• Bulletin of the Korean Chemical Society
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• v.28 no.7
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• pp.1175-1182
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• 2007

A series of new organic semiconductors hexyl end-capped thiophene-anthracene oligomers containing the anthracene moiety in the center of the oligomers are synthesized. The target oligomers have been obtained by Stille coupling reactions as key step reactions. The synthesized thiophene-anthracene oligomers were characterized by 1H-NMR, 13C-NMR and high-resolution mass spectroscopy, respectively. All of the oligomers are soluble in chlorinated solvents. Their optical, thermal and electrochemical properties were measured. The hexyl end-capped oligomers and their unsubstituted oligomers exhibit the same absorption behavior in dilute toluene solution. Hexyl end-capped bis-terthienylanthracene oligomer is observed to show liquid crystalline mesophase at 166 oC in heating process. The thermal analyses as well as the electrochemical measurement data indicate that the designed materials show better thermal and oxidation stability than the corresponding oligothiophenes without anthracene core. Fluorescence lifetimes and fluorescence quantum yields of the thiophene-anthracene oligomers are measured to be 10-14 ps and 3.4-9.9 × 10?3 which are much shorter and lower than those of oligothiophenes respectively.

• Transactions of The Korea Fluid Power Systems Society
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• v.7 no.2
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• pp.1-6
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• 2010

A new type fiber optic sensing system has been developed as a commercially available standard using the technique of hetero-core spliced fiber optic sensor, for the purposes of monitoring large scaled structures, preserving natural environments and measuring physical phenomenons. The sensing system has been tested and evaluated in a possible outdoor condition in view of the full scaled operation at actual sites to be monitored. Additionally, the developed system in this work conveniently provides us with various options of sensor modules intended to measure such physical quantities as displacement, distortion, pressure, binary states and liquid adhesion. The experiment study has been performed to examine the performance to a pseudo-cracking experiment in the outdoor situation, and to clarify temperature influences to the system in terms of the coupling of optical connectors and the OTDR stability. It has been verified that the sensing system is robust to the temperature change ranging from the general condition to the hard condition. Especially, in this study, the specification and performances of the pressure sensor have been demonstrated to show the capability of inspecting various physical quantities.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.39-39
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• 2010

The authors have an extensive study of photoluminescences for Zn-polar and O-polar faces of single-crystalline ZnO bulks. In the photoluminescence (PL) spectra at 10 K, Zn-polar and O-polar faces show a common emission feature: neutral donor-bound excitons and their longitudinal-optical (LO) phonon replicas are strong, and free excitons are very weak. However, in the PL spectra at room temperature (RT), Zn-polar and O-polar faces show extremely different emission characteristics: the emission intensity of Zn-polar face is 30 times larger than that of O-polar face, and the band edge of Zn-polar face is 33 meV red-shifted from that of O-polar face. The temperature dependence of photoluminescence indicates that the PL spectra at RT are closely associated with free excitons and their phonon-assisted annihilation processes. As a result, it is found that the RT PL spectra of Zn-polar face is dominated by the first-order LO phonon replica of A free excitons, while that of O-polar face is determined by A free excitons. This is ascribed that Zn-polar face has larger exciton-phonon coupling strength than O-polar face.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.11a
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• pp.28-31
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• 1999

Carbon fiber/epoxy composites using electrodeposited monomeric and polymeric coupling agents were compared with the dipping and the untreated cases. Treating conditions such as time, concentration and temperature were optimized. Four-fibers embedded micro-composites were prepared for fragmentation test. Interfacial properties of four-fiber composites with different surface treatments were investigated with simultaneous acoustic emission (AE) monitoring. The microfailure mechanisms occurring from fiber break, matrix and interlayer crackings were examined by AE parameters and an optical microscope. It was found that interfacial shear strength (IFSS) of electrodeposited carbon fibers was much higher than the other cases under dry and wet conditions. Well separated and different-shaped AE groups occurs for the untreated and ED treated case, respectively.

• Korean Journal of Optics and Photonics
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• v.6 no.1
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• pp.21-25
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• 1995

Q-switched Waveguide $CO_{2}$ laser using polygon mirror were constructed and their output characteristics were measured. Waveguide was made of the beryllium oxide tube of inner diameter of 2 mm, outer diameter of 20 mm, and length of 200 mm. A flat ZnSe output coupler of 80% reflectivity was placed on the 9 mm distance from the end of the waveguide. Convex lens was used to reduce the coupling loss between the polygon mirror and the waveguide. The polygon mirror was located behind of convex lens. With this condition, continuous output of the laser were measured as 1.2 W. In the Q-switched mode. pulse width 120 ns were measured with rotational speed 7,559 RPM. and peak power of up to 250 W. 250 W.

• Polymer(Korea)
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• v.28 no.6
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• pp.538-544
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• 2004

Polyurethanes containing L-lysine segments in the main chain (PULL) were synthesized from 4,4'-diphenymethyl diisocynate, poly(tetramethylene glycol), and z-lysine oligomer as a chain extender. Insulin-immobilized polyurethanes (PULL-In) were prepared by a coupling reaction of PULL surface amino groups with insulins. The amount of immobilized insulin was about 0.30 nmol/$\textrm{cm}^2$, as determined by Bradford method. The interactions of NIH/3T3 fibroblasts with surface-modified PULLs were investigated using $^3$H-thymidine incoporation and optical microscopy. The cell growth rate on PULL-In film was higher than those on other substrates. The cell proliferation by the immobilized insulin was almost same as that by the free one.

• Macromolecular Research
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• v.11 no.4
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• pp.250-255
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• 2003

We prepared the photorefractive sol-gel glass based on organic-inorganic hybrid materials containing a charge transporting molecule, second-order nonlinear optical (NLO) chromophore, photosensitizer, and plasticizer. Carbazole and 2-{ 4-[(2-hydroxy-ethyl)-methyl-amino]-benzylidene}-malononitrile were reacted with isocyanato-triethoxy silane and the functionalized silanes were employed to fabricate the efficient photorefractive media induding 2,4,7-trinitrot1uorenone (TNF) to form a charge transfer complex. The prepared sol-gel glass samples showed a large net gain coefficient and high diffraction efficiency at a certain composition. As the concentration of photosensitizer increased, the photorefractive properties were enhanced due to an increment of charge carrier density. Dynamic behavior of the diffraction efficiency was also investigated with the concentration of the photosensitizer.

• Korean Journal of Crystallography
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• v.11 no.3
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• pp.137-146
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• 2000

The stoichiometric mix of evaporating materials for he CuInS₂ single crystal thin films was prepared. To obtain the single crystal thin films, CuINS₂ mixed crystal was deposited on etched semi-insulator GaAs(100) substrate by the hot wall epitaxy(HWE) system. The source and substrate temperature were 640℃ and 430℃, respectively and the thickness of the single crystal thin films was 2 ㎛. The crystalline structure of single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction(DCXD). The carrier density and mobility deduced from Hall data are 9.64x10/sup 22//㎥ and 2.95x10/sup -2/ ㎡/V·s, respectively at 293 K. he optical energy gap was found to be 1.53 eV at room temperature. From the photocurrent spectrum obtained by illuminating perpendicular light on the c-axis of the thin film, we have found that the values of spin orbit coupling splitting ΔSo and the crystal field splitting ΔCr were 0.0211 eV and 0.0045 eV at 10K, respectively. From PL peaks measured at 10K, were can assign the 807.7 nm (1.5350 eV) peak to E/sub x/ peak of the free exciton emission, the 810.3 nm(1.5301 eV) peak to I₂ peak of donar-bound exciton emission and the 815.6 nm(1.5201 eV) peak to I₁ peak of acceptor-bound excition emission. In addition, the peak observed at 862.0 nm(1.4383 eV) was analyzed to be PL peak due to donor-acceptor pair(DAP).

• Korean Journal of Optics and Photonics
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• v.19 no.1
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• pp.25-30
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• 2008

In this paper, a novel architecture for device miniaturization of multimode interference-based (MMI) couplers is proposed. The coupling length of $N{\times}N$ MMI couplers scales as the square of the MMI region width so that the use of these structures with large-N ports can require large chip size. To solve the design problem, the butterfly grating-assisted MMI couplers, that have smaller device dimensions than conventional MMI couplers, are discussed and evaluated. Numerical simulations and novel design rules for such structures derived through theoretical analysis are presented.

• Korean Journal of Optics and Photonics
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• v.12 no.4
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• pp.289-293
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• 2001

A metal capillary splice fiber-optic sensor was fabricated for use as an intensity-based macro-bending sensor. As the radius of curvature due to the macro-bending decreases, the angular misalignment of the fiber ends inside the metal capillary increases, i.e., the coupling efficiency of the fiber splice is reduced. Thus, macro-bending can be detected by the measurement of the reduction of transmitted power. The detectable range of macro-bending. was measured approximately from 20 mm to 85 mm. The center wavelengths of the fiber Bragg gratings are 1543.3 nm and 1549.5 nm, respectively. The maximum bending loss of this sensor was measured about -11.92 dB. Using this metal capillary spliced fiber sensor and fiber Bragg gratings, macro-bending detection has been demonstrated, and it is shown to have potential for multi-point macro-bending sensors. nsors.