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Synthesis of Organized $TiO_2$ Electrodes Using Graft Copolymer and Their Applications to Dye-Sensitized Solar Cells (가지형 공중합체를 이용한 나노구조 $TiO_2$ 제조 및 염료감응 태양전지 응용)

  • Ahn, Sung Hoon;Koh, Joo Hwan;Park, Jung Tae;Kim, Jong Hak
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.64.1-64.1
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    • 2010
  • The morphology of mesoporous $TiO_2$ films plays an important role in the operation of a DSSC. For example, the energy conversion efficiency of DSSCs with well-organized mesoporous $TiO_2$ films is much higher than those with traditional films possessing a random morphology. In previous research, well-organized mesoporous $TiO_2$ films have mainly been synthesized using an amphiphilic block copolymer, e.g., a poly(ethylene oxide) (PEO)-based template. A graft copolymer is more attractive than a block copolymer due to its low cost and the ease with which it can be synthesized. In this work, we provide the first report on the successful synthesis of well-organized mesoporous $TiO_2$ films templated by an organized graft copolymer as a structure directing agent. Well-organized mesoporous $TiO_2$ films with excellent channel connectivities were developed via the sol gel processusing an organized PVC-g-POEM graft copolymer synthesized by one-pot ATRP. The careful adjustment of copolymer composition and solvent affinity using a THF/$H_2O$/HCl mixture was used to systematically vary the material structure. The influence of the material structure on solar cell performance was then investigated. A solid-state DSSC employing both the graft copolymer templated organized 700 nm-thick $TiO_2$ films and graft copolymer electrolytes exhibited a solar conversion efficiency of 2.2% at 100 $mW/cm^2$. This value was approximately two-fold higher than that attained from a DSSC employing a random mesoporous $TiO_2$ film. The solar cell performance was maximized at 4.6% when the film thickness was increased to $2.5{\mu}m$. We believe that this graft copolymer-directed approach introduces a new and simple route toward the synthesis of well-organized metal oxide films as an alternative to a conventional block copolymer-based template.

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A Study on the Utilization of Korean Traditional Food in Gwangju and Jeonnam Area Dietitians - For the Elementary, Middle and High Schools - (광주$\cdot$전남지역 학교영양사의 한국 전통음식 활용실태에 관한 연구 -초$\cdot$$\cdot$고등학교의 비교-)

  • Jung Lan-Hee;Jeon Eun-Raye
    • Journal of the Korean Home Economics Association
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    • v.43 no.9 s.211
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    • pp.97-107
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    • 2005
  • The purpose of this study was to investigate the elementary, middle and high school food service utilization of traditional Korean food in Gwangju and Jeonnam Area dietitians, and to provide basic data for the utilization of traditional food in school food service. The conclusions of this study are as follows. The utilizations of traditional Korean food was remarkable among the dietitians who are elderly, have worked for a long time, are married and in elementary schools. For the elementary, middle and high schools, the utilization of rice was remarkable in Bombop(boiled rice and nuts)(p<.001), Okeukbop(boiled rice mixed with five grains)(p<.001), Potbop(boiled rice and red-bean)(p<.001), Boribop(boiled rice and barley)(p<.01), and Kongbop(boiled rice and beans)(p<.01) The utilization of one-dish meals was remarkable in Kongnamulbop(boiled rice and bean sprouts)(p<.001). The utilization of porridge was remarkable in Hobakjuk(pumpkin porridge)(p<.001) and Potjuk(red-bean porridge)(p<.001). The utilization of noodles was remarkable in Mandu soup(a bun stuffed with seasoned meat and vegetables)(p<.001) and Kalkuksu(cut noodles)(p<.001). The utilization of soup and pot stew was remarkable in Kongnamul soup(p<.001), sagolugeoji soup(p<.001), Calbitang(p<.001) and sullungtang(p<.001), kongbiji stew(p<.01), and soondubu stew(p<.05). The utilization of steamed dish and hard-boiled food was remarkable in green perilla stew(p<.001), fish stew(p<.001) and seasoned and steamed pollack(p<.01). The utilization of pan-boiled food stew was remarkable in small octopus stew(p<.001). The utilization of fried food or grilled food was remarkable in grilled fish(p<.001), bindaetteok(vegetable pancake)(p<.001), fried green pumpkin(p<.001), fried sea food with stone-leek(p<.001) and Buchu fried food(p<.001). The utilization of salad and cooked vegetables was remarkable in spinach salad(p<.001), cucumber salad(p<.001) and Kongnamul(bean sprouts)(p<.05). The utilization of Kimchi was remarkable in Baek kimchi(p<.001), Gat(leaf-mustard) kimchi(p<.001), Youlmu(young radish) kimchi(p<.01) and Oisobaki(p<.01). The utilization of desserts was remarkable in seasonable fruits(p<.001), Kangjung(p<.01), Tteok(rice cake)(p<.01) and Sik Hye(Cinnamon flavored persimmon punch)(p<.01).

STATISTICAL STUDY ON HABITUAL METHODS Of TOILET TRAINING FOR INFANT AND TODDLER (한국 영.유아의 대소변 가리기 훈련습성에 관한 일 연구)

  • 최경자
    • Journal of Korean Academy of Nursing
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    • v.3 no.3
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    • pp.119-132
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    • 1973
  • This study observed on habitual methods of toilet training for infants and toddlers in Korea thru 300 mothers at four medical institutions Ewha Woman′s University Hospital, Ewha Maternal and Child Health Center, Severance Hospital and Seoul National University Hospital) with a design to analyze beginning time, duration of period, methods employed, motives, equipments used, special terminology used for the subject training. The main purpose of this study was to generalize the proper methods of toilet training, and also to contribute a better psychological education for the mother and child. The results obtained from this study were as follows; 1. Majority of (67.3%) observed were in the age category between 30 and 40 years, and dominant numbers (64.7%) were housewives with high level of education and from middle class family background. 2. In the most cases (85%), toilet training was carried out by mothers(including wives who had a job) while more than half of mothers (53.7%) maintained their important motive for the training was "due to having high regard for cleanliness" 3. As for the time of beginning toilet training: finding indicated that starting period was decided (70%) at inconsiderate desertion of each mother. whereas, only minority group (30%) represents the cases where mother started the training when they consider tile child was physically and psychologically randy. Also greater number (77.7%) started bladder training prior to that of bowel. 4. It is noticeable that in course of training a large number of mothers (48.3%) applied strict training method when the child proper talenting, and the more rigid and strict in tile training. the more malformation of personality of the infant and toddler were seen after the training period (P<0.01). 5. Over the half of the total cases denoted (bowel 54.3%, bladder 67.7%) starting period before one year and in most cases (bowel 79.3%, bladder 729)the training was accomplished within 12 month, and therefore it was noted that earlier start(before 1 year) shortened the training period (with 12 month) . There was no significant difference between male and female infants in both starting period and duration of period in bladder training, however, in bowel training there was a tendency that female started earlier(7-12 months needed, 51.4%) than tile male (13-18 months needed, largest number 41.4%), and also in cases of female the period for needed for training were shorter than the cases of male. 6. Many a number (bowel 50.3%, bladder 97.7%) employed the method of continuous talenting at regular interval in accordance with that of child′s habit formed before training. Equipment used were various kinds, however, pieces of paper for male (45.5%) and piss pot or bedpost (42.3%) for female were common, on the other hand, "Eung-ga" for defecation (52.3%) and "Shii" for the urination (95.3%) were most standard expression that used during the training period.

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Stereoselective Synthesis of Novel Bestatin Analogs (새로운 베스타틴 유사체의 입체선택적 합성)

  • Seo, Youngran;Lee, SooBeom;Kim, Young Gyu
    • Applied Chemistry for Engineering
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    • v.26 no.1
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    • pp.111-115
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    • 2015
  • Two new analogs of bestatin were prepared from $\small{D}$-leucine and $\small{D}$-valine in a stereoselective and efficient way. An aminopeptidase inhibitor bestatin shows significant biological effects on immunomodulation and is marketed for the treatment of acute myelocytic leukemia. The key intermediates, trans-oxazolidine methyl esters 2a and 2b, were obtained with more than 20 to 1 stereoselectivity in a one-pot procedure by the three cascade reactions between N-hydroxymethyl protected ${\alpha}$-amino aldehydes (4a and 4b) and phenylsulfonylnitromethane ($PhSO_2CH_2NO_2$) and the following in-situ ozonolysis. Basic hydrolysis of 2a and 2b, and then the peptide coupling with $\small{L}$-Leu-OMe produced the protected derivatives of two new bestatin analogs, 3a and 3b, respectively. The new isobutyl and isopropyl analogs of bestatin (1a and 1b) were produced in overall 51% and 38% yields, respectively, with high stereoselectivity from the corresponding protected ${\alpha}$-amino aldehydes 4 in a six-step process.

Separation of Aluminum and Iron from Platinum Mixture using Synthetic Extraction Resins (합성(合成) 추출(抽出) 수지(樹脂)를 이용(利用)한 백금용액(白金溶液)으로부터 알루미늄과 철(鐵)의 분리(分離))

  • Lim, Gwang-Il;Han, Dong-Hyuk;Hwang, In-Sung;Han, Choon;Lee, Jin-Young;Kim, Joon-Soo;Park, Hyung-Kyu
    • Resources Recycling
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    • v.20 no.3
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    • pp.68-76
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    • 2011
  • For the separation of aluminum and iron from platinum mixtures, extraction resins were synthesized and separation efficiencies were compared with those by commercial one, $P_{204}$. During synthesis, the suspension polymerization method was adopted with D2EHPA as an extractant. Also, benzoyl peroxide as a starter was divided into 3parts and injected for the uniform size and dispersion of resin particles. Comparison tests resulted in 100% separation of Fe and Pt for both synthetic and $P_{204}$ resins. In case of Al and Pt, synthetic and $P_{204}$ resin gave extraction efficiencies of 99.9% and 98.9%, respectively. Difference in extractant contents of synthetic resin(61.8%) and $P_{204}$(60%) was considered to give differences in separation efficiencies of aluminum and iron elements. For both resins, separation efficiencies of Al and Fe increased up to $55^{\circ}C$. According to FT-IR analyses of both resins, specific peaks of D2EHPA and crosslinked polystyrene were identified at the wavenumber of $1000cm^{-1}$ and $2900cm^{-1}$ respectively.

Growth and Soil Chemical Property of Small Apple Trees as Affected by Organic Fertilizers and Mulch Sources (비료원과 멀칭재료에 따른 사과 유묘의 생장 및 토양이화학성 변화)

  • Choi, Hyun-Sug;Rom, Curt;Lee, Youn;Cho, Jung-Lai;Jung, Seok-Kyu;Jee, Hyeong-Jin
    • Korean Journal of Environmental Agriculture
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    • v.30 no.1
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    • pp.9-15
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    • 2011
  • BACKGROUND: This study was conducted to evaluate the effects of the fertilizer sources and ground cover mulches on nutrient release, growth, and photosynthesis in small one-year-old apple (Malus ${\times}$ domestica Borkh.) trees in controlled conditions. METHODS AND RESULTS: Treatments included no fertilizer (NF), commercial organic fertilizer (CF), and poultry litter (PL) for fertilizer treatments, and wood chips (WC), shredded paper (SP), green compost (GC), and grass clippings (GR) for cover mulch treatments. All treatments were applied proportionally based on the volume ratio equivalent to the soil. CF, PL, and GR treatments that had optimum carbon (C) and nitrogen (N) ratios (less than 30:1) for N mineralization through the microbes released the greatest $NH_4^+$ concentrations in the pot media at 90 days after the treatments, but GC mulch with the optimum C:N ratio did not. CF-, PL- and GR-treated plants had the largest leaf area, thickest stem diameter, longest shoot extension, and greater dry matter production. CONCLUSION(s): CF and PL showed an suitable organic nutrient source for improving plant growth in an orchard. Interestingly, GR also could be a nutrient source for tree growth, if vegetation competition is controlled by maintaining vegetation height and recycling enough grass clippings to the soil in an orchard.

A Study on Utilization Effect and Implementation Model of Directory Service Based Information Resource Management System (디렉터리 서비스 기반 정보자원 관리시스템의 활용 효과 및 구축 모델에 대한 연구)

  • Lee, Sung-Jun;Kim, Hyuk;Lee, Kwang Soo;Kim, Minsoo
    • Journal of Information Technology and Architecture
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    • v.11 no.4
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    • pp.427-439
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    • 2014
  • Introduction of new information systems due to continuous progress of ICT has made the enterprise IT environment into a mixed pot of various IT resources. Rapidly changing business situation has emphasized the integration of organizational IT resources as one of key competitive advantages. Those distributed IT resources are now demanding to solve the problems not only on their own effective management but also on security and control issues against unauthorized infiltration and information leakages. Under the situation that the number of IT resources is constantly increasing, it is needed to study a management model and its implementation that integrally solves above all problems. In this paper, it is revealed that a directory service can be used to integrally manage distributed IT resources and a directory service based system model for distributed IT resource management is suggested. By implementing an HR solution over active directory service, it is demonstrated that our integrated management model for distributed resources is applicable to real business cases. It is expected that for small and medium sized enterprises with limited IT investments, directory service based IT resource management system can be a cost-effective solution for increasing security threats and lack of governance.

Biocontrol Potential of Streptomyces griseus H7602 Against Root Rot Disease (Phytophthora capsici) in Pepper

  • Nguyen, Xuan-Hoa;Naing, Kyaw-Wai;Lee, Young-Seong;Tindwa, Hamisi;Lee, Geon-Hyoung;Jeong, Byoung-Kon;Ro, Hee-Myeong;Kim, Sang-Jun;Jung, Woo-Jin;Kim, Kil-Yong
    • The Plant Pathology Journal
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    • v.28 no.3
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    • pp.282-289
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    • 2012
  • The root rot of pepper (Capsicum annuum L.) caused by Phytophthora capsici is one of the most important diseases affecting this crop worldwide. This work presents the evaluation of the capacity of Streptomyces griseus H7602 to protect pepper plants against Phytophthora capsici and establishes its role as a biocontrol agent. In this study, we isolated an actinomycete strain H7602 from rhizosphere soil, identified it as Streptomyces griseus by 16S rRNA analysis and demonstrated its antifungal activity against various plant pathogens including P. capsici. H7602 produced lytic emzymes such as chitinase, ${\beta}$-1,3-glucanase, lipase and protease. In addition, crude extract from H7602 also exhibited destructive activity toward P. capsici hyphae. In the pot trial, results showed the protective effect of H7602 against pepper from P. capsici. Application of H7602 culture suspension reduced 47.35% of root mortality and enhanced growth of pepper plants for 56.37% in fresh root and 17.56% g in fresh shoot as compared to control, resulting in greater protection to pepper plants against P. capsici infestation. Additionally, the enzymatic activities, chitinase and ${\beta}$-1,3-glucanase, were higher in rhizosphere soil and roots of pepper plants treated with H7602 than other treated plants. Therefore, our results indicated a clear potential of S. griseus H7602 to be used for biocontrol of root rot disease caused by P. capsici in pepper.

The Anti-bacterial Activity of Eco-friendly Farming Material based on Chinese Nut-gall Extraction on Acidovorax citrulli (오배자 추출물 유래 친환경제제의 세균성과실썩음병균에 대한 항세균활성)

  • Seo, Tae-Jin;Yang, Soo-Jeong;Lee, Bong-Choon;Kim, Kang-Min;Lee, Kui-Jae;Ju, Ho-Jong
    • Korean Journal of Organic Agriculture
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    • v.24 no.3
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    • pp.571-582
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    • 2016
  • Bacterial fruit blotch (BFB) is one of most important diseases in Cucurbitaceae due to infection of Acidovorax citrulli, causing huge economic losses damage worldwide. This seedborn disease spread rapidly at period of high temperature and humidity. The eco-friendly farming is getting popular. So far there was no effective agent to control BFB in eco-friendly farming. Therefore, effect of the material based on chinese nut-gall extract with antibacterial activity against BFB to was tested against A. citrulli. Different hosts showed various symptoms of BFB. Liquid formulation among exhibited most effective anti-bacterial activity on A. citrulli. Pot experiment in greenhouse showed the potential as an control agent of BFB in cucurbits. The treatment of material based on chinese nut-gall extract showed the positive effect on survival of the watermelon seedling and on the length of the cucumber seedling treated with A. citrulli. We cautiously conclude that the material based on chinese nut-gall extract used in this study may be good agents against major diseases of cucurbits in the future even though it is require to be tested with more study on field test.

The Interrelationships between Yield, Transpiration of the Tobacco Plant, and Seasonal Meteorological Factors during the Growing Season I. Interrelationship between Change of Soil Moisture and Transpiration during the Growing Season (연초재배기간중(煙草栽培期間中) 증산량(蒸散量) 및 수량(收量) I. 연초생육기간(煙草生育期間)동안의 증산량변화(蒸散量變化)와 토양수분(土壤水分)과의 상호관계(相互關係))

  • Hong, Soon-Dal;Kim, Jai-Joung;Cho, Seong-Jin;Lee, Yun-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.3
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    • pp.228-233
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    • 1989
  • Successive changes of transpiration by the tobacco plant during the growing season with pot trial treated with 30cm and 100cm ground water tables were compared with change of soil moisture content in rhizospere of field under natural rainfall conditions. Transpiration from the 41st to the 60th day after transplanting was the highest showing about 50% of total transpiration of whole cultivation period. As the result, soil moisture condition in rhizospere of field was kept insufficiently during the above period. Transpiration by the plant was so remarkably affected by the meteorological environment that the transpiration on rain-cloudy day was one third of that on clear day at middle stage of the growth. Maximum transpiration in a clear day was obtained from 14:00 to 16:00 at the 58th day after transplanting.

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