• Title/Summary/Keyword: Oil-water Interface

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On Oil-Water Interface of Oil Layer Contained in Tandem Oil Fences (이중유벽 사이에 가두어진 기름층의 거동특성)

  • Doh D.H.;Hyun B.S.;Choi S.H.;Hong S.H.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.1
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    • pp.25-34
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    • 2000
  • A panoramic-PIV technique is employed to characterize the travelling tip vortices and the profile of oil-water Interface in the tandem fence arrangement. Instantaneous as well as time-averaged velocity profiles of the water layer close to the interface were obtained to evaluate the possibility of measuring the shear stress distribution on oil-water interface. It was proven that the present technique could provide some qualify data precise enough to resolve detailed flow structures inside a shear layer formed on oil-water interface provided it is nearly stationary.

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Cosmetic Emulsions: Stabilization by Particles (화장품 에멀젼: 입자에 의한 안정화)

  • Cho, Wan-Goo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.36 no.1
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    • pp.1-16
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    • 2010
  • The preparation and properties of emulsions stabilized by the adsorption of solid particles at the oil-water interface are reviewed. Comparison is made with the behaviour of surfactant-stabilized emulsions. Many of the properties of Pickering emulsions are attributed to the large free energy of adsorption for particles. The main differences is due to the irreversible adsorption of particles to the interface. Phase inversion from w/o (water-in-oil) to o/w (oil-in-water) can be brought by increasing the volume fraction of water. Hydrophilic particles tend to form o/w emulsion whereas hydrophobic particles form w/o emulsion. The contact angle at the oil-water interface is main parameter to decide the emulsion type. The aspects of stability of Pickering emulsions are in contrast to general emulsions in some points. The possibility using Pickering emulsions for cosmetics is also proposed.

Polymer Adsorption at the Oil-Water Interface

  • Lee, Woong-Ki;Pak, Hyung-Suk
    • Bulletin of the Korean Chemical Society
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    • v.8 no.5
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    • pp.398-403
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    • 1987
  • A general theory of polymer adsorption at a semi-permeable oil-water interface of the biphasic solution is presented. The configurational factor of the solution in the presence of the semi-open boundary at the interface is evaluated by the quasicrystalline lattice model. The present theory gives the feature of the bulk concentration equilibria between oil-water subsystems and the surface excesses of ${\Gamma}^{\alpha}$ and ${\Gamma}^\{beta}$ of the polymer segments as a function of the degree of polymerization $\gamma$, the Flory-Huggins parameter in $\beta$-phase $x_{\rho}^{{\beta}_{\rho}}$, the differential adsorption energy parameter in $\beta$-phase $x_{\sigma}^{{\beta}_{\rho}}$, the differential interaction energy parameter ${\Delta}x_{\rho}$ and the bulk concentration of the polymer in ${\beta}-phase ${\varphi}_2^{{\beta(*)}_2}$. From our numerical results, the characteristics of ${\Gamma}^{\alpha}$ are shown to be significantly different from those of ${\Gamma}^{\beta}$ in the case of high polymers, and this would be the most apparent feature of the adsorption behavior of the polymer at a semi-permeable oil-water interface, which is sensitively dependent on ${\Delta}x_{\rho}$ and r.

Shearing Conditions on the Interface of a Spherical Water Drop Sinking in Silicone Oil

  • Uemura, Tomomasa;Yamauchi, Makoto
    • Journal of Mechanical Science and Technology
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    • v.15 no.12
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    • pp.1845-1852
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    • 2001
  • This paper deals with the experiment to obtain quantitative information about conditions of the interface between a water drop and surrounding oil. Velocity distributions in very close region of the interface are measured by introducing a new illumination technique and a telecentric lens. It enables precise measurements of velocity distributions in the close region to the interface. Although the measured velocity distributions exhibit strong influence from the solid wall of an experimental tube, the coincidence of inner and outside velocities on the interface is clearly confirmed for the clean interface. The shearing stresses on the interface, which are proportional to the velocity gradient normal to the interface, clearly show conditions of contaminated interface, which can be divided into two parts. From front stagnation point to somewhere near a separation point, the distribution of shearing stresses is well coincide with that of the Hadamard's analytical solution, while the distribution on the latter part of the interface sows quite different feature, which is supposed to be strongly influenced by contamination of the surface.

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An Experimental Study on Low-Temperature Behavior of Stratified Fluids in a Square Cavity with Upper Cooling Surface (상부에 냉각면이 있는 정방형내 이종유체의 저온거동에 관한 실험적 연구)

  • Lee, D.S.;Kim, B.C.
    • Solar Energy
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    • v.20 no.1
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    • pp.55-62
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    • 2000
  • An experimental study on the stratified fluids with water and silicon oil of same volume in the cavity with upper cooling surface was carried out to investigate the flow characteristics, heat transfer through the interface of fluids, and the applications of thermal behaviors in a square cavity. The experiments were performed with variation of initial temperature and cooling surface temperature. The temperature drop of oil was faster than that of water and freezing was initiated from the interface of oil and water and propagated downward. For the water above $4^{\circ}C$, the cooling rate was faster than that below $4^{\circ}C$ and showed almost same temperature distribution but for the water that of below $4^{\circ}C$, it showed the stable stratified temperature distribution. The lower the initial temperature and the higher the cooling surface temperature was, the longer the supercooling duration.

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SIMULATION OF WATER-OIL-AIR FLOWS AROUND OIL BOOMS UNDER RELATIVE MOTION (상대운동을 하는 방제판 주위 물-기름-공기 유동 모사)

  • Shin, Sangmook
    • Journal of computational fluids engineering
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    • v.21 no.3
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    • pp.31-38
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    • 2016
  • The FDS-HCIB method is expanded to simulate water-oil-air flows around oil booms under relative motion, which is intended to increase the thickness of contained oil. The FDS scheme captures discontinuity in the density field and abrupt change of the tangential velocity across an interface without smearing. The HCIB method handles relative motions of thin oil booms with ease. To validate the developed FDS-HCIB code for water-oil-air flow around a moving body, the computed results are compared with the reported experimental results on the shape, length, and thickness of the oil slicks under towing. It is observed that the increase in pressure field between two barriers lifts the oil slick and the interfacial wave propagates and reflects as one barrier gets closer to the other barrier.

Containment Failures of Oil Restricted by Vertical Plates in Current (유벽에 갇힌 기름층의 조류중 손실에 관한 연구)

  • Song Museok;Hyun Beom-Soo;Suh Jung-Chun
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.1 no.2
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    • pp.40-51
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    • 1998
  • The interaction of contained oil slicks with current was investigated with a two-dimensional experimental setup in the circulating water channel facility. A vertical plate was used to contain the oils against the currents and the evolution of the oil slick, mainly focusing on the water/oil interface, was examined with an aid of a laser sheet. Two different oils - soy bean oil and diesel oil - were studied with varying the current speed (10 cm/sec to 35 cm/sec), the barrier depth (4 cm and 8 cm) and the volume of oil (2 liter to 12 liter). Different types of the interface behavior were observed according to the conditions and their mechanism was discussed based basically on the dimensional analysis. The critical speeds of two types of oil loss mechanism (entrainment failure and drainage failure) were also examined.

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A Statistical Termodynamic Study of Phase Equilibria in Microemulsions

  • Kyung-Sup Yoo;Hyungsuk Park
    • Bulletin of the Korean Chemical Society
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    • v.12 no.3
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    • pp.334-342
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    • 1991
  • To investigate the phase equilibria and structural properties of microemulsions, we study a simple phenomenological model on the basis of the cubic lattice cell with which the oil- and water-filled cells are connected one another, respectively. The surfactant is assumed to be insoluble in both oil and water, and to be adsorbed at the oil-water interface. The Schulman condition, according to which the lateral pressure of the surfactant layer is compensated by the oil-water interfacial tension, is found to hold to good approximation in the middle-phase microemulsion. Our results show that the oil- and water-filled domains in that microemulsion are about 50-150 $\AA$ across, and depend sensitively on the curvature parameters. The phase diagram is not symmetric in this model. It may be asymmetrized intrinsically by non-equivalency of oil and water. The two- and tree-phase equilibria including critical points and critical endpoints are found.

Improvement of Structure to Prevent Water Infiltration and oil leakage for Reduction Units of KTX (KTX 감속구동장치 수분유입 및 누유 방지를 위한 구조개선)

  • Lee, Min-Soo;Kim, Yong-Kee
    • Proceedings of the KSR Conference
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    • 2007.05a
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    • pp.20-25
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    • 2007
  • KTX is being operated on Kyung-Pu High Speed Railroad Line and Ho-Nam Railroad Line from April 2004. Reduction units is occurring water infiltration at heavy snow and oil leakage because of labyrinth structure. This paper describes design method and evaluation technology to improve structure to prevent water infiltration and oil leakage for reduction units of KTX. This reduction units need high power and high speed to run and they have to make optimal lubricant without change current interface.

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