
  • The optical characteristics of cresol red, phenol red, and neutral red immobilized in the thin film were investigated with absorbance measurement in order to find a sensing part of a fiber-optic pH sensor. Sol-Gel method with tetramethyl orthosilicate as a precursor was used to immobilize the pH indicators in the thin film. The absorbance spectra were measured when pH indicators were immobilized in the film and were dissolved in the buffer solution. Experimental results showed that the absorbance spectra could be changed when the pH indicator is immobilized in the thin film. As compared with other pH indicators, the neutral red exhibited similar absorbance spectra regardless of physical conditions and was sensitive over whole pH range between 4 and 11. In addition, the absorbance ratio of base peak to acid peak tended to increase in proportion to the increase in pH. Experimental results indicate that the neutral red is a good pH indicator for fabrication of a sensing part of the fiber-optic pH sensor.

Characteristics and Fabrication of Dissolved Oxygen and pH Measurement System based on the Optical Sensor for Analysis of Cell Metabolic Functions (세포대사 기능 분석을 위한 광학센서 기반 용존산소와 pH 측정 시스템의 제작 및 특성 분석)

  • Jang, Jiwoon;Hwang, Insook;Lee, Jongmok;Lee, Sunmin;Kang, Sora;Kim Pak, Youngmi;Kim, Nayoung
    • Journal of Sensor Science and Technology
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    • v.25 no.1
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    • pp.51-56
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    • 2016
  • This study evaluates the performance of an optical sensor and measurement system (CMA-24) which can analyze the fluctuation of dissolved oxygen and pH simultaneously. In the optical sensor system, the fluorescent materials, Rudpp and HPTS which are sensitive to dissolved oxygen and pH, respectively, are coated on the bottom of a 24-well -plate by the sol-gel technology. The detection times of the emission light of the oxygen sensor were $4,186{\pm}13.90{\mu}s$ and $4,452{\pm}36.68{\mu}s$ for the dissolved oxygen of 17% $O_2$ and 7.6% $O_2$, respectively. On the other hand, the detection times of the pH sensor were $6,699.43{\pm}14.64{\mu}s$, $6,722.24{\pm}6.21{\mu}s$, and $6,748.52{\pm}2.63{\mu}s$ using pH 6, 7, and 8, respectively. When we determined cellular respiration levels of C2C12 myocytes with CMA-24, $O_2$/pH measurement system, the ratio of the uncoupled to coupled OCR (oxygen consumption rate) was 1.41. The results mean that this CMA-24 system shows almost the same sensitiveness as the commercial system.

Development of Reflection-type Fiber-optic pH Sensor Using Sol-gel Film (졸-겔 필름을 이용한 반사형 광섬유 pH 센서의 개발)

  • Yoo, Wook-Jae;Seo, Jeong-Ki;Jang, Kyoung-Won;Moon, Jin-Soo;Han, Ki-Tek;Park, Jang-Yeon;Lee, Bong-Soo;Cho, Seung-Hyun;Heo, Ji-Yeon;Park, Byung-Gi
    • Journal of Sensor Science and Technology
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    • v.20 no.4
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    • pp.266-271
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    • 2011
  • A reflection-type fiber-optic pH sensor, which is composed of a pH sol-gel film, plastic optical fibers, a mirror, a light source and a spectrometer, is developed in this study. As pH indicators, a bromthymol blue, a cresol red and a thymol blue are used, and they are immobilized in the sol-gel films. The emitted light from a light source is guided by a fiber-optic Y-coupler and plastic optical fibers to the pH sol-gel film in a pH sensing probe. The pH change in the sensing probe gives rise to a change in the color of the pH sol-gel film, and the optical characteristic of reflected light through the pH sol-gel film is also changed. Therefore, we have measured the spectra of reflected lights, which are changed according to the color variations of the pH sol-gel films with different pH values, by using of a spectrometer. Also, the relationships between the pH values and the intensities of reflected lights are obtained on the basis of the color variations of the pH sol-gel films.

Optical Voltage Sensor Using $SiO_2$ Pockels Cell ($SiO_2$ 포켈 소자를 이용한 광전압센서)

  • Shin, K.H.;Chun, J.P.;Cho, H.K.;Kim, S.K.;Kim, Y.H.;Kim, Y.S.;Park, H.S.
    • Proceedings of the KIEE Conference
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    • 1991.07a
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    • pp.846-849
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    • 1991
  • This paper reports the principle, system confiquration, test results of optical voltage sensor using quartz pockels cell. The Pockels effect of quartz material is used for designing optical voltage sensor. The quarts material has very high half-wave voltage, so, it can be applied to measure high voltage level. Experimental results show that the optical voltage sensor has excellent linear characteristics within the applied AC voltage of 1200V.

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Feasibility Study on the Development of Fiber-Optic pH Sensor for Endoscope (내시경용 광섬유 pH 측정 센서 개발을 위한 기초 연구)

  • Lee, Bong-Soo;Hong, Ju-Young;Hwang, Young-Muk;Cho, Seung-Hyun
    • Journal of Sensor Science and Technology
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    • v.13 no.3
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    • pp.213-217
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    • 2004
  • The general method to find a H. pylori in the stomach is the rapid urease test but it is only used to decide the infection with H. pylori. In this study, it is tried to develope fiber-optic pH sensor which can be used with gastroscop to quantify H. pylori. To measure the degree of infection with H. pylori, the color change of phenol red according to the degree of pH is measured by optical fibers with different light sources and the optimum distance from a sample to the end of sensor tip is decided by measuring the maximum reflectivity from a sample. Also the sensitivity study is carried out to decide the optimum light source which has sensitive change of reflectivity to the change of pH. It is expected that the fiber-optic pH sensor which measures the degree of infection with H. pylori exactly can be developed.

A pH Optosensor Based on Fluoresence from Nile Blue Encapsulated within Silica Sol-Gel Film (실리카 졸-겔막을 이용한 pH 광학센서)

  • Lee, Jung-Min;Li, Ming;Lee, Sang-Hak;Kim, Young-Sun;Kim, Chang-Jin;Lee, Boo-Huyng
    • Journal of Sensor Science and Technology
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    • v.13 no.3
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    • pp.169-174
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    • 2004
  • A fiber optic pH sensor has been fabricated using nile blue entrapped in an ammonia catalyzed silica sol-gel film coated on glass substrate by dip-coating. The sensor was fixed on the end of an optical fiber. The sensor showed pH sensitivity when dipped into liquids at different pHs. Linear and reproducible responses were obtained in standard buffer solutions in the pH range $6.0{\sim}8.5$, which encompasses the clinically-relevant range. The effects of interferences on the determination of pH were also investigated. The sensors were successfully applied to the determination of pH in different commercial ionic drinks.

Study on pH Sensor using Methylene Blue Adsorption and A Long-Period Optical Fiber Grating Pair

  • Jeon Young-Hee;Kwon Jae-Joong;Lee Byoung-Ho
    • Journal of the Optical Society of Korea
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    • v.10 no.1
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    • pp.28-32
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    • 2006
  • We propose a new pH-sensing scheme using a methylene blue adsorption on an optical fiber cladding surface. Interactions between the silica and hydroxyl ions of a base solution induce the surface of the silica negatively charged. The charged surface attracts the positively charged chromophores of methylene blue. As the pH of the solution is reduced, the electrostatic attraction will also be reduced. This electrostatic attraction can change the transmitted light intensity of the cladding mode, since the boundary condition changes. We also carried out a simulation to verify the effect from external refractive index change around a long-period fiber grating. Our results confirm that the wavelength shift by external refractive index change is negligible compared to the transmitted light intensity variation of the cladding mode. By using a long-period grating pair, we can detect the cladding mode transmittance variations. Experimentally, we showed the possibility of pH sensing in the $1.5{\mu}m$ infrared region.

Characterization of gold nanoparticles on optical fiber for localized surface plasmon resonance sensor (광섬유 국소화 표면 플라즈몬 공명 센서를 위한 광섬유 표면상의 금 나노 입자 특성 분석)

  • Lee, Hoon;Lee, Seung-Ki
    • Journal of Sensor Science and Technology
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    • v.18 no.3
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    • pp.226-233
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    • 2009
  • In this study, the optical properties of localized surface plasmon resonance sensor using optical fiber was analyzed as the variation of a size and surface density of gold nano particles on the etched optical fiber surface. It is shown that a size and surface density of gold nano particles on optical fiber surface are controlled by $Na_3$ citrate quantity and pH of gold colloid solution. To measure the sensitivity, peak wavelength of absorbance spectrum was detected as the reflective index of the solution. The sensor sensitivity is linearly dependent on the size and surface densities of gold nano particles from the results of optical experiments.