• Title/Summary/Keyword: One-phase reaction

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Reaction Characteristics of Rubbers and LPG fuels in LPLi Fuel Supply System (고무류 반응특성이 LPG액상공급시스템의 연료분사기 성능에 미치는 영향)

  • Kim, Chang-Up;Park, Cheol-Woong;Choi, Kyo-Nam;Kang, Kern-Yong
    • Journal of ILASS-Korea
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    • v.12 no.2
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    • pp.94-100
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    • 2007
  • The liquid phase LPG injection (LPLi) system (the third generation technology) has been considered as one of the next generation fuel supply systems for LPG vehicles, since it has a very strong potential to accomplish the higher power, higher efficiency, and lower emission characteristics than the mixer type (the second generation technology) fuel supply system. To investigate the characteristics of LPG residue in liquid phase LPG injection system, various rubbers in LPG fuel system were reacted with LPG fuels during 3 months. The experimental results showed that the residue of a cover rubber in a fuel pump after test increased 10 times higher than that before test. Furthermore, the amount of sulfur, nitrogen species which are considered as main sources in deposit formation in the LPLi fuel injector were also found to be higher than that in original LPG fuel. And rubber properties of fuel pump cover were decreased after reaction test compared with those of the original rubber. Therefore, the rubber for fuel pump cover is not suitable for a proper material in LPLi fuel system. And these results can provide more information if a motor company shares the data of core rubber parts in field test LPLi vehicles.

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Altered Ground Reaction Forces in Individuals with Chronic Ankle Instability Compared to Lateral Ankle Sprain Copers and Healthy Controls during Walking

  • Inje Lee;Sunghe Ha;Sae Yong Lee
    • Korean Journal of Applied Biomechanics
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    • v.33 no.3
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    • pp.94-100
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    • 2023
  • Objective: Few studies have investigated alterations of ground reaction force (GRF) in individuals with chronic ankle instability (CAI) compared with lateral ankle sprain (LAS) copers and healthy controls during walking. This study aimed to investigate differences in GRF variables among the CAI, LAS coper, and control groups. Method: Eighteen individuals with CAI, 18 LAS copers, and 18 healthy controls were recruited for this study. All participants walked on 8-m walkway with a force plate three times. GRF data during stance phase were extracted and analyzed. The analysis of variance and ensemble curve analysis were used for statistical analyses of discrete points and time-series data respectively. Results: The CAI group showed a greater loading rate (LR) and a shorter time to impact peak force than the other groups, as well as decreased vGRF from 56% to 65% in the stance phase than the control group. No significant differences were noted in the other variables. Conclusion: Based on these findings, individuals with CAI should enhance their ability to create propulsion during the push-off phase and spend more time absorbing GRF to decrease the LR, which is considered one of risk factors for overuse injury and ankle osteoarthritis.

A study on Sintering Characteristics of Commercial 7xxx Series Al Alloy Powders (상용 7xxx Series Al 합금계 혼합분말의 소결 특성)

  • ;;;Panyu
    • Journal of Powder Materials
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    • v.11 no.1
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    • pp.69-73
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    • 2004
  • The sintering characteristics of commercial 7xxx series Al-Zn-Mg-Cu alloy have been investigated. Sintering system of this blended elemental powder has aspects of both transient and supersolidus liquid phase sintering. Transient liquids occur when the constitution point during sintering lies in a solid phase region but where the sintering temperature is greater than either the melting point of one of the constituent or a eutectic temperature. Supersolidus liquid phase sintering occurs when a preblended powder is heated to a temperature between the solidus and liquids. However, these reaction were restrained their inter diffusion due to the appearance of the oxide film. Thus, 7xxx series Al alloy is extremely sensitive to process variables, including particle size, holding time and sintering temperature. Therefore, above phenomenons were observed formation and behaviour of the liquid by using SEM and DSC.

Measuring Nano-Width of Wave Fronts in Combustion: a Numerical Approach (연소시 발생하는 파면의 나노 사이즈 두께 측정: 수치적 접근)

  • Yoh, Jai-Ick
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.20-27
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    • 2005
  • I consider the structure of steady wave system which is admitted by the continuum equations for materials that undergo phase transformations with exothermic chemical reaction. In particular, the dynamic phase front structures between liquid and gas phases, and solid and liquid phases are computationally investigated. Based on the one-dimensional continuum shock structure analysis, the present approach can estimate the nano-width of waves that are present in combustion. For illustration purpose, n-heptane is used in the evaporation and condensation analysis and HMX is used in the melting and freezing analysis of energetic materials of interest. On-going effort includes extension of this idea to include broad range of liquid and solid fuels, such as rocket propellants.

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XRD Study for the Effect of Aging and Gel Composition on the Crystdlinity of MCM-41 (숙성과 겔 성분이 MCM-41의 결정성에 미치는 효과에 대한 XRD 연구)

  • Park, Dong-Ho;Park, Sung-Soo
    • Journal of the Korean Chemical Society
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    • v.44 no.1
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    • pp.52-59
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    • 2000
  • The reaction gel mixtures of molar composition (0.3${\sim}$2.1) $SiO_2:\;(0.10{\sim}0.50)\;CTABr:\;0.15{\sim}0.23)\;TMAOH:\;(20{\sim}100)\;H_2O$ we prepared and then aged at room temperature for a definite duration. The aged gel is reacted hydrothermally at $150^{\circ}C$ for 2 days. The pH of reaction gel during synthesis is strongly influenced by the concentration of TMAOH and silica source. The pH change affects the phase of product, which is monitored by X-ray diffractometer. With increasing the TMAOH ratio from 0.19 to 0.23, the gel becomes more basic, and the product involves more lamellar phase. At TMAOH ratio lower than 0.19, the hexagonal phase is lower with decrease of pH. The content of the lamellar phase increases at a lower $SiO_2$ concentration, and higher concentrations have a clear detrimental effect on the crystallinity ofMCM-41 due to an excess silica source. The best quality MCM-41 is synthesized from a reaction gel composition of $1.0\;SiO_2:\;0.27\;CTABr:\;0.19\;TMAOH:\;40\;H_2O$. The pH values of this gel, aged one for 24 hr, and reacted one at $150^{\circ}C$ for 2 days are 12.3, 11.5, and 10.5, respectively. Gel aging for 24 h is essential for preparing high quality MCM-41. Longer aging causes a decrease of hexagonal phase.

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A Comparative Study on Electrochemical Impedance Analysis of Solid Carbon Fuels in Direct Carbon Fuel Cell (직접탄소 연료전지에서 고체 탄소 연료에 따른 전기화학 임피던스 비교 연구)

  • Cho, Jaemin;Eom, Seongyong;Lee, Gwangseob;Ahn, Seongyool;Kim, Duckjool;Choi, Gyungmin
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.6
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    • pp.620-628
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    • 2014
  • Direct Carbon Fuel Cell(DCFC) is one of new power generation that the chemical energy of solid carbon can be converted into electrical energy directly. At the high temperature, the electrochemical reaction of the carbon takes place and the carbon reacts with oxygen to produce carbon dioxide as followed overall reaction ($C+O_2{\rightarrow}CO_2$). However, in case of using the raw coals as a fuel of DCFC, the volatile matter containing carbon, hydrogen, and oxygen produces at operating temperature. In this study, the electrochemical reaction of Adaro coal was compared with Graphite. This work focused on the electrochemical reaction of two kinds of solid carbon by Electrochemical Impedance Spectroscopy(EIS). The EIS results were estimated by equivalent circuit analysis. The constant phase element(CPE) was applied in Randle circuit to explain an electrode and fuel interface. The correlation between the fuel characteristic and electrochemical results was discussed by elements of equivalent circuit of each fuel.

The Effct of SHS Reaction Heat Control on the Microstructure of TiAl (고온 자전 합성시 반응열 제어가 TiAl 미세 조직에 미치는 영향에 관한 연구)

  • Mun, Jong-Tae;Yeom, Jong-Taek;Sin, Bong-Mun;Kim, Yong-Seok;Lee, Yong-Ho
    • Korean Journal of Materials Research
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    • v.5 no.7
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    • pp.869-879
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    • 1995
  • TiAi intermetallic compound has been extensively studied for possible high temperature structural applications because of its high specific strength at high temperature, high creep resistance, and good oxidation resistance at elevated temperatures. In addition to its good properties, an economic manufacturing routes should be developed for this material to be used more extensively. One of the promising route in manufacturing TiAl intermetallics is the Self-propagating High-temperature Synthesis (SHS) method. Thus in this study, an attempt was made to study the mechanism of the SHS process in TiAl synthesis. The composition of the sample was Ti-(45, 50, 53)at% Al and the microstuctures of the products were analyzed using optical microscope and scanning electron microscope. When the phases formed at the main SHS reaction of whicyh combustion temperature is higher than the melting temperature of aluminum were identified as TiAl and Ti$_3$Al ; Ti$_3$Al cores surrounded by TiAl phase. In order to increase the combustion temperature, carbon was added 5 and 10at.%. When the carbon content was 10at.%, the heat of the reaction was large enough to melt the phase formed and that is consistent with the theoretical calculation results of the adiabatic temperature. The combution temperatue, which was measured by a computer data acquisition system, increased with the carbon content. The phases formed from the reaction involving the carbon added were indentified as TiAl and Ti$_2$AlC using XRD. The vickers hardness of the reaction product increased with the carbon content.

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Effect of Space Velocity on the DeNOx Performance in Diesel SCR After-Treatment System (디젤 SCR 후처리장치 내 공간속도가 NOx 저감에 미치는 영향)

  • Wang, Tae-Joong;Baek, Seung-Wook;Kang, Dae-Hwan;Kil, Jung-Ki;Yeo, Gwon-Koo
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.49-54
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    • 2006
  • The present study conducted a numerical modeling on the diesel SCR (selective catalytic reduction) system using ammonia as a reductant over vanadium-based catalysts $(V_2O_5-WO_3/TiO_2)$. Transient modeling for ammonia adsorption/desorption on the catalyst surface was firstly carried out, and then the SCR reaction was modeled considering for it. In the current catalytic reaction model, we extended the pure chemical kinetic model based on laboratory-scale powdered-phase catalyst experiments to the chemico-physical one applicable to realistic commercial SCR reactors. To simulate multi-dimensional heat and mass transfer phenomena, the SCR reactor was modeled in two dimensional, axisymmetric domain using porous medium approach. Also, since diesel engines operate in transient mode, the present study employed an unsteady model. In addition, throughout simulations using the developed code, effects of space velocity on the DeNOx performance were investigated.

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Two-Phase Anaerobic Digestion of Food and Livestock Wastewater and Hygienic Aspects of the Digested Water (음식물폐기물과 축산분뇨 혼합폐수의 이상혐기소화에 따른 소화액의 위생성 연구)

  • Jeong, Doo-Young;Chung, Myung-Hee;Kim, Young-Jun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.4
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    • pp.66-73
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    • 2009
  • Temperature phase anaerobic co-digestion process was conducted with the one to one mixture of food wastewater with livestock wastewater, and the presence and the dynamics of various pathogenic microorganisms was analyzed. The mixture contained various enteric and pathogenic bacteria, such as Escherichia coli. Enterobacteriaceae, Coliform bacteria. Staphylococcus aureus, Salmonella, Shigella, Listeria, and Yeast. Anaerobic digestion has become stabilized around 21 days after the reaction started, showing about 80% to 90% of remarkable reduction rates of microorganisms until this period in acidogenic reactor (AR) and methanogenic reactor (MR), respect ively. After stabilization, the average reduction rate of organic matter was recorded as around 60% in MR. Most microorganisms in the effluent were not detected at around the last period of the reaction, except Listeria and S. aureus, which showed the growth even at the last day of the reaction.

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The Immediate Effects of Ankle Restriction Using an Elastic Band on Ground Reaction Force during a Golf Swing

  • Yi, Kyungock;Kim, OkJa
    • Korean Journal of Applied Biomechanics
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    • v.26 no.2
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    • pp.191-195
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    • 2016
  • Purpose: The purpose of this study was to analyze the immediate effects of ankle restriction with an elastic band on ground reaction force during a golf swing. Method: There were five subjects who were teaching pros with an average golf score of 75. A force platform (9281B, Switzerland) was used. The independent variable was the presence of an elastic band. The dependent variables were three-dimensional ground reaction forces to analyze the transfer of momentum with the timing, control and coordination of the three forces. A paired t-test within subject repeated measure design was used via an SPSS 20.0. Results: Wearing an elastic band around one's ankles significantly makes shorter time differences between the moment of cross anterior / posterior forces and vertical force and median value of anterior / posterior forces during the backswing, between medial and lateral maximum and anterior / posterior force from the top of the back swing to the mid down swing, and creates an anterior / posterior maximum force. Conclusion: Wearing an elastic band around one's ankles affects control and coordination between three dimensional forces, and anterior force power according to each phase of the golf swing.