• Proceedings of the Materials Research Society of Korea Conference
• /
• 2003.11a
• /
• pp.131-131
• /
• 2003

The advent of photonic technologies in the field of communications and data transmission has been heavily increasing the demand in integrated optical (IO) circuits capable of accomplishing not only simple tasks like signal, but also more sophisticated functions like all-optical signal routing or active multiplexing/demultiplexing. In the last decade, sol-gel technology has been widely used to prepare optical materials. Sol-gel processes show many promises for the development of low-loss, high-performance glass integrated optical circuits. However, crack formation is likely to occur during heat treatment in thick gel films. In order to overcome the critical thickness limitation, the organic-modified silicate has been widely used. In this case coating matrices have been prepared from the organo-silanes of T structures, acidic catalyst and the as-prepared gel films have been heat-treated below 200$^{\circ}C$ to avoid the crack formation and the degradation of organic components. However, the films prepared in the acidic condition and the low heat temperature make the films contain high OH groups which is the major optical loss function. In this work, C$\sub$6/H$\sub$5/SiO$\sub$1.5/ films were prepared on silicon substrate by sol-gel method using base catalyst in a PTMS/NH$_4$OH/H$_2$O/C$_2$H$\sub$5/OH system. The sol showed spinable viscosity at 50 wt% of solid content, and neglectable viscosity change with time. The films were crack-free and transparent after curing at 450 $^{\circ}C$, and highly condensed to minimize OH content in C$\sub$6/H$\sub$5/SiO$\sub$1.5/ networks. The effects of heat treatment of the films are characterized on the critical thickness, the chemical composition and the refractive indices by means of SEM, FT-IR, TGA, prism coupler, respectively.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2001.10a
• /
• pp.57-60
• /
• 2001

In order to extend the life time of building and civil infra-structure, nowadays, patch type fibrous composite materials are widely used. Retrofitted concrete columns and beams gain the stiffness and strength, but they lose toughness and show brittle failure. Usually, the cracks of concrete structures are visible with naked eyes and the status of the structure in the life cycle is estimated with visible inspection. After retrofitting of the structure, crack visibility is blocked by retrofitted composite materials. Therefore, structural monitoring after retrofitting is indispensible and self diagnosis method with optical fiber sensor is very useful. In this paper, We try to detect peel out effect and find the strain difference between main structure and retrofitting patch material when they separate each other.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2006.11a
• /
• pp.83-84
• /
• 2006

For phase transition method, good recording sensitivity, low heat radiation, fast crystallization and hi-resolution are essential. Also, A retention time is very important part for phase transition. In our presentation wall, we chose Ge-Se-Te material to use a Se material which has good optical sensitivity than Sb. A Ge-Se-Te sample was fabricated and Irradiated with He-Ne laser and DPSS laser to investigate a reversible phase change by light.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2011.05a
• /
• pp.7.2-7.2
• /
• 2011

Photoelectrochemical solar cells such as dye-sensitized cells (DSSCs), which exhibit high performance and are cost-effective, provide an alternative to conventional p-n junction photovoltaic devices. However, the efficiency of such cells plateaus at 11~12%, in contrast to their theoretical value of 33%. The majority of research has focused on improving energy conversion efficiency of DSSC by controlling nanostructure and exploiting new materials in photoelectrode consisting of semiconducting oxide nanoparticles and a transparent conducting oxide electrode (TCO). In this presentation, we introduce monodisperesed TiO2 nanoparticles prepared by forced hydrolysis method and their superiority as photoelectrode materials was characterized with aids of optical and electrochemical analysis. Inverse opal-based scattering layers containing highly crystalline anatase nanoparticles are also introduced and their feasibility for use as bi-functional light scattering layer is discussed in terms of optical reflectance and charge generation properties as a function of optical wavelength.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.23 no.5
• /
• pp.224-229
• /
• 2013

Vanadium oxide thin films were deposited on $c-Al_2O_3$ (001) substrate by in-situ RF magnetron sputtering. Oxygen partial pressure was adjusted to prepare thermochromic $VO_2$ phase. X-ray diffraction patterns and scanning electron microscopy convincingly showed that plate-like $V_2O_5$ grains were changed into round-shape $VO_2$ grains as oxygen partial pressure decreased. After the optimized deposition conditions were fixed, the effect of substrate temperature and orientation on the optical properties of $VO_2$ thin films was analyzed.

• Proceedings of the Optical Society of Korea Conference
• /
• 2000.02a
• /
• pp.224-225
• /
• 2000

Transparent and hard materials such as sapphire are used for many industrial applications as optical windows, hard materials on mechanical contact against abrasion, and substrate materials for opto-electronic semiconductor devices such as blue LED and blue LD etc. The materials should be cut along the proper shapes possible to be used for each application. In case of blue LED, the blue LED wafer should be cut to thousands of blue LED pieces at the final stage of the manufacturing process. The process of cutting the wafer is usually divided into two steps. The wafer is scribed along the proper shapes in the first step. It is inserted between transparent flexible sheets for easy handling. And then, it is broken and split in the next step. Harder materials such as diamonds are usually used to scribe the wafer, while it has a problem of low depth of scribing and abrasion of the harder material itself. The low depth of scribing can induce failure in breaking the wafer along the scribed line. It was also known that the expensive diamond tip should be replaced frequently for the abrasion. (omitted)

• Textile Coloration and Finishing
• /
• v.24 no.4
• /
• pp.233-238
• /
• 2012

The opto-functional materials have been developed as a promising research topic toward the end uses for optical materials and applications. The attractive area in this part was the design of sensor molecules for detecting harmful environmental factors. These harmful factors impart undesired effects on wide range of chemical and biological phenomenon. In this context, many researchers have studied luminescence chemosensor materials. These sensor molecules showed optical signals such as color or fluorescence change by detecting harmful environmental factors. In this study, the novel fluorescence chemosensor 1 has been designed and synthesized through reaction of rhodamine 6g hydrazide and 2-hydroxy-1-naphthaldehyde. The chemosensor 1 had been analyzed by UV-Vis and fluorescence spectrophotometer. We found that this chemosensor 1 has 'off-on' and dual type sensing properties toward $Cu^{2+}$ and $Mg^{2+}$.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.28 no.1
• /
• pp.9-13
• /
• 2018

In this work, we investigated the variation of optical characteristics with the thickness of bulk GaN grown by hydride vapor phase epitaxy(HVPE) to evaluate applicability as GaN substrates in fabrication of high-brightness optical devices and high-power devices. We fabricated 2-inch GaN substrates by using HVPE method of various thickness (0.4, 0.9, 1.5 mm) and characterized the optical property with the variation of defect density and the residual stress using chemical wet etching, Raman spectroscopy and photoluminescence. As a result, we confirmed the correlation of optical properties with GaN crystal thickness and applicability of high performance optical devices via fabrication of homoepitaxial substrate.

• Journal of the Optical Society of Korea
• /
• v.16 no.3
• /
• pp.236-242
• /
• 2012

In general, such methods as interferometers or wavefront sensors are commonly used for testing of an optical system and optical components. In these cases, the surrounding environments are unlikely to affect the measurements. On the other hand, intraocular lenses of hydrophilic materials with special properties experience a certain difficulty in testing the optical properties. An intraocular lens is dried in the air, which causes deformation and changes the optical characteristics such as index of refraction and thickness. Thus, it is hard to measure the optical characteristics of an intraocular lens by using common methods. In this study, a special structure is used for measuring of the transmission wavefront aberration and effective focal length of an intraocular lens of hydrophilic materials by using a Shark-Hartmann sensor among the various measuring methods. As an application of this measuring method, this study shows a simple method to measure the index of refraction of unknown liquids with a plano-convex lens with a well known index of refraction. Also, this method is used to measure the optical properties of a plano-convex such as index of refraction and curvature by using a liquid with a well known index of refraction.

• Journal of Photoscience
• /
• v.10 no.2
• /
• pp.203-208
• /
• 2003

Two coupled molecules were successfully synthesized by condensation of amine-donor-substituted barbituric acid derivativies as nonlinear optical chromophores. A flexible spacer of the alkyl chain with different lengths of carbon chains (5 and 6 carbons) was introduced between two chromophores, which prevented crystallization and aggregation of molecules. Two coupled molecules (B-Cn-B, n=5, 6) had glass-transition temperatures on a second heating around 81 and 76$^{\circ}C$ without melting points, respectively. To explore the linear optical properties, thin-films were prepared and examined by a photometry method using Nd:YVO$_4$ CW laser. Also, microscopic and macroscopic nonlinear optical properties were measured by Hyper-Rayleigh Scattering (HRS) and the Maker Fringes method using Nd:YAG ps pulse laser, respectively. In spite of the moderate hyperpolarizabilities of coupled molecules, the second order NLO coefficient (d$\_$33/) was larger than the conventional Disperse Red 1 doped PMMA polymeric system.