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Improvement of Thermal Efficiency using Atkinson Cycle in a High-Compression Ratio, Spark-Ignition, Natural Gas Engine for Power Generation (고압축비 전기점화 천연가스 발전용 엔진에서 앳킨슨 사이클 적용을 통한 열효율 향상)

  • Junsun Lee;Hyunwook Park;Seungmook Oh;Changup Kim;Yonggyu Lee;Kernyong Kang
    • Journal of ILASS-Korea
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    • v.28 no.2
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    • pp.55-61
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    • 2023
  • Natural gas is a high-octane fuel that is effective in controlling knocking combustion. In addition, as a low-carbon fuel with a high hydrogen-carbon ratio, it emits less carbon dioxide and almost no particulate matter compared to conventional fossil fuels. Stoichiometric combustion engines equipped with a three-way catalyst are useful in various fields such as transportation and power generation because of their excellent exhaust emission reduction performance. However, stoichiometric combustion engines have a disadvantage of lower thermal efficiency compared to lean combustion engines. In this study, a combination of high compression ratio and Atkinson cycle was implemented in a 11 liter, 6-cylinder, spark-ignition engine to improve the thermal efficiency of the stoichiometric engine. As a result, pumping and friction losses were reduced and the operating range was extended with optimized Atkinson camshaft. Based on the exhaust gas limit temperature of 730℃, the maximum load and thermal efficiency were improved to BMEP 0.66 MPa and BTE 35.7% respectively.

Development of Portable Boiler Tube Health Evaluation System (휴대용 보일러튜브 건전성 평가시스템 개발)

  • Chang Min Lee;Han Sang Lee;Bum Shin Kim
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.46 no.3
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    • pp.101-108
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    • 2023
  • Although the proportion of coal-fired power generation is decreasing, efficient operating technology is needed to continuously invest in facilities and reduce maintenance costs until it is abolished. Boilers, one of the main facilities of power plants, operate for a long time in harsh environments of high temperature and high pressure. In addition, damage due to deterioration is likely to occur depending on the fuel and tube material used. It is very important to judge soundness because damage caused by deterioration adversely affects facility operation. Previously, replication method was used to analyze the progress of deterioration. In the replication method, pre-treatment such as chemical treatment is performed on the boiler tube in the field, the area is reproduced by attaching a film, and the replicated film is determined by an expert in the laboratory with an expensive microscope. However, this method involves substantial costs and time requirements, as well as the possibility of human errors. To address these issues, we developed a mobile health assessment system in this research. Since it is detachable and takes images in real time, this system enables swift evaluations across a broad range and facilitates the assessment of preprocessing quality. In addition, it was intended to reduce existing human mistakes by developing a degradation classification algorithm using the merger cluster method.

Effect of Cross-Linking Characteristic on the Physical Properties and Storage Stability of Acrylic Rubber

  • Seong-Guk Bae;Min-Jun Gim;Woong Kim;Min-Keun Oh;Ju-Ho Yun;Jung-Soo Kim
    • Elastomers and Composites
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    • v.58 no.3
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    • pp.136-141
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    • 2023
  • Polyacrylic rubber (ACM) is well known for its excellent heat resistance and chemical stability. Additionally, its performance can be readily manipulated by modifying its functional groups, rendering it highly attractive to various industries. However, extreme climate changes have necessitated an expansion of the operating temperature range and lifespan of ACM products. This requires the optimization of both the compounding process and functional-group design. Hence, we investigated the relationship between the cross-linking system and mechanical properties of an ACM with a carboxylic cure site. The crosslink density is determined by chemical kinetics according to the structure of additives, such as diamine crosslinkers and guanidine accelerators. This interaction enables the manipulation of the scotch time and mechanical properties of the compound. This fundamental study on the correlation analysis between cross-linking systems, physical properties, and storage stability can provide a foundation for material research aimed at satisfying the increasingly demanding service conditions of rubber products.

Growth of SiC Oxidation Protective Coating Layers on graphite substrates Using Single Source Precursors

  • Kim, Myung-Chan;Heo, Cheol-Ho;Park, Jin-Hyo;Park, Seung-Jun;Han, Jeon-Geon
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.122-122
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    • 1999
  • Graphite with its advantages of high thermal conductivity, low thermal expansion coefficient, and low elasticity, has been widely used as a structural material for high temperature. However, graphite can easily react with oxygen at even low temperature as 40$0^{\circ}C$, resulting in CO2 formation. In order to apply the graphite to high temperature structural material, therefore, it is necessary to improve its oxidation resistive property. Silicon Carbide (SiC) is a semiconductor material for high-temperature, radiation-resistant, and high power/high frequency electronic devices due to its excellent properties. Conventional chemical vapor deposited SiC films has also been widely used as a coating materials for structural applications because of its outstanding properties such as high thermal conductivity, high microhardness, good chemical resistant for oxidation. Therefore, SiC with similar thermal expansion coefficient as graphite is recently considered to be a g행 candidate material for protective coating operating at high temperature, corrosive, and high-wear environments. Due to large lattice mismatch (~50%), however, it was very difficult to grow thick SiC layer on graphite surface. In theis study, we have deposited thick SiC thin films on graphite substrates at temperature range of 700-85$0^{\circ}C$ using single molecular precursors by both thermal MOCVD and PEMOCVD methods for oxidation protection wear and tribological coating . Two organosilicon compounds such as diethylmethylsilane (EDMS), (Et)2SiH(CH3), and hexamethyldisilane (HMDS),(CH3)Si-Si(CH3)3, were utilized as single source precursors, and hydrogen and Ar were used as a bubbler and carrier gas. Polycrystalline cubic SiC protective layers in [110] direction were successfully grown on graphite substrates at temperature as low as 80$0^{\circ}C$ from HMDS by PEMOCVD. In the case of thermal MOCVD, on the other hand, only amorphous SiC layers were obtained with either HMDS or DMS at 85$0^{\circ}C$. We compared the difference of crystal quality and physical properties of the PEMOCVD was highly effective process in improving the characteristics of the a SiC protective layers grown by thermal MOCVD and PEMOCVD method and confirmed that PEMOCVD was highly effective process in improving the characteristics of the SiC layer properties compared to those grown by thermal MOCVD. The as-grown samples were characterized in situ with OES and RGA and ex situ with XRD, XPS, and SEM. The mechanical and oxidation-resistant properties have been checked. The optimum SiC film was obtained at 85$0^{\circ}C$ and RF power of 200W. The maximum deposition rate and microhardness are 2$mu extrm{m}$/h and 4,336kg/mm2 Hv, respectively. The hardness was strongly influenced with the stoichiometry of SiC protective layers.

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A Study on the Change in Microstructures of Traditional Forged High Tin Bronzes by Quenching (담금질 조건에 따른 방짜유기의 미세조직 변화 연구)

  • Lee, Jae-Sung;Jeon, Ik-Hwan;Park, Jang-Sik
    • Journal of Conservation Science
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    • v.27 no.4
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    • pp.421-430
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    • 2011
  • Thermal conditions in practice at the traditional bronze workshop of the Korean Folk Village in Yongin were examined along with the microstructures of some high tin bronze objects made there. Laboratory experiments approximating the conditions of the workshop were also carried out and the results were compared. The operating temperature of the workshop furnace was measured to range from $750^{\circ}C$ to $850^{\circ}C$ while the surface temperature of an object, upon its removal from the furnace for additional thermo-mechanical treatments, was generally in the range of $600^{\circ}C$ to $685^{\circ}C$. This variation in working temperatures was reflected in varying microstructures developed upon quenching. The products of the Folk Village were found to consist of microstructures where the ${\alpha}$ grains of the Cu-Sn system were distributed in the background of different phases including the ${\beta}$-martensite phase, retained ${\gamma}$ phase, ${\alpha}+{\delta}$ eutectoid or their mixtures. This variability, which is also identified in objects made in ancient times as well as in our laboratory experiments, suggests that the actual thermal conditions given during the quenching treatments are much more complicated than is inferred from the temperature measurements. This paper will present detailed accounts of the thermo-mechanical treatments as observed in the high tin bronze workshop of the Korean Folk Village and discuss the evolution of varying microstructures in terms of the substantial variability involved in the implementation of the traditional forged high tin bronze technology of Korea.

INVESTIGATION OF EMISSION RATES OF AMMONIA, NITROUS OXIDE AND OTHER EXHAUST COMPOUNDS FROM ALTERNATIVE- FUEL VEHICLES USING A CHASSIS DYNAMOMETER

  • Huai, T.;Durbin, T.-D.;Rhee, S.-H.;Norbeck, J.-M.
    • International Journal of Automotive Technology
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    • v.4 no.1
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    • pp.9-19
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    • 2003
  • Exhaust emissions were characterized for a fleet of 10 alternative-fuel vehicles (AFVx) including 5 compressed natural gas (CNG) vehicles. 3 liquefied petroleum gas (LPG) vehicles and 2 85% methanol/15% California Phase 2 gasoline (M85) vehicles. In addition to the standard regulated emissions and detailed speciation of organic gas compounds, Fourier Transform Infrared Spectroscopy (FTIR) was used to measure ammonia (NH$_3$) and nitrous oxide ($N_2$O) emissions. NH$_3$, emissions averaged 0.124 g/mi for the vehicle fleet with a range from <0.004 to 0.540 g/mi. $N_2$O emissions averaged 0.022 g/mi over the vehicle fleet with range from <0.002 to 0.077 g/mi. Modal emissions showed that both NH$_3$, and $N_2$O emissions began during catalyst light-off and continued as the catalyst reached its operating temperature. $N_2$O emissions primarily were formed during the initial stages of catalyst light-off. Detailed speciation measurements showed that the principal component of the fuel was also the primary organic gas species found in the exhaust. In particular, methane, propane and methanol composed on average 93%, 79%, and 75% of the organic gas emissions, respectively, for the CNG, LPG. and M85 vehicles.

Prediction on gas exchange process of a multi-cylinder 4-stroke cycle spark ignition engine (다기관 4사이클 스파크 점화기관의 가스 교환과정에 관한 예측)

  • 이병해;이재철;송준호
    • Journal of the korean Society of Automotive Engineers
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    • v.13 no.2
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    • pp.67-87
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    • 1991
  • The computer program which predicts the gas exchange process of multi-cylinder 4-Stroke cycle spark-ignition engine, can be great assistance for the design and development of new engine. In this study, the computer program was developed to predict the gas exchange process of multi-cylinder four stroke cycle spark ignition engine including intake and exhaust systems. When gas exchange process is to be calculated, the evaluation of the variation of the thermo-dynamic properties with time and position in the intake and exhaust systems is required. For the purpose, the application of the generalized method of characteristics to the gas exchange process is known as one of the method. The simulation model developed was investigated to the analysis of the branch system of multi-cylinder. The models used were the 2-zone expansion model and single zone model for in cylinder calculation and the generalized method of characteristic including area change, friction, heat transfer and entropy gradients for pipe flow calculation. The empirical constants reduced to least number as possible were determined through the comparison with the experimented indicator diagram of one particular operation condition and these constants were applied to other operating condition. The predicted pressures in cylinder were compared with the experimental results over the wide range of equivalence ratio and ignition timing. The predicted values have shown good agreement with the experimental results. The thermodynamic properties in the intake and exhaust system were predicted over the wide range of equivalence ratio and ignition timing. The obtained results can be summarized as follows. 1. Pressures in the exhaust manifold have a little influence on the equivalence ratio, a great influence on the ignition timing. 2. Pressures in the inlet manifold are nearly unchanged by the equivalence ratio and the ignition timing. 3. In this study, the behaviors of the exhaust temperature, gas in the exhaust manifold were ascertained.

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Effect of spinning parameters of polyethersulfone based hollow fiber membranes on morphological and mechanical properties

  • Tewfik, Shadia R.;Sorour, Mohamed H.;Shaalan, Hayam F.;Hani, Heba A.
    • Membrane and Water Treatment
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    • v.9 no.1
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    • pp.43-51
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    • 2018
  • Hollow fiber (HF) membranes are gaining wide interest over flat membranes due to their compaction and high area to surface volume ratio. This work addresses the fabrication of HF from polysulfone (PS) and polyethersulfone (PES) using N-methylpyrrolidone (NMP) as solvent in addition to other additives to achieve desired characteristics. The semi-pilot spinning system includes jacketed vessel, four spinneret block, coagulation and washing baths in addition to dryer and winder. Different parameters affecting dry-wet spinning phase inversion process were investigated. Dope compositions of PES, NMP and polyvinyl pyrrolidone (PVP) of varying molecular weights as additive were addressed. Some critical parameters of importance were also investigated. Those include dope flow rate, air gap, coagulation & washing baths and drying temperatures. The measured dope viscosity was in the range from 1.7 to 36.5 Pa.s. Air gap distance was adjusted from 20 to 45 cm and coagulation bath temperature from 20 to $46^{\circ}C$. The HF membranes were characterized by scanning electron microscope (SEM), atomic force microscope (AFM) and mechanical properties. Results indicated prevalence of finger like structure and average surface roughness from about 29 to 78.3 nm. Profile of stress strain characteristics revealed suitability of the fibers for downstream interventions for fabrication of thin film composite membrane. Different empirical correlations were formulated which enable deeper understanding of the interaction of the above mentioned variables. Data of pure water permeability (PWP) confirmed that the fabricated samples fall within the microfiltration (MF)-ultrafiltration (UF) range of membrane separation.

The Effect of the Fill Charge Ratio on the Heat Transfer Characteristics of a Two-Phase Closed Thermosyphon (충전율의 변화가 밀폐형 2-상 열사이폰의 열전달 특성에 미치는 영향에 관한 연구)

  • Park, Yong-Joo;Hong, Sung-Eun;Kim, Chul-Ju
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.12
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    • pp.1646-1654
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    • 2002
  • A two-phase closed thermosyphon was one of the most effective devices in the removing heat because of its simple structure, thermal diode characteristics, wide operating temperature range and so on. In this study, a two-phase closed thermosyphon(working fluid PFC(C6F14), container copper(inner grooved surface)) was fabricated with a reservoir which can change the fill charge ratio. The experiments were performed in the range of 50~600W heat flow rate and 10~70% fill charge ratio. The results were compared with some correlations that were presented by Rohsenow and Immura et al. in the evaporator, by Nusselt, Gross and Uehara et al. in the condenser and by Cohen and Bayley, Wallis, Kutateladze and Faghri et al. in heat transfer limitation etc.. The heat transfer coefficient at the evaporator increased with the input power. However the effect of the fill charge ratio was nearly negligible. At the condenser, it showed an opposite trend to the evaporator and with increase of the fill charge ratio, showed some enhancement of heat transfer. The heat transport limitation was occurred by the dry-out limitation for small fill charge ratio(10%) and presented about 100W. For the case of large fill charge ratio(Ψ$\geq$40%), it was occurred by the flooding limitation at about 500W.

A Study on the Construction of Littman and Littrow Type Tunable Diode Laser Systems (Littman 및 Littrow 타입 파장가변 반도체 레이저의 제작에 관한 연구)

  • Baek, Woon-Sik
    • Korean Journal of Optics and Photonics
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    • v.17 no.3
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    • pp.273-277
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    • 2006
  • In this paper, we constructed the Littman type and fixed Littrow type tunable external-cavity diode laser systems. The laser output, which is the 0th-order diffracted beam from the diffraction grating in an external cavity, was the single longitudinal mode. Its FWHM was measured as less than 9MHz. With the diode driving current of 140mA and operating temperature of $25^{\circ}C$, the coarse tuning range of 5.375nm was measured for the Littman type, and of 13.65nm was measured for the fixed Littrow type. A fine tuning experiment in which an external mirror was rotated by a PZT driven by a sawtooth wave was performed, and its tuning range of 0.042nm was measured for both types. The fixed Littrow type tunable external-cavity diode laser system was an improvement on the conventional Littrow type tunable laser system in which the output direction varies due to the grating embedded in the mirror plate.