• 제목/요약/키워드: Optical and structural properties

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Fabrication of CdTe thin films by sputtering and its application on CdTe/CdS solar cells (Sputtering에 의한 CdTe박막제조 및 CdTe/CdS태양전지에의 응용)

  • Jung, H.W.;Lee, C.;Kim, S.;Shin, S.H.;Park, K.J.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1645-1647
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    • 1996
  • Polycrystalline CdTe thin films -have been studied for photovoltaic application because of their high absorption coefficient and optimal band gap energy (1.54 eV) for solar energy conversion. In this study, we prepared CdTe films using RF-magnetron sputtering method and investigated structural, optical and electrical properties with spectrophotometer, XRD, EDX, and resistivity meter. CdTe films at $200\;^{\circ}C$ showed a mixture of zinc blend (Cubic) and wurtzite (hexagonal) phase. On the other hand, the films at $400\;^{\circ}C$ showed highly oriented structure having hexagonal structure. The resistivity of CdTe films deposited on $SiO_2$ substrates was about $10_7\;{\Omega}cm$. The value of resistivity decreased with the increase of the substrate temperature. CdTe were sputtered on CdS thin films prepared by chemical bath deposition for the formation of the heterojunction. I-V characteristics of these cells were measured at a light density of $100mw/cm^2$, AM. 1.0. The present thin film solar cells showed a conversion efficiency of about 5%.

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A Study on the Photo Reversible One-dimensional Photonic Crystals Composed of TeOx(x=1.42)/SiO2 (TeOx(x=1.42)/SiO2로 구성된 광가변적인 1차원 광자결정 연구)

  • Kong, Heon;Yeo, Jong-Bin;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.2
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    • pp.99-103
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    • 2015
  • One-dimensional photonic crystals (1D PCs) were fabricated by RF sputtering technique on p-Si (100), and fused quartz substrates. The 1D PCs structures consisted of $TeO_x$ (x=1.42), and $SiO_2$ with the difference refractive index. In order to estimate the effect on a defect level within 1D PCs structures, samples were prepared with both normal, and defect mode. The structural and optical properties were confirmed by Scanning electron microscope (SEM), and Ultraviolet visible near-infrared spectrophotometer (UV-VIS-NIR) respectively. In the case of a 1D PC normal mode without defect layer, it had a photonic band gap (PBG) in the near infrared (NIR) region. In the case of a 1D PC defect mode with defect layer, it had a sharp transmission band owing to a defect level, and moved towards the longer wavelength after exposing He-Cd laser with a wavelength of 325 nm.

Design studies for mandrel type fiber-hydrophones with FEM (FEM을 이용한 맨드랠(Mandrel) 형광- 음향 수중 청음기의 설계에 관한 연구)

  • Im, Jong-In;Roh, Yong-Rae
    • The Journal of the Acoustical Society of Korea
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    • v.16 no.3
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    • pp.73-80
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    • 1997
  • This paper describes structural optimization of optical fiber-wound mandrel hydrophones with Finite Element Method (FEM). The hydrophone is supposed to have operation frequency range of up to 10 kHz and show omni-directional sensitivity pattern at 5 kHz. Studied parameters are mandrel geometry, molding thickness, and material properties of constitutional parts of the hydrophone. Theoretical calculation result shows that pressure sensitivity of the hydrophone increased as either mandrel length or molding thickness gets larger. Also higher pressure sensitivity requires a mandrel or molding material with relatively low Youngs modulus or Poissons ratio. Hydrophone bandwidth increases either as the mandrel length becomes shorter or as the mandrel becomes harder. The omni-directional characteristic is improved as the mandrel length becomes shorter, at 5 kHz. With the above results, we determine the structure of an optical fiber-wound mandrel hydrophone which has the pressure sensitivity of $30 {\times} 10_{-7}$ Rad./Pa, operation frequency range of up to 10 kHz, and shows omni-directional sensitivity pattern at 5 kHz.

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Optimization of Thermo-optical Property for Electrostatic Actuating MEMS-based Variable Emissivity Radiator (정전 구동형 MEMS 기반 가변 방사율 라디에이터의 광학 물성치 최적화 설계)

  • Ha, Heon-Woo;Kang, Soo-Jin;Han, Sung-Hyeon;Kim, Tae-Gyu;Oh, Hyun-Ung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.43 no.2
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    • pp.149-155
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    • 2015
  • MEMS-based louver and shutter type conventional variable emissivity radiators change their emissivity properties in accordance with a temperature condition to achieve efficient thermal control performance. However, there are some drawbacks such as a structural safety of the mechanical moving parts under sever launch environment and constant power consumption to maintain the intended emissivity. In this study, to overcome above drawbacks, we proposed a MEMS-based variable emissivity radiator, which can change the emissivity property according to the polarity change of electrodes by using electric charge of the bead. The effectiveness of the optimized radiator design has been demonstrated through the comparison of efficiency with the fixed emissivity radiator.

Characterization of AZO thin films grown on various substrates by using facing target sputtering system

  • Lee, Chang-Hyeon;Son, Seon-Yeong;Bae, Gang;Lee, Chang-Gyu;Kim, Hwa-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.123-123
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    • 2015
  • Al doped ZnO(AZO) films as a transparent conductive oxide (TCO) electrode were deposited on glass, polyethylene naphthalate (PEN) and polyethylene terephthalate (PET) at room temperature by a conventional rf-magneton sputtering (CMS) and a facing target sputtering (FTS) using Al2O3 and ZnO targets. In order to investigation of AZO properties, the structural, surface morphology, electrical, and optical characteristics of AZO films were respectively analyzed. The resistivities of AZO films using FTS system were $6.50{\times}10-4{\Omega}{\cdot}cm$ on glass, $7.0{\times}10-4{\Omega}{\cdot}cm$ on PEN, and $7.4{\times}10-4{\Omega}{\cdot}cm$ on PET substrates, while the values of AZO films using CMS system were $7.6{\times}10-4{\Omega}{\cdot}cm$ on glass, $1.20{\times}10-3{\Omega}{\cdot}cm$ on PEN, and $1.58{\times}10-3{\Omega}{\cdot}cm$ on PET substrates. The AZO-films deposited by FTS system showed uniform surface compared to those of the films by CMS system. We thought that the films deposited by FTS system had low stress due to bombardment of high energetic particles during CMS process, resulted in enhanced electrical conductivity and crystalline quality by highly c-axis preferred orientation and closely packed nano-crystalline of AZO films using FTS system.

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Efficiency Characteristics of Cu(In,Ga)Se2 Photovoltaic Thin Films According to the Mo:Na Thickness (Mo:Na두께에 따른 Cu(In,Ga)Se2 태양전지 박막의 효율 특성)

  • Shin, Younhak;Kim, Myunghan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.9
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    • pp.701-706
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    • 2013
  • We have focused on the conversion efficiency of CIGS thin film solar cell prepared by co-evaporation method as well as the optimization of process condition. The total thickness of back electrode was fixed at 1 ${\mu}m$ and the structural, electric and optical properties of CIGS thin film were investigated by varying the thickness of Mo:Na bottom layer from 0 to 500 nm. From the experimental results, the content of Na was appeared as 0.28 atomic percent when the thickness of Mo:Na layer was 300 nm with compactly densified plate-shape surface morphology. From the XRD measurements, (112) plane was the strongest preferential orientation together with secondary (220) and (204) planes affecting to the crystallization. The lowest roughness and resistivity were 2.67 nm and 3.9 ${\Omega}{\cdot}cm$, respectively. In addition, very high carrier density and hole mobility were recorded. From the optimization of Mo:Na layer, we have achieved the conversion efficiency of 9.59 percent.

Sodium titanate as an infrared reflective material for cool roof application

  • Ullah, Mahboob;Kim, Hee Jung;Heo, Jae Gu;Roh, Dong Kyu;Kim, Dae-Sung
    • Journal of Ceramic Processing Research
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    • v.20 no.spc1
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    • pp.86-91
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    • 2019
  • A solid-state route was used to prepare sodium titanium oxide (NTO, Na2Ti3O7) as a solar heat protecting material with an impressive solar reflectance (TSR = 94.3%) using a high refractive index rutile TiO2. The solar reflectance of the synthesized NTO was measured using UV-Vis-NIR spectrophotometer. Solar reflectance property of the synthesized compound depends on the calcination temperature. The solar reflectance property of the synthesized NTO powder was compared with commercial rutile TiO2. The compound synthesized at 900 ℃ for 24 hrs had remarkable solar reflectance 94.3% than that calcined below 900 ℃. Crystalline nature, structural property, morphology and optical properties of NTO powders were characterized and analyzed using XRD, FE-SEM, EDS and UV-Vis-NIR spectrophotometer. From the results, we guessed that NTO would be a suitable "solar heat protecting candidate" for energy-saving applications in coating industries.

SPIN POLARIZED PHOTOEMISSION AND MAGNETIC CIRCULAY DICHROISM STUDY OF FeAl THIN FILMS

  • Kim, K.W.;Kudryavtsev, Y.V.;Chang, G.S.;Whang, C.N.;Lee, Y.P.
    • Journal of the Korean Vacuum Society
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    • v.6 no.S1
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    • pp.53-58
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    • 1997
  • It is well known that the equiatomic FeAl alloy crystallizes in a paramagnetic CsCl structure and is very stable in a wide temperature range owing to a significant charge transfer from Al to Fe. A presence of structural defects normally enhances the magnetic and magneto-optical properties of this alloy. In this study spin-resolved photoemission and magnetic circular dichroism (MCD) were carried out on both ordered and disordered $Fe_{0.52}Al_{0.48}$ alloy films. The disordered state in the alloy films was obtained by a vapor quenching deposition on cooled substrates. It is shown that the order-disorder transition in the Fe0.52Al0.48 alloy films leads to a significant change in the spin polarization. Form the MCD results the orbital and spin magnetic moments of the constituent atoms are obtained. According to the sum rule the spin and orbital magnetic moments of Fe in the disordered FeAl film are $\mu\frac{SR}{spin}=0.8\mu_B$ and $\mu\frac{SR}{orb}=0.14\mu_B$ respectively. The spin magnetic moment is also evaluated to be $\mu\frac{BR}{spin}=0.77\mu_B$ by the branching ration method employing a photon polarization of 90%.

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Internal structure and kinematics of the massive star forming region W4

  • Lim, Beomdu;Yun, Hyeong-Sik;Rauw, Gregor;Naze, Yael;Kim, Jinyoung S.;Lee, Jeong-Eun;Hwang, Narae;Park, Byeong-Gon;Park, Sunkyung;Sung, Hwankyung;Kim, Seulgi
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.72.3-72.3
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    • 2019
  • OB associations are young stellar systems on a few tens to a hundred parsec scale, and many of them are composed of multiple substructures. It is suggested that some hints about their formation process are probably imprinted on structural features and internal kinematics. In this context, we study the massive star forming region W4 in the Cassiopeia OB6 association using the Gaia proper motion data and high-resolution optical spectra taken from Hectochelle on MMT. We probe the structure and internal kinematics of W4 to trance its formation process. Several nonmembers with different kinematic properties are excluded in our sample. Some of them may be young stellar population spread over a large area of the Perseus spiral arm given their wide spatial distribution over 50 parsecs. W4 is composed of an central open cluster (IC 1805) and an extended stellar component. Their global expansion patterns are detected in stellar proper motion. In this presentation, we will further discuss the formation process of W4, based on the velocity dispersions of stars comprising these substructure.

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Structural Evolution of ZnO:Ga Thin Film on Profiled Substrate Grown by Radio Frequency Sputtering

  • Sun, J.H.;Kim, J.H.;Ahn, B.G.;Park, S.Y.;Jung, E.J.;Lee, J.H.;Kang, H.C.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.72-72
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    • 2011
  • Recently, Zinc oxide (ZnO) nano-structures have been received attractive attention because of their outstanding optical and electrical properties. It might be a promising material considered for applications to photonic and electronic devices such as ultraviolet light emitting diode, thin film transistor, and gas sensors. ZnO nano-structures can be typically synthesized by the VLS growth mode and self-assembly. In the VLS growth mode using various growth techniques, the noble metal catalysts such as Au and Sn were used. However, the growth of ZnO nano-structures on nano-crystalline Au seeds using radio frequency (RF) magnetron sputtering might be explained by the profile coating, i.e. the ZnO nano-structures were a morphological replica of Au seeds. Ga doped ZnO (ZnO:Ga) nano-structures using this concept were synthesized and characterized by XRD, AFM, SEM, and TEM. We found that surface morphology is drastically changed from initial islands to later sun-flower typed nano-structures. We will present the structural evolution of ZnO:Ga nano-structures with increasing the film thickness.

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