• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2442-2444
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• 2007

CO adsorbates on the surface of Pt supported on carbon catalysts (Pt/C) were investigated by CO stripping voltammetry. Three types of CO adsorbed samples were prepared: by methanol dehydrogenation only (COm), by CO gas bubbling only (COg), and by methanol dehydrogenation followed by CO gas bubbling (COm+g). Our coverage data show that CO gas can be adsorbed on Pt/C catalyst already saturated with CO adsorbates by methanol dehydrogenation. The COm+g sample showed the properties of both COm as well as COg samples in terms of the potential although the CO adsorbed by dehydrogenation was completely exchanged with CO in the electrolyte solution. Therefore, the oxidation pathways of CO on Pt/C were observed to depend on the initial adsorption conditions of CO more strongly than on the CO coverage. Our results imply that an initial CO poisoning condition in fuel cell operation is an important factor to determine the difficulty in removing the adsorbed CO and confirm that the properties of the adsorbed CO do not change even with chemical replacement with CO in different conditions. In addition, our results indicate a low CO surface mobility on the Pt in an electrolyte solution.

• Composites Research
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• 제30권1호
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• pp.7-14
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• 2017

In this paper, the inter-lamina shear strength (ILSS) of multi-wall carbon nanotube (MWNT) reinforced carbon fiber reinforced plastics (CFRP) and thin-ply composites were verified under low earth orbit (LEO) space environment. CFRP, MWNT reinforced CFRP, thin-ply CFRP and MWNT reinforced thin-ply CFRP were tested after aging by using accelerated ground simulation equipment. The used ground simulation equipment can simulate high vacuum ($2.5{\times}10^{-6}torr$), atomic oxygen (AO, $9.15{\times}10^{14}atoms/cm^2{\cdot}s$), ultraviolet light (UV, 200 nm wave length) and thermal cycling ($-70{\sim}100^{\circ}C$) simultaneously. The duration of aging experiment was twenty hours, which is an equivalent duration to that of STS-4 space shuttle condition. After the aging experiment, ILSS were measured at room temperature ($27^{\circ}C$), high temperature ($100^{\circ}C$) and low temperature ($-100^{\circ}C$) to verify the effect of operation temperature. The MWNT and thin-ply shows good improvement of ILSS at ground condition especially with the thin-ply. And after LEO exposure large degradation of ILSS was observed at MWNT added composite due to the thermal cycle. And the degradation rate was much higher under the high temperature condition. But, at the low temperature condition, the ILSS was largely recovered due to the matrix toughening effect.

• 한국기계가공학회지
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• 제19권1호
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• pp.43-48
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• 2020

At present, 24 nuclear power plants are in operation nationwide as the main power source responsible for about 27% of Korea's electricity, and five nuclear power plants are currently under construction. Issues of nuclear safety and reliability have always existed, but after the Fukushima accident, ensuring reliability has become an even more important issue for safety. Compared to other kinds of accidents, the initial response after a nuclear accident is more important than any other accident. Prior to accidents, it is important to be able to predict and judge the accident in advance for the sake of prevention. In this research, non-destructive inspection methods for existing pipe welds include radiographic, ultrasonic, magnetic particle practice, and liquid penetration testing. For this experiment, carbon steel pipes like that of the material used in nuclear pipes were adopted, and specimen welded to the flange (Flange) were manufactured. After testing, the weld specimen were not damaged through the infrared thermography (IRT) experiment. This study attempted to improve the safety of carbon steel pipes through a comparative analysis of finite element analysis.

• Korean Chemical Engineering Research
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• 제47권3호
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• pp.368-372
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• 2009

흡착제의 흡착특성인 흡착표면적과 세공크기를 수정진동자를 이용하여 측정하는 방법을 제안하고 그 성능을 조사하였다. 액체질소를 활용하는 기존의 방법에 비해 상온에서 이산화탄소를 이용하기 때문에 장치가 소형이고, 조작이 간편하며 짧은 흡착시간 내 측정이 가능한 이점을 가지고 있다. 마이크로 입자의 카본 크라오젤과 대나무 활성탄에 대해 흡착특성을 측정한 측정치를 흡착능 측정기로 측정한 측정치와 비교한 결과 메조세공의 흡착제에 대해서는 유효한 측정치가 얻어진 반면 마이크로 세공의 입자에서는 다소 큰 오차를 나타내었다.

• 수산해양기술연구
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• 제46권4호
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• pp.313-323
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• 2010

Fuel consumption in fisheries is a primary concern due to environmental effects and costs to fishermen. Much research has been carried out to reduce the fuel consumption related to fishing operations. The fuel consumption of fishing gear during fishing operation is generally related to hydrodynamic resistance on the gear. This research demonstrates a new approach using numerical methods to reduce fuel consumption. By designing the fishing gear using drawing software, the whole and partial resistance force on the gear can be calculated as a result of simulations. The simulation results will suggest suitable materials or gear structure for reducing the hydrodynamic forces on the gear while maintaining the performance of the gear. This research will helpful to reduce the $CO_2$ emissions from fishing operations and lead to reduce fishing costs due to fuel savings.

• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2006년도 춘계학술발표논문집
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• pp.223-226
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• 2006

The micro-gas sensor based on carbon nanotubes (CNTs) was fabricated and its gas sensing characteristics on nitrogen dioxide ($NO_2$) have been investigated. The sensor consists of a heater, an insulating layer, a pair of contact electrodes, and CNT-sensing film on a micromachined diaphragm. The heater plays a role in the temperature change to modify sensor operation. Gas sensor responses of CNT-film to $NO_2$ at room temperature are reported. The sensor exhibits a reversible response with a time constant of a few minutes at thermal treatment temperature of $130^{\circ}C$.

• Nuclear Engineering and Technology
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• 제49권1호
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• pp.103-112
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• 2017

Application of the supercritical condition in reactor core cooling needs to be properly justified based on the extreme level of parameters involved. Therefore, a numerical study is presented to compare the thermalhydraulic performance of supercritical and single-phase natural circulation loops under low-to-intermediate power levels. Carbon dioxide and water are selected as respective working fluids, operating under an identical set of conditions. Accordingly, a three-dimensional computational model was developed, and solved with an appropriate turbulence model and equations of state. Large asymmetry in velocity and temperature profiles was observed in a single cross section due to local buoyancy effect, which is more prominent for supercritical fluids. Mass flow rate in a supercritical loop increases with power until a maximum is reached, which subsequently corresponds to a rapid deterioration in heat transfer coefficient. That can be identified as the limit of operation for such loops to avoid a high temperature, and therefore, the use of a supercritical loop is suggested only until the appearance of such maxima. Flow-induced heat transfer deterioration can be delayed by increasing system pressure or lowering sink temperature. Bulk temperature level throughout the loop with water as working fluid is higher than supercritical carbon dioxide. This is until the heat transfer deterioration, and hence the use of a single-phase loop is prescribed beyond that limit.

• International Journal of Automotive Technology
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• 제7권1호
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• pp.9-15
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• 2006

Prediction of the performance of a carbon canister in vehicle evaporative emission control system has become an important aspect of overall fuel system development and design. A vehicle's evaporative emission control system is continuously working, even when the vehicle is not running, due to generation of vapors from the fuel tank during ambient temperature variations. Evaporative emissions from gasoline powered vehicles continue to be a major concern. The objective of this paper is to clarity the flow characteristics and other such fundamental data for the canister during loading and purging are needed, and this data will prove valuable in the development of the canister. This paper is to evaluate the relationship between carbon canister condition and engine performance during engine operation, and the effects of evaporative emissions on the engine performance were investigated.

• 한국해양공학회지
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• 제27권6호
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• pp.65-72
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• 2013

This paper describes a finite element analysis (FEA) of the body frame of a subsea robot, Crabster200 (CR200). CR200 has six legs for mobility instead of screw type propellers, which distinguishes it from previous underwater robots such as remotely operated vehicles (ROVs) and autonomous underwater vehicles (AUVs). Another distinguishing characteristic is the body frame, which is made of carbon fiber reinforced plastic (CFRP). This body frame is designed as a rib cage structure in order to disperse the applied external loads and reduce the weight. The frame should be strong enough to support many devices for exploration and operation underwater. For a reasonable FEA, we carried out specimen tests. Using the obtained material properties, we performed a modal analysis and FEA for CR200 with a ready posture. Finally, this paper presents the FEA results for the CFRP body frame and the compares the characteristics of CFRP with conventional material, aluminum.

• Elastomers and Composites
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• 제30권3호
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• pp.185-194
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• 1995

Membrane process has been employed to separate a specific substance from gas or liquid mixture, and treat wastewater. This is due to the fact that the substance of mixture can be permeated and separated selectively by membrane. Since Initial equipment and operation costs are not expensive, membrane process has been adopted in various fields such as petroleum Industry, chemistry, polymer, electronics, foods, biochemical industry and wastewater treatment. In this study, $CaCO_3$ particles impregnated in silicone rubber network were extracted by using supercritical carbon dioxide and pore distribution of silicone $rubber-CaCO_3$ was investigated with varying amount of extract. Silicone rubber has excellent mechanical properties such as heat-resistance, cold-resistance etc. and $CaCO_3$ has microporous structure. It is possible to make silicone $rubber-CaCO_3$ composite sheets via work-intensive kneading processes. In so doing $CaCO_3$ particles become distributed and impregnated in silicone rubber network. Supercritical carbon dioxide diffuse through composite sample, then sample is swollen. $CaCO_3$ in silicone rubber network Is dissolved in supercritical carbon dioxide, and its sites become pores. Pore distribution, pore shape and surface area are observed by SEM(scanning electron microscope) micrograph and BET surface area analyzer examination respectively. Pore characteristics of membrane suggest the possibilities that the membrane can be used for process of mixture separation and wastewater treatment.