• Title/Summary/Keyword: Optical conductivity

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Impact of Phonon Dispersion on Thermal Conductivity Model (포논 분산이 열전달 모델에 미치는 영향)

  • Chung, Jae-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.8
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    • pp.1165-1173
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    • 2003
  • The effects of (1) phonon dispersion on thermal conductivity model and (2) differentiation of group velocity and phase velocity are examined for germanium. The results show drastic change of thermal conductivity regardless of the same relaxation time model. Also the contribution of transverse acoustic (TA) phonon and longitudinal acoustic (LA) phonon on the thermal conductivity at high temperatures is reassessed by considering more rigorous dispersion model. Holland model, which is commonly used for modeling thermal conductivity, underestimates the scattering rate for TA phonon at high frequency. This leads the conclusion that TA is dominant heat transfer mode at high temperatures. But according to the rigorous consideration of phonon dispersion, the reduction of thermal conductivity is much larger than the estimation of Holland model, thus the TA at high frequency is expected to be no more dominant heat transfer mode. Another heat transfer mechanism may exist at high temperatures. Two possible explanations we the roles of (1) Umklapp scattering of LA phonon at high frequency and (2) optical phonon.

Characterization and Fabrication of Tin Oxide Thin Film by RF Reactive Sputtering (RF Reactive Sputtering법에 의한 산화주석 박막의 제조 및 특성)

  • Kim, Young-Rae;Kim, Sun-Phil;Kim, Sung-Dong;Kim, Sarah Eun-Kyung
    • Korean Journal of Materials Research
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    • v.20 no.9
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    • pp.494-499
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    • 2010
  • Tin oxide thin films were prepared on borosilicate glass by rf reactive sputtering at different deposition powers, process pressures and substrate temperatures. The ratio of oxygen/argon gas flow was fixed as 10 sccm / 60 sccm in this study. The structural, electrical and optical properties were examined by the design of experiment to evaluate the optimized processing conditions. The Taguchi method was used in this study. The films were characterized by X-ray diffraction, UV-Vis spectrometer, Hall effect measurements and atomic force microscope. Tin oxide thin films exhibited three types of crystal structures, namely, amorphous, SnO and $SnO_2$. In the case of amorphous thin films the optical band gap was widely spread from 2.30 to 3.36 eV and showed n-type conductivity. While the SnO thin films had an optical band gap of 2.24-2.49 eV and revealed p-type conductivity, the $SnO_2$ thin films showed an optical band gap of 3.33-3.63 eV and n-type conductivity. Among the three process parameters, the plasma power had the most impact on changing the structural, electrical and optical properties of the tin oxide thin films. It was also found that the grain size of the tin oxide thin films was dependent on the substrate temperature. However, the substrate temperature has very little effect on electrical and optical properties.

Optical and Electrical Characteristics of viologen-diTCNQ thin film prepared by Langmuir-Blodgett Technique (LB법을 이용한 viologen-diTCNQ 박막의 광학적 및 전기적 특성)

  • 이용수;신동명;김태완;강도열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.45-48
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    • 1997
  • Enhancing the electrical conductivity of the ultrathin organic films is one of the important factors for the development of molecular electronic devices. The Langmuir-Blodgett(LB) technique has recently been attracted interest as the a method of deposition ultrathin films. We have fabricated N-docosyl-N'-methyl viologen-diTCNQ(DMVT) anion radical LB film and investigated the optical and electrical conductivity. We have measured UV/visible and FT-lR spectrum. In ESR spectrum, we confirmed that a half-amplitude linewidth is clearly dependent on both temperature and incident angle, which indicates conducting species change. The in-plane electrical conductivity of 21 layers is approximately 1.37$\times$10$^{-6}$ (S/cm).

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Normal-state charge dynamics of ternary platinum germanide superconductor La2Pt3Ge5

  • Song, S.J.;Sung, N.H.;Cho, B.K.;Moon, S.J.
    • Progress in Superconductivity and Cryogenics
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    • v.17 no.4
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    • pp.12-15
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    • 2015
  • We report on the infrared spectroscopic studies of the normal-state electronic response of rare-earth ternary platinum germanide superconductor $La_2Pt_3Ge_5$. We analyzed the temperature-dependent optical conductivity spectra using the Drude-Lorentz oscillator model. We found that the two Drude responses with distinct scattering rates are required to explain the charge dynamics at 10 K while a single Drude mode could reproduce the far-infrared conductivity at higher temperatures. Our results indicated the two-band character of the electronic structure and highlighted the disparate temperature evolution of the electrodynamics of the two electronic states.

Thermal Conduction in Transparent Carbon Nanotube Films

  • Zhu, Lijing;Kim, Duck-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.201-201
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    • 2012
  • Using materials with high thermal conductivity is a matter of great concern in the field of thermal management. In this study, we present our experimental results on an important physical property of carbon nanotube (CNT) films, two-dimensional thermal conductivity obtained by using an optical method based on Raman spectroscopy. We prepared four kinds of CNT films to investigate the effect of CNT type on heat spreading performance of films. This first comparative study using the optical method shows that the arc-discharge single-walled carbon nanotubes yield the best heat spreading film. And we observed thermal conductivity values of CNT films with various transmittances and found that the Raman method works as long as the sample is a transparent film. This study provides useful information on characterization of thermal conduction in transparent CNT films and could be an important step toward high-performance carbon-based heat spreading films.

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Electrical Conductivity and Optical Properties of Elongated Conducting Polymer (연신도전성고분자의 전기전도와 광학적 특성)

  • 박대희;강성화;임기조
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.59-62
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    • 1994
  • Tact Electrical conductivity. optical absorption spectra of poly(p-phenylene vinylene) and their dependence on stretching are discussed in detail. The conductivity in the parallel direction to the stretching is higher over one order in magnitude than that in the perpendicular direction to the stretching is higher over one order in magnitude than that in the perpendicular direction to the stretching. The photocurrent spectrum for the ligh polarized parallel to the chain direction is much enhanced in lower photon energy compared with that for the light polarized perpendicular to that direction. The result may be originated in the difference of energies which is needed to photogenerate carriers wi th the light polarized parallel and perpendicular to the chain stretched direction.

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Characteristics of Hybrid Optical Pickup Actuator at High Temperature (하이브리드형 광픽업 액추에이터의 고온특성)

  • Lee, Jin-Won;Kim, Kwang;Cheong, Young-Min;Kim, Dae-Whan
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.11b
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    • pp.1010-1014
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    • 2002
  • A new type actuator has been designed and investigated to overcome thermal problems in slim optical disc drive which is adopted in mobile storage devices. Recently, in optical storage device technical trends, the size of optical disc drives is slimmer to adopt notebook computer and the spindle rotate velocity is faster to achieve high transfer rate and the power of actuator is higher to perform tilting, etc. However, these trends of optical disc drives tend to raise the environment temperature of drives, actuator power and parts temperature. Moreover, it is more difficult to remove the heat inside a drive and the temperature of an actuator increases and drive slims. As a result, increase of surface temperature of actuator body caused that second resonance of an actuator moves down to a lower frequency band and the performance of optical parts also deteriorates. Especially objective lens, coil and magnet of the actuator parts are easily damaged. To manage these thermal problems, in this paper an actuator with a hybrid blade, which is composed of vectra which has low thermal conductivity and magnesium which has high thermal conductivity, has been suggested and verified. Despite the high temperature environment, the proposed actuator showed good dynamic performance.

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Changes fo Electric conductivity of Amorphous Silicon by Argon radical Annealing

  • Lee, Jae-Hee
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.63-63
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    • 1999
  • The stability of hydrogenated amorphous silicon (a-Si:H) films under the light soaking are very important since the applications of a-Si:H films are solar cells, color sensors, photosensors, and thin film transistors(TFTs). We found the changes of the electric conductivity and the conductivity activation energy (Ea) of a-Si:H films by argon radical annealing. The deposition rate of a-Si:H films depends on the argon radical annealing time. The optical band gap and the hydrogen contents in the a-Si:H films are changes along the argon radical annealing time. We will discuss the microscopic processes of argon radical annealing in a-si:H films.

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The analysis on the optical properties of $Cd_1-_xZn_xS$ films deposited by CBD method (CBD법을 이용한 Cd1-xZnxS 박막의 광학적 특성분석)

  • Son, W.C.;Lee, J.H.;Kim, J.H.;Moon, J.S.;Park, Y.K.;Yang, K.J.
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1649-1651
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    • 2000
  • Optical properties of $Cd_{1-x}Zn_{x}S$ films deposited by :chemical bath deposition(CBD), which is a very attractive method for low-cost and large-area solar cells, are presented, Especially, in order to control more effectively the zinc component of the films, zinc acetate, which used as the zinc source, mixed in reaction solution after preheating and the pH of the reaction solution decreased with increasing the concentration of zinc acetate. The films prepared after preheating and pH control had larger zinc component and higher optical band gap. As the more zinc substituted for Cd in the films, the optical transmittance improved, while the absorption edge shifts to a shorter wavelength and the optical band gap increased. The photo conductivity of the films was larger than the dark conductivity, while the ratio of those increased with increasing the mole ratio of zinc acetate.

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Optical properties of LK-99 and Cu2S

  • Hong Gu Lee;Yu-Seong Seo;Hanoh Lee;Yunseok Han;Tuson Park;Jungseek Hwang
    • Progress in Superconductivity and Cryogenics
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    • v.26 no.2
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    • pp.1-4
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    • 2024
  • We investigated Pb10-xCux(PO4)6 (0.9 < x < 1.1) (LK-99) and Cu2S, presumed to be contained as an impurity in LK-99, in a wide spectral range from far infrared to ultraviolet using optical spectroscopy. The optical conductivity spectra of both samples were obtained from measured reflectance spectra at various temperatures from 80 to 434 K. Both samples showed several infrared-active phonons in the far and mid-infrared regions. LK-99 showed typical insulating features with a band gap of ~1 eV. Cu2S showed a nonmonotonic temperature-dependent trend and two energy gaps: one energy gap of ~93 meV and a band gap of 2.42 eV. Our results indicate that LK-99 cannot be a superconductor because it is an insulator with a large band gap.