• Journal of the Institute of Electronics Engineers of Korea SC
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• v.39 no.6
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• pp.34-42
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• 2002

In this paper, we propose a temperature independent the detective voltage source in voltage detector. The value of a detective voltage source is designed to become m times of silicon bandgap voltage at zero absolute temperature. By properly choosing the temperature coefficient of diode, the temperature coefficient of a concave voltage nonlinearities generated by the ${\Delta}V_{BE}$ section of diode between base and emitter of transistors with a different area can be summed with convex nonlinearities the $V_{BE}$ voltage to achieve the near zero temperature coefficient of the detective voltage source. We designed that the value of a detective voltage can be varied by ${\Delta}V_{BE}$, the $V_{BE}$multiplier circuit and resistor. In order to verify the performance of a proposed detective voltage source, we manufactured the voltage detector IC for 1.9V which is fabricated in $6{\mu}m$ Bipolar technology and measured the operating characteristics, the temperature coefficient of a detective voltage. To reduce the deviation of a detective voltage in the IC process step, we introduced a trimming technology, ion implantation and an isotropic etching. In manufactured IC, the detective voltage source could achieve the stable temperature coefficient of 29ppm/$^{\circ}C$ over the temperature range of -30$^{\circ}C$ to 70$^{\circ}C$. The current consumption of a voltage detector constituted by the proposed detective voltage source is $10{\mu}A$ from 1.9V-supply voltage at room temperature.

• Journal of Institute of Control, Robotics and Systems
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• v.20 no.5
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• pp.543-550
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• 2014

In many industrial processes and operations, such as power plants, petrochemical industries and ships, shell and tube heat exchangers are widely used and probably applicable for a wide range of operating temperatures. The main purpose of a heat exchanger is to transfer heat between two or more medium with temperature differences. Heat exchangers are highly nonlinear, time-varying and show time lag behavior during operation. The temperature control of such processes has been challenging for control engineers and a variety of forms of PID controllers have been proposed to guarantee better performance. In this paper, a scheme to control the outlet temperature of a shell and tube heat exchanger system that combines the PID controller with feedforward control and anti-windup techniques is presented. A genetic algorithm is used to tune the parameters of the PID controller with anti-windup and the feedforward controller by minimizing the IAE (Integral of Absolute Error). Simulation works are performed to study the performance of the proposed method when applied to the process.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.29 no.11
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• pp.570-579
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• 2017

In this study, we examined the multi-stage piston-type air compressors typically used in a railroad vehicle, and the heat transfer efficiency was analyzed according to the design conditions of the heat exchanger (a compressor component module for cooling the compressed high temperature air). For the fin-tube heat exchanger used in the most air compressors, numerical analysis was performed to analyze heat transfer by defining the various rectangle tube sizes and the number of fin-per-unit area as design variables under the same flow rate of compressed air. Also, this analysis compared the temperature of the compressed air. Regarding environmental conditions for analysis, the flow rate of the external cooling air was measured and the mean value of the values was applied. And a "turbulence model" was considered in both the external flow of the cooling air and the internal flow inside the tube. From the results of analysis, it was found that the change of the aspect ratio value of the tube greatly influences the heat transfer efficiency of the compressed air, and influences if the fin density is relatively small. As a result, the optimum design specifications of the heat exchanger for air compressors were confirmed based on the analysis of the heat transfer efficiency, according to the design conditions of fin and tube by the operating temperature range of the compressed air.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.451-454
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• 2009

Production and application of biodiesel are expected to grow steadily in the coming years and thus output of its by-product, crude glycerin, will accordingly increase as well. In the present study, gasification of biodiesel by-product as a renewable energy was performed in an entrained flow gasifier to investigate the gasification performance with the operating conditions. Crude glycerin shows a high heating value of 6,000 kcal/kg and low ash and sulphur content. Gasification was conducted in a temperature range of $950\;{\sim}\;1500\;^{\circ}C$. The variation of syngas composition with excess air ratio of 0.17 ~ 0.7 for air or oxygen as a gasification agent was investigated. From the results, syngas heating value, carbon conversion and cold gas efficiency of more than $2500\;kcal/Nm^3$, 95% and 65% were achieved, respectively. The temperature dependency of syngas composition, carbon conversion, and cold gas efficiency shows a similar tendency to excess air ratio at the temperature corresponding to the excess air ratio. The $H_2/CO$ ratio of the product gas was varied from 1.25 to 0.7 with the excess air ratio and this gas composition was favorable for DME synthesis. The optimum excess air ratio for gasification of biodiesel by-product was evaluated to be an approximately 0.35 to 0.4. The present results indicate that crude glycerin can be utilized as a feedstock for gasification to make syngas.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.6
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• pp.64-71
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• 2013

In this study we designed a lean $NO_x$ trap (LNT) model with $GT-POWER^{TM}$ program and then the LNT model was compared to the bench flow reactor test results. This model consists of 9 kinetic reactions to represent the main steps of NO oxidation, $NO_x$ adsorption, $NO_x$ release and then its reduction. The comparison was performed on the operating conditions at the space velocity of 50,000 1/hr and 80,000 1/hr with the temperature range of $200^{\circ}C{\sim}500^{\circ}C$ with the even spaced temperature step of $50^{\circ}C$. The experimental results show that the $NO_x$ conversion efficiency was enhanced by the temperature up to $350^{\circ}C$ and then decayed at higher temperatures. The LNT model predicts the similar trend of the $NO_x$ conversion efficiency to the experimental results below $350^{\circ}C$, but overestimates above $350^{\circ}C$. This overestimation comes from the higher reduction efficiency which was obtained by the different reduction gas composition such as $C_3H_6$ in the model to replace $CH_4$, $C_2H_4$ in the bench test.

• Journal of the Korean Institute of Gas
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• v.2 no.1
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• pp.1-6
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• 1998

A low power (below than 300 mW) catalytic bead combusible gas sensor is developed and utilized with a computer controlled sampling system for measuring heat content of natural gas. The heat content of gas is proportional to the change in the energy required to exposure to the sample of combustible gas. The heat content of natural gas samples ranging 36.30 - 39.88 $MJ/m^3$ is measured in the range of approximately $1\%$ error, which is comparable to its nominal heat content. Each gas represents a slightly different curve of sensitivity to sensor temperature. Thus all of the sensitivities are not equal to every temperature. In calibration process the choice of a optimum operating temperature is an important factor that influences the overall performance of the measurement system.

• Journal of the Korean Electrochemical Society
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• v.15 no.1
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• pp.35-40
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• 2012

The composite membranes using Nafion as matrix and 1-ethyl-3-methylimidazolium tetracyanoborate (EMITCB) as ion-conducting medium in replacement of water were prepared and characterized. The amount of EMITCB in Nafion varied from 30 to 50wt%. The composite membranes are characterized by ion conductivity, thermogravitational analyses (TGA) and small-angle X-ray scattering (SAXS). The composite membranes containing EMITCB of 40wt% showed the maximum ionic conductivity which was ~0.0146 S $cm^{-1}$ at 423.15 K. It is inferred that the decrease in ionic conductivity of all the composite membranes might be due to the decomposition of a tetracyanoboric acid formed in the composite membranes. The results of SAXS indicated that the ionic clusters to conduct proton in the composite membranes were successfully formed. In accordance with the results of ionic conductivity as a function of a reciprocal temperature, SAXS showed a proportional decrease in scattering maximum $q_{max}$ as the amount of EMITCB increases in the composite membranes, which results in the increase in ionomer cluster size. The TGA showed no significant decomposition of the ionic liquid as well as the composite membranes in the range of operating temperature ($120-150^{\circ}C$) of high temperature proton exchange membrane fuel cells (HTPEMFC). As a result, EMITCB is able to play an important role in transferring proton in the composite membranes at elevated temperatures with no external humidification for proton exchange membrane fuel cells.

• Journal of the Korean Electrochemical Society
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• v.3 no.4
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• pp.191-195
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• 2000

Electrochemical properties of the oxygen electrode in phosphoric acid fuel cell have been studied using AC impedance method as a function of applied potential, operating temperature and teflon content in the electrode. The oxygen electrode reaction in the $105wt.\%$ phosphoric acid is characterized by a parallel resistive component, $R_p$ and a capacitive component, $C_p$ with serial electrolyte resistance, $R_s$. The conductivity of the phosphoric acid is found to be 0.31-0.47 S/cm in the range of $130\;to\;190^{\circ}C$ from the measured impedance. The increase of applied potential and temperature produced the decreased RP and the increased $C_p$, which means the increase of the oxygen electrode reaction rate. The single cells with the cathode of various teflon contents were tested, and the cathode with $40wt.\%$ teflon showed good performance, which is considered to be related to an optimized impedance behavior.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.4
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• pp.346-352
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• 2012

The properties of methane oxidation were studied in this research over transition metal containing $CeO_2$ (TM/$CeO_2$, TM=Ni, Co, Cu, Fe) with TM content of 5 wt. % at atmospheric pressure. The characteristics of catalysts were investigated by various characterization techniques, including XRD, GC, SEM and EPMA analyses. The catalytic tests were carried out in a fixed Rmix ratio of 1.5 ($CH_4/O_2$) in a fixed-bed reactor operating isothermally at atmospheric pressure. Only the Ni/$CeO_2$ catalysts showed syngas production above $400^{\circ}C$ via typical partial oxidation reaction whereas other catalysts induced complete oxidation resulting in the production of $CO_2$ and $H_2O$ in whole reaction temperature range. From the quantitative analysis on carbon deposition after catalytic tests, Cu/$CeO_2$ was found to show the highest resistance on carbon deposition. Therefore Cu can be proposed as an efficient catalyst element which can be combined with a conventional Ni-based SOFC anode to enhance the carbon tolerance.

• Bulletin of the Korean Chemical Society
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• v.19 no.6
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• pp.661-666
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• 1998

Active reaction sites and electrochemical O2 reduction kinetics on La_{1-x}Sr_xMnO_{3+{\delta}} (x=0.1-0.4)/YSZ (yttria-stabilized zirconia) electrodes are investigated in the temperature range of 700-900 ℃ at $Po_2=10^{-3}$-0.21 atm. Results of the steady-state polarization measurements, which are formulated into the Butler-Volmer formalism to extract transfer coefficient values, lead us to conclude that the two-electron charge transfer step to atomically adsorbed oxygen is rate-limiting. The same conclusion is drawn from the $Po_2$-dependent ac impedance measurements, where the exponent m in the relationship of $I_o$ (exchange current density) ∝ $P_{o_{2}}^m$ is analyzed. Chemical analysis is performed on the quenched Mn perovskites to estimate their oxygen stoichiometry factors (δ) at the operating temperature (700-900 ℃). Here, the observed δ turns out to become smaller as both the Sr-doping contents (x) and the measured temperature increase. A comparison between the 8 values and cathodic activity of Mn perovskites reveals that the cathodic transfer coefficients $({\alpha}_c)$ for oxygen reduction reaction are inversely proportional to δ whereas the anodic ones $({\alpha}_a)$ show the opposite trend, reflecting that the surface oxygen vacancies on Mn perovskites actively participate in the $O_2$ reduction reaction. Among the samples of x= 0.1-0.4, the manganite with x=0.4 exhibits the smallest 8 value (even negative), and consistently this electrode shows the highest ${\alpha}_c$ and the best cathodic activity for the oxygen reduction reaction.