• Title/Summary/Keyword: Optical materials

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Preparation and Characterization of UV-cured Polyurethane Acrylate/ZnO Nanocomposite Films (자외선 경화형 폴리우레탄 아크릴레이트/ZnO 나노콤포지트 필름의 제조 및 특성 분석)

  • Jeon, Gwonyoung;Park, Su-il;Seo, Jongchul;Seo, Kwangwon;Han, Haksoo;You, Young Chul
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.610-616
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    • 2011
  • A series of polyurethane acrylate/ZnO (PUA/ZnO) nanocomposite films with different ZnO contents were successfully prepared via a UV-curing system. The synthesis and physical properties including morphological structure, thermal properties, barrier properties and optical properties, and antimicrobial properties were investigated as a function of ZnO concentration. FTIR and SEM results showed that these PUA/ZnO nanocomposite films did not have a strong interaction between PUA and ZnO, which may lead to no increase in thermal stability. By incorporating ZnO nanoparticles, the UV blocking and antibacterial properties increased as the content of ZnO increased. Specially, the oxygen permeability in composite films changed from $2005cc/m^2/day$ to $150cc/m^2/day$ by adding the ZnO nanoparticle, which indicates that the PUA/ZnO nanocomposite films can be applied as good barrier packaging materials. Physical properties of the UV-cured PUA/ZnO nanocomposite film are strongly dependent upon the dispersion state of ZnO nanoparticles and their morphology in the films.

Laser Fabrication of Graphene-based Materials and Their Application in Electronic Devices (레이저 유도에 의한 그래핀 합성 및 전기/전자 소자 제조 기술)

  • Jeon, Sangheon;Park, Rowoon;Jeong, Jeonghwa;Hong, Suck Won
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.1
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    • pp.1-12
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    • 2021
  • Here, we introduce a laser-induced graphene synthesis technology and its applications for the electric/electronic device manufacturing process. Recently, the micro/nanopatterning technique of graphene has received great attention for the utilization of these new graphene structures, which shows progress developments at present with a variety of uses in electronic devices. Some examples of practical applications suggested a great potential for the tunable graphene synthetic manners through the control of the laser set-up, such as a selection of the wavelength, power adjustment, and optical techniques. This emerging technology has expandability to electric/electronic devices combined together with existed micro-packaging technology and can be integrated with the new processing steps to be applied for the operation in the fields of biosensors, supercapacitors, electrochemical sensors, etc. We believe that the laser-induced graphene technology introduced in this paper can be easily applied to portable small electronic devices and wearable electronics in the near future.

Design and Evaluation of IMI Multilayer Hybrid Structure-based Performance Enhanced Surface Plasmon Resonance Sensor for Biological Analysis (생물학적 분석용 IMI 하이브리드 다중레이어 구조 기반 성능 향상된 표면 플라즈몬 공명 센서의 설계 및 특성 분석)

  • Song, Hyerin;Ahn, Heesang;Kim, Kyujung
    • Korean Journal of Optics and Photonics
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    • v.33 no.4
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    • pp.177-186
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    • 2022
  • The performance of a surface plasmon resonance sensor is evaluated based on the sensitivity (nm/RIU) and sharpness from the full width at half maximum (FWHM) and the peak depth of a resonance peak. These factors are determined by the materials and conformational properties of the sensing structure. In this paper, we investigated an optimized insulator-metal-insulator (IMI) multilayer-based surface plasmon resonance sensor structure to simultaneously achieve high sensitivity, narrow FWHM, and deep peak depth while using gold for the metallic film layer which occurs peak broadening. By adopting the optimized structure, sensitivity of 8,390 nm/RIU, FWHM of 11.92 nm, and a resonance peak depth of 93.1% were achieved for 1.45-1.46 refractive index variation of the sensing layer. With the suggested structure conformation, high sensitivity and resolution of sensing performance can be achieved.

Construction Method of ECVAM using Land Cover Map and KOMPSAT-3A Image (토지피복지도와 KOMPSAT-3A위성영상을 활용한 환경성평가지도의 구축)

  • Kwon, Hee Sung;Song, Ah Ram;Jung, Se Jung;Lee, Won Hee
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.40 no.5
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    • pp.367-380
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    • 2022
  • In this study, the periodic and simplified update and production way of the ECVAM (Environmental Conservation Value Assessment Map) was presented through the classification of environmental values using KOMPSAT-3A satellite imagery and land cover map. ECVAM is a map that evaluates the environmental value of the country in five stages based on 62 legal evaluation items and 8 environmental and ecological evaluation items, and is provided on two scales: 1:25000 and 1:5000. However, the 1:5000 scale environmental assessment map is being produced and serviced with a slow renewal cycle of one year due to various constraints such as the absence of reference materials and different production years. Therefore, in this study, one of the deep learning techniques, KOMPSAT-3A satellite image, SI (Spectral Indices), and land cover map were used to conduct this study to confirm the possibility of establishing an environmental assessment map. As a result, the accuracy was calculated to be 87.25% and 85.88%, respectively. Through the results of the study, it was possible to confirm the possibility of constructing an environmental assessment map using satellite imagery, optical index, and land cover classification.

New Yellow Quinoline Derivatives Including Dione Moiety for Image Sensor Color Filters (이미지 센서 컬러 필터용 다이온 성분을 포함하는 신규 황색 퀴놀린 유도체)

  • Sunwoo, Park;Seyoung, Oh;Yuna, Kang;Hyukmin, Kwon;Sunwoo, Dae;Changyu, Lee;Dae Won, Kim;Min-Sik, Jang;Jongwook, Park
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.80-85
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    • 2023
  • New yellow quinoline-dione dye derivatives were designed and synthesized for use in image sensor color filters. The synthesized compounds have a basic chemical structure composed of quinoline and dione groups. New materials were evaluated on the basis of their optical and thermal properties under conditions mimicking those of a commercial device fabrication process. A comparison of their related performances revealed that, between the two prepared compounds, 2-(3-hydroxyquinolin-2(1H)-ylidene)-1H-indene-1,3(2H)-dione (HQIDO) exhibited the superior performance as an image sensor color filter material, including a solubility greater than 0.5 wt% in propylene glycol monomethyl ether acetate solvent and a high decomposition temperature of 298 ℃, respectively. The results suggest that HQIDO can be used as a yellow dye additive in an image sensor colorant.

Effect of Binder and Electrolyte on Electrochemical Performance of Si/CNT/C Anode Composite in Lithium-ion Battery (리튬이온 이차전지에서 Si/CNT/C 음극 복합소재의 전기화학적 성능에 대한 바인더 및 전해액의 효과)

  • Choi, Na Hyun;Kim, Eun Bi;Yeom, Tae Ho;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.60 no.3
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    • pp.327-333
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    • 2022
  • In this study, silicon/carbon nanotube/carbon (Si/CNT/C) composites for anode were prepared to improve the volume expansion of silicon used as a high-capacity anode material. Si/CNT were prepared by electrostatic attraction of the positively charged Si and negatively charged CNT and then hydrothermal synthesis was performed to obtain the spherical Si/CNT/C composites. Poly(vinylidene fluoride) (PVDF), polyacrylic acid (PAA), and styrene butadiene rubber (SBR) were used as binders for electrode preparation, and coin cell was assembled using 1.0 M LiPF6 (EC:DMC:EMC = 1:1:1 vol%) electrolyte and fluoroethylene carbonate (FEC) additive. The physical properties of Si/CNT/C anode materials were analyzed using SEM, EDS, XRD and TGA, and the electrochemical performances of lithium-ion batteries were investigated by charge-discharge cycle, rate performance, dQ/dV and electrochemical impedance spectroscopy tests. Also, it was confirmed that both capacity and rate performance were significantly improved using the PAA/SBR binder and 10 wt% FEC-added electrolyte. It is found that Si/CNT/C have the reversible capacity of 914 mAh/g, the capacity retention ratio of 83% during 50 cycles and the rate performance of 70% in 2 C/0.1 C.

Optically transparent ultrasound transducers for combined ultrasound and photoacoustic imaging: A review (초음파-광음향 융합 영상을 위한 투명 초음파 변환기)

  • Shunghun Park;Jin Ho Chang
    • The Journal of the Acoustical Society of Korea
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    • v.42 no.5
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    • pp.441-451
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    • 2023
  • Ultrasound transducers are an essential component of combined photoacoustic and ultrasound imaging systems and play an important role in image evaluation. However, ultrasound transducers are opaque; therefore, light must bypass the ultrasound transducer to reach the target point to produce a photoacoustic image. Providing different paths for the optical and acoustic signals results in a complicated system design, increasing the system volume. To overcome these problems, an optically Transparent Ultrasound Transducer (TUT) was developed. Unlike conventional opaque ultrasound transducers, optically TUT can be fabricated by a variety of manufacturing methods and they are suitable for use with specific piezoelectric elements and serve various purposes. In this study, a comparative analysis of the results of using Lithium Niobate (LNO), Lead Magnesium Niobate-Lead Titanate (PMN-PT), and Polyvinylidene Difluoride (PVDF), which are materials used in piezoelectric element-based TUT. LNO is a piezoelectric element widely used in TUT, and PMN-PT has been actively studied recently with a higher transmission and reception rate than LNO. Existing TUT have lower ultrasound resolution than photoacoustic resolution, but they have recently been manufacturing focused TUT with high ultrasound resolution using PVDF. A comparative analysis of the production results of these TUT was performed.

Interfacial and Durability Evaluation of Jute and Hemp Fiber/Polypropylene Composites Using Micromechanical Test and Acoustic Emission (미세역학적시험법과 음향방출을 이용한 Jute 및 Hemp 섬유/폴리프로필렌 복합재료의 내구성 및 계면 평가)

  • Kim, Pyung-Gee;Jang, Jung-Hoon;Kim, Sung-Ju;Hwang, Byung-Sun;Park, Joung-Man
    • Composites Research
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    • v.20 no.3
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    • pp.55-62
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    • 2007
  • Interfacial evaluation and durability of Jute and Hemp fibers/polypropylene (PP) composites were investigated. Moisture content of various treated conditions were measured by thermogravimetic analyzer (TGA). After boiling water test, mechanical properties and IFSS between Jute, Hemp fibers and PP matrix decreased. On the other hand, work of adhesion increased due to swelled fibril by water. Surface energies of Jute and Hemp fibers before and after boiling water test were obtained using dynamic contact angle measurement. IFSS was not always consistent with thermodynamic work of adhesion. In boiling water case, since Jute and Hemp fibers could be swelled by water, surface area and moisture infiltration space increased. Environmental effect on microfailure modes of Jute or Hemp fibers and Jute or Hemp fibers/PP composites were obtained by observing via optical microscope and by monitoring acoustic emission (AE) events and their AE parameters. After boiling water test, unlike Hemp fiber, microfailure process of Jute fiber could occur due to low tensile strength by swelled fibril. In addition, AE events occurred more and AE amplitude and energy became lower than those of before boiling water test.

Clinical Results of Subtotal Fasciectomy for Treatment of Dupuytren Contracture (아전 근막절제술을 이용한 듀피트렌 구축의 치료 결과)

  • Lee, Yoon-Min;Song, Seok-Whan;Kim, Yong-Woo;Choi, Jae-Hoon
    • Journal of the Korean Orthopaedic Association
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    • v.54 no.4
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    • pp.353-360
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    • 2019
  • Purpose: In the treatment of Dupuytren's contracture, the aim of optical treatment is to lower the recurrence rate and reduce complications. This paper reports the results of subtotal fasciectomy in Dupuytren's contracture, extending the excision of palmar fascial structures from the diseased to normal appearing adjacent fascial structure. Materials and Methods: From 2007 to 2017, 45 patients with Dupuytren's contracture treated by subtotal fasciectomy were reviewed retrospectively. The mean follow-up period was 45.9 months. Ninety-two digits were involved (index: 2, middle: 10, ring: 44, little: 36). The predisposing factors and affected joint were reviewed and the preoperative and postoperative contracture was measured. For clinical results, quick disabilities of the arm, shoulder, and hand (quick DASH) were used. Complications, including wound or skin problems, nerve injuries, hematoma, and complex regional pain syndrome, were assessed. Results: Preoperative flexion contracture was 43.2° in the proximal interphalangeal joint and 32.9° in the metacarpophalangeal joint. In nine cases, patients had residual contracture of 9.7° (range, 5°-20°) on average and if the total number of cases were included, the mean residual contracture was 2.3° on average. The quick DASH score at the 12 months follow-up was 12.4. The overall complication rate was 26.6%. Conclusion: Subtotal fasciectomy can be a good surgical treatment option for Dupuytren's contracture with a low recurrence and low complication rate compared to other open procedures.

Guided-mode Resonances in Periodic Surface Structures Induced on Si Thin Film by a Laser (레이저에 의해 생성된 Si 박막의 주기적 표면 구조에서의 도파모드 공진 연구)

  • Ji Hyuk Lee;Yoon Joo Lee;Hyun Hong;Eun Sol Cho;Ji Young Park;Ju Hyeon Kim;Min Jin Kang;Eui Sun Hwang;Byoung-Ho Cheong
    • Korean Journal of Optics and Photonics
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    • v.34 no.6
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    • pp.241-247
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    • 2023
  • We examine the spectral characteristics of laser-induced periodic surface structures (LIPSSs) formed on an amorphous silicon film irradiated by a 355-nm nanosecond laser. A Gaussian beam with a diameter of 196 ㎛ is used to perform a two-dimensional raster scan. The laser's pulse number is varied from 190 to 280, and its intensity is adjusted within 100-130 mJ/cm2. LIPSSs with a periodicity of approximately 330 nm form on the surface of the Si film, aligned perpendicular to the laser's polarization. Transmission spectra of the samples show dips around 700 nm for transverse electric polarization and around 500 nm for transverse magnetic polarization. The features are investigated with a one-dimensional-grating model using a rigorous coupled-wave analysis. Simulations confirm that the observed dips are due to the resonant modes, depending on the polarization.