• Title/Summary/Keyword: Optical and structural properties

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Structural and Optical Properties of ZnS Thin Films Fabricated by Using RF Sputtering and Rapid Thermal Annealing Process for Buffer Layer in Thin Film Solar Cells (박막태양전지 버퍼층 적용을 위해 RF 스퍼터링 및 급속열처리 공정으로 제작한 황화아연 박막의 구조적 광학적 특성)

  • Park, Chan-Il;Jun, Young-Kil
    • The Journal of the Korea institute of electronic communication sciences
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    • v.15 no.4
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    • pp.665-670
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    • 2020
  • Buffer layer in CIGS thin-film solar cells improves energy conversion efficiency through band alignment between the absorption layer and the window layer. ZnS is a non-toxic II-VI compound semiconductor with direct-transition band gaps and n-conductivity as well as with excellent lattice matching for CIGS absorbent layers. In this study, the structural and optical properties of ZnS thin films, deposited by RF magnetron sputtering method and subsequently performed by the rapid thermal annealing treatment, were investigated for the buffer layer. The zincblende cubic structures along (111), (220), and (311) were shown in all specimens. The rapid thermal annealed specimens at the relatively low temperatures were polycrystalline structure with the wurtzite hexagonal structures along (002). Rapid thermal annealing at high temperatures changed the polycrystalline structure to the single crystal of the zincblende cubic structures. Through the chemical analysis, the zincblende cubic structure was obtained in the specimen with the ratio of Zn/S near stoichiometry. ZnS thin film showed the shifted absorption edge towards the lower wavelength as annealing temperature increased, and the mean optical transmittance in the visible light range increased to 80.40% under 500℃ conditions.

The characteristics of ZnO Thin film on PES substrate by pulsed laser deposition (펄스레이저 증착법에 의한 polyethersulfone 기판상의 ZnO박막의 특성)

  • Choi, Young-Jin;Lee, Cheon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.1
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    • pp.113-115
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    • 2010
  • In this study, ZnO films have been grown on PES(polyethersu]fone) substrate by PLD(pulsed laser deposition) and characterized as a change of laser density and substrate temperature. Growing conditions were changed with substrate temperatures ranging from 50 to $200^{\circ}C$ and laser densities ranging from $0.2\sim0.4 J/cm^2$. Optical and structural properties were measured by XRD, SEM, AFM, PL measurement.

Structural and discharge characteristics of MgO films prepared by Arc Ion Plating (AIP) method

  • Kim, Jong-Kuk;Kim, Do-Geun;Lee, Eun-Sung;Lee, Sung-Hun;Lee, Gun-Hwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.625-627
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    • 2002
  • MgO thin films were deposited on glass and (100) Si substrates by an Arc Ion Plating (AIP) equipment using a magnesium metal target at various oxygen gas flow. In this work, we investigated the relationship between the structural properties and the discharge characteristics of MgO coating layers. X-ray diffraction and AFM have been used to study behaviors of the structure and surface morphology. The optical transmittance and the ion induced secondary electron emission coefficient of the MgO films have been also measured. The resistivity of the deposited MgO films was gradually increased from 0.17 G ohm/${\square}$ to 0.35 G ohm/${\square}$ with the oxygen gas flow. The growth rate of the MgO coating layer was decreased with increasing the oxygen gas flow, while the optical transmittance was improved.

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One-step microwave synthesis of surface functionalized carbon fiber fabric by ZnO nanostructures

  • Ravi S. Rai;Vivek Bajpai
    • Advances in nano research
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    • v.14 no.6
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    • pp.557-573
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    • 2023
  • The rapid growth of zinc-oxide (ZnO) nanostructures (NSs) on woven carbon fiber (WCF) is reported in this study employing a microwave-aided chemical bath deposition process. The effects of different process parameters such as molar concentration, microwave duration and microwave power on morphologies and growth rate of the ZnO on WCF were studied. Furthermore, an attempt has been taken to study influence of different type of growth solutions on ZnO morphologies and growth rates. The surface functionalization of WCF fabrics is achieved by successful growth of crystalline ZnO on fiber surface in a very short duration through one-step microwave synthesis. The morphological, structural and compositional studies of ZnO-modified WCF are evaluated using field-emission scanning electron microscopy, X-ray diffraction and energy dispersive X-ray spectroscopy respectively. Good amount of zinc and oxygen has been seen in the surface of WCF. The presence of the wurtzite phase of ZnO having crystallite size 30-40 nm calculated using the Debye Scherrer method enhances the surface characteristics of WCF fabrics. The UV-VIS spectroscopy is used to investigate optical properties of ZnO-modified WCF samples by absorbance, transmittance and reflectance spectra. The variation of different parameters such as dielectric constants, optical conductivity, refractive index and extinction coefficient are examined that revealed the enhancement of optical characteristics of carbon fiber for wide applications in optoelectronic devices, carbon fiber composites and photonics.

Conducting Polyaniline-Titanium Dioxide Nanocomposites Prepared by Inverted Emulsion Polymerization

  • Karim, Mohammad Rezaul;Lee, Hyun-Woo;Cheong, In-Woo;Park, Sung-Min;Oh, Weon-Tae;Yeum, Jeong-Hyun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2009.03a
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    • pp.158-159
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    • 2009
  • Conducting polyaniline (PAni)-titanium dioxide ($TiO_2$) nanocomposites have been synthesized by the inverted emulsion polymerization method. The resultant PAni-$TiO_2$ nanocomposites are characterized with their structural, morphological, conducting and optical properties.

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Preparation of AZO thin film on the flexible substrate (Flexible 기판을 이용한 AZO 박막제작)

  • Cho, Bum-Jin;Keum, Min-Jong;Kim, Kyung-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.281-282
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    • 2005
  • The AZO thin film was prepared on flexible substrate by Facing Targets Sputtering method. The substrate used the Polycarbonate(PC), thickness 200$\mu$m. In particular, the AZO thin film was prepared at room temperature because the substrate is weak in heat. The structural, electrical, optical properties of the AZO thin film were investigated and the surface was observed by microscope.

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A study on the improvement of optical, structural properties and environmental stability of ZnS optical thin films prepared by ion-assisted deposition (이온 보조 증착에 의한 ZnS 광학 박막의 광학적, 구조적 특성과 환경적 안정성 개선에 관한 연구)

  • 김형근;반승일;김석원;한성홍
    • Korean Journal of Optics and Photonics
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    • v.8 no.1
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    • pp.37-41
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    • 1997
  • The optical property, the environmental stability and the crystallization of ZnS thin films prepared by ion-assisted deposition (IAD) were investigated and compared with those of conventional electron-beam deposited thin films. The humidity(R.H. 85%) test and the thermal(15$0^{\circ}C$) show that the IAD films have relatively higher refractive index, smaller extinction coefficient and environmentally more stable than the conventional films. It is believed to originate from the reduced adsorption of moisture which reflect the increased packing density and the improved microstructure by ion bombardment. XRD experiments also confirm that conventionally grown films have an amorphous in comparison with the crystalline structured IAD films.

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Monitoring of Beam-column Joint Using Optical Fiber Sensors (광섬유센서를 이용한 Beam-column 조인트의 하중에 따른 변위 계측)

  • Kim, Ki-Soo
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.15 no.1 s.94
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    • pp.3-11
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    • 2005
  • For monitoring of the civil and building structure, optical fiber sensors are very convenient. The fiber sensors are very small and do not disturb the structural properties. They also have several merits such as electro-magnetic immunity, long signal transmission, good accuracy and multiplexibility in one sensor line. Strain measurement technologies with fiber optic sensors have been investigated as a part of smart structure. In this paper, we investigated the possibilities of fiber optic sensor application to the monitoring of beam-column joints of structures. We expect that the fiber optic sensors replace electrical strain gauges. The commercial electric strain gauges show good stability and dominate the strain measurement market. However, they lack durability and long term stability for continuous monitoring of the structures. In order to apply the strain gauges, we only have to attach them to the surfaces of the structures. In this paper, we investigate the possibility of using fiber optic Bragg grating sensors to joint structure. The sensors show nice response to the structural behavior of the joint.

Monitoring of Beam-Column Joint Using Optical Fiber Sensors (광섬유센서를 이용한 Beam-column 조인트의 하중에 따른 변위 계측)

  • 김기수
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.11a
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    • pp.595-601
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    • 2003
  • For monitoring of the civil and building structure, optical fiber sensors are very convenient. The fiber sensors are very small and do not disturb the structural properties. They also have several merits such as electro-magnetic immunity, long signal transmission, good accuracy and multiplicity of one sensor line. Strain measurement technologies with fiber optic sensors have been investigated as a part of smart structure. In this paper, we investigated the possibilities of fiber optic sensor application to the monitoring of beam-column joints of structures. We expect that the fiber optic sensors replace electrical strain gauges. The commercial electric strain gauges show good stability und dominate tile strain measurement market. However, they lack durability and long term stability for continuous monitoring of the structures. In order to apply the strain gauges, we only have to attach them to the surfaces of the structures. In this paper, we investigate the possibility of using fiber optic Bragg grating sensors to joint structure. The sensors show nice response to the structural behavior of the joint.

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