• 제목/요약/키워드: Optical and structural properties

검색결과 931건 처리시간 0.029초

박막태양전지 버퍼층 적용을 위해 RF 스퍼터링 및 급속열처리 공정으로 제작한 황화아연 박막의 구조적 광학적 특성 (Structural and Optical Properties of ZnS Thin Films Fabricated by Using RF Sputtering and Rapid Thermal Annealing Process for Buffer Layer in Thin Film Solar Cells)

  • 박찬일;전영길
    • 한국전자통신학회논문지
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    • 제15권4호
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    • pp.665-670
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    • 2020
  • CIGS 박막 태양 전지의 버퍼층은 흡수층과 윈도우층 사이의 밴드정렬(band alignment)을 통해 에너지 변환 효율을 향상시킨다. ZnS는 무독성의 II-VI 반도체 화합물로서 직접천이형 광대역 밴드갭과 n형 전도성을 가지며, 높은 광투과성, 높은 굴절률 등의 우수한 전기적, 광학적 특성을 가지고 있고, 우수한 격자정합을 가지는 물질이다. 이 연구에서, RF 마그네트론 스퍼터링 방법에 의해 증착 후 급속 열처리에 의해 제작된 ZnS 버퍼층 박막의 구조적, 광학적 특성의 상관관계에 대해 고찰하였다. (111), (220), (311) 면의 섬아연광 입방정 구조를 확인할 수 있고, 상대적으로 저온에서 급속열처리를 수행한 시료에서는 (002) 면의 우르쯔광 육방정 구조가 함께 나타나는 다결정이 되었다. 고온에서 급속열처리 수행한 시료에서는 섬아연광 입방정 구조의 단결정으로 상전이 된다. 화학적 성분 분석을 통해서 Zn/S의 비율이 화학양론에 근접한 시료에서 섬아연광 입방정 구조의 단결정이 나타났음을 확인하였다 급속열처리 온도가 증가할수록 흡수단이 다소간 단파장 쪽으로 이동되고, 가시광 파장 범위에서 평균 광투과율이 증가하는 경향성을 보이며 500℃ 조건에서는 80.40%로 향상되었다.

펄스레이저 증착법에 의한 polyethersulfone 기판상의 ZnO박막의 특성 (The characteristics of ZnO Thin film on PES substrate by pulsed laser deposition)

  • 최영진;이천
    • 전기학회논문지
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    • 제59권1호
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    • pp.113-115
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    • 2010
  • In this study, ZnO films have been grown on PES(polyethersu]fone) substrate by PLD(pulsed laser deposition) and characterized as a change of laser density and substrate temperature. Growing conditions were changed with substrate temperatures ranging from 50 to $200^{\circ}C$ and laser densities ranging from $0.2\sim0.4 J/cm^2$. Optical and structural properties were measured by XRD, SEM, AFM, PL measurement.

Structural and discharge characteristics of MgO films prepared by Arc Ion Plating (AIP) method

  • Kim, Jong-Kuk;Kim, Do-Geun;Lee, Eun-Sung;Lee, Sung-Hun;Lee, Gun-Hwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.625-627
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    • 2002
  • MgO thin films were deposited on glass and (100) Si substrates by an Arc Ion Plating (AIP) equipment using a magnesium metal target at various oxygen gas flow. In this work, we investigated the relationship between the structural properties and the discharge characteristics of MgO coating layers. X-ray diffraction and AFM have been used to study behaviors of the structure and surface morphology. The optical transmittance and the ion induced secondary electron emission coefficient of the MgO films have been also measured. The resistivity of the deposited MgO films was gradually increased from 0.17 G ohm/${\square}$ to 0.35 G ohm/${\square}$ with the oxygen gas flow. The growth rate of the MgO coating layer was decreased with increasing the oxygen gas flow, while the optical transmittance was improved.

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One-step microwave synthesis of surface functionalized carbon fiber fabric by ZnO nanostructures

  • Ravi S. Rai;Vivek Bajpai
    • Advances in nano research
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    • 제14권6호
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    • pp.557-573
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    • 2023
  • The rapid growth of zinc-oxide (ZnO) nanostructures (NSs) on woven carbon fiber (WCF) is reported in this study employing a microwave-aided chemical bath deposition process. The effects of different process parameters such as molar concentration, microwave duration and microwave power on morphologies and growth rate of the ZnO on WCF were studied. Furthermore, an attempt has been taken to study influence of different type of growth solutions on ZnO morphologies and growth rates. The surface functionalization of WCF fabrics is achieved by successful growth of crystalline ZnO on fiber surface in a very short duration through one-step microwave synthesis. The morphological, structural and compositional studies of ZnO-modified WCF are evaluated using field-emission scanning electron microscopy, X-ray diffraction and energy dispersive X-ray spectroscopy respectively. Good amount of zinc and oxygen has been seen in the surface of WCF. The presence of the wurtzite phase of ZnO having crystallite size 30-40 nm calculated using the Debye Scherrer method enhances the surface characteristics of WCF fabrics. The UV-VIS spectroscopy is used to investigate optical properties of ZnO-modified WCF samples by absorbance, transmittance and reflectance spectra. The variation of different parameters such as dielectric constants, optical conductivity, refractive index and extinction coefficient are examined that revealed the enhancement of optical characteristics of carbon fiber for wide applications in optoelectronic devices, carbon fiber composites and photonics.

Conducting Polyaniline-Titanium Dioxide Nanocomposites Prepared by Inverted Emulsion Polymerization

  • Karim, Mohammad Rezaul;Lee, Hyun-Woo;Cheong, In-Woo;Park, Sung-Min;Oh, Weon-Tae;Yeum, Jeong-Hyun
    • 한국염색가공학회:학술대회논문집
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    • 한국염색가공학회 2009년도 학술발표대회
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    • pp.158-159
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    • 2009
  • Conducting polyaniline (PAni)-titanium dioxide ($TiO_2$) nanocomposites have been synthesized by the inverted emulsion polymerization method. The resultant PAni-$TiO_2$ nanocomposites are characterized with their structural, morphological, conducting and optical properties.

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Flexible 기판을 이용한 AZO 박막제작 (Preparation of AZO thin film on the flexible substrate)

  • 조범진;금민종;김경환
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.281-282
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    • 2005
  • The AZO thin film was prepared on flexible substrate by Facing Targets Sputtering method. The substrate used the Polycarbonate(PC), thickness 200$\mu$m. In particular, the AZO thin film was prepared at room temperature because the substrate is weak in heat. The structural, electrical, optical properties of the AZO thin film were investigated and the surface was observed by microscope.

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이온 보조 증착에 의한 ZnS 광학 박막의 광학적, 구조적 특성과 환경적 안정성 개선에 관한 연구 (A study on the improvement of optical, structural properties and environmental stability of ZnS optical thin films prepared by ion-assisted deposition)

  • 김형근;반승일;김석원;한성홍
    • 한국광학회지
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    • 제8권1호
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    • pp.37-41
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    • 1997
  • Ar 이온 보조 증착(IAD)에 의해 제작된 ZnS 박막의 광학적 특성, 환경적 안정성, 결정성을 기존의 보통 박막과 비교 분석하였다. IAD 박막은 보통 박막에 비해 상대적으로 높은 굴절률과 낮은 소멸 계수를 나타내었고, 습도(85%)와 온도(150.deg. C)에 대한 안정성 테스트 결과 수분 감도와 온도 의존성이 현저히 감소되어 이들 환경에 대하여 안정성을 갖는 것으로 나타났다. 이러한 결과는 이온 충격에 의해 박막의 조밀도가 증가되어 내부 미세구조가 개선되므로 대기중의 수분 흡착 감소에 기인한 것으로 분석된다. 또한 X선 회절 실험 결과 보통 박막은 전형적인 박막의 비정질 구조를 나타낸 반면 IAD 박막은 결정질의 구조를 나타내었다.

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광섬유센서를 이용한 Beam-column 조인트의 하중에 따른 변위 계측 (Monitoring of Beam-column Joint Using Optical Fiber Sensors)

  • 김기수
    • 한국소음진동공학회논문집
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    • 제15권1호
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    • pp.3-11
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    • 2005
  • For monitoring of the civil and building structure, optical fiber sensors are very convenient. The fiber sensors are very small and do not disturb the structural properties. They also have several merits such as electro-magnetic immunity, long signal transmission, good accuracy and multiplexibility in one sensor line. Strain measurement technologies with fiber optic sensors have been investigated as a part of smart structure. In this paper, we investigated the possibilities of fiber optic sensor application to the monitoring of beam-column joints of structures. We expect that the fiber optic sensors replace electrical strain gauges. The commercial electric strain gauges show good stability and dominate the strain measurement market. However, they lack durability and long term stability for continuous monitoring of the structures. In order to apply the strain gauges, we only have to attach them to the surfaces of the structures. In this paper, we investigate the possibility of using fiber optic Bragg grating sensors to joint structure. The sensors show nice response to the structural behavior of the joint.

광섬유센서를 이용한 Beam-column 조인트의 하중에 따른 변위 계측 (Monitoring of Beam-Column Joint Using Optical Fiber Sensors)

  • 김기수
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2003년도 추계학술대회논문집
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    • pp.595-601
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    • 2003
  • For monitoring of the civil and building structure, optical fiber sensors are very convenient. The fiber sensors are very small and do not disturb the structural properties. They also have several merits such as electro-magnetic immunity, long signal transmission, good accuracy and multiplicity of one sensor line. Strain measurement technologies with fiber optic sensors have been investigated as a part of smart structure. In this paper, we investigated the possibilities of fiber optic sensor application to the monitoring of beam-column joints of structures. We expect that the fiber optic sensors replace electrical strain gauges. The commercial electric strain gauges show good stability und dominate tile strain measurement market. However, they lack durability and long term stability for continuous monitoring of the structures. In order to apply the strain gauges, we only have to attach them to the surfaces of the structures. In this paper, we investigate the possibility of using fiber optic Bragg grating sensors to joint structure. The sensors show nice response to the structural behavior of the joint.

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