• Title/Summary/Keyword: Oil-in-water emulsion

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Preparation and Properties of W/O Emulsion by D Phase Emulsification (D상 유화물을 이용한 W/O 유화물의 제조와 특성)

  • Kim, H.J.;Jeong, N.H.;Yun, Y.K.;Park, K.S.;Nam, K.D.
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.2
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    • pp.25-32
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    • 1998
  • The emulsion stability of W/O emulsion prepared by D phase emulsification during storage and handling is studied by using phase diagrams. The process of D phase emulsification begins with the formation of isotropic surfactant solution, followed by formation of oil-in-surfactant (O/D) gel emulsion by dispersion of octamethylcyclotetrasiloxane(OMCS) in the surfactant solution. Polyols were essential components for this purpose. To understand the function of polyols, the solution behavior of nonionic surfactant/oil/water/polyol systems were investigated by the ternary phase diagrams of polyoxyethylene oleyl ether/OMCS/propylene glycol(PG) aqueous solutions. The addition of PG increased the solubility of oil in the isotropic surfactant phase. D phase emulsification method has been applied to a new type of cosmetics. By using this emulsification technique, O/W emulsion were formed without a need for adjust of HLB. Fine and stable W/O emulsions were prepared by D phase emulsion.

The Exhaust Gas Reduction of Diesel Engine by MDO (Marine Diesel Oil) Emulsion Fuel (MDO (Marine Diesel Oil) 에멀젼 연료에 의한 디젤엔진의 배출가스 저감)

  • Kim, Moon-Chan
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.7
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    • pp.476-482
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    • 2014
  • In this study, the characteristics of emulsified fuel and engine emissions were studied with engine dynamometer. Microexplosion took place in the combustion chamber. While combustion, emulsion fuel scattered to micro particles and it caused to smoke reduction. The heat produced from water vapour reduce the temperature of internal combustion chamber and it caused to inhibition of NOx production. It can be verified by the lower exhaust temperature of each ND-13 mode using emulsion fuel than that of MDO fuel. The NOx and smoke concentration were reduced by increasing water content in emulsion fuel. The power also decreased according to the increment of water content of emulsion fuel because emulsion fuel has low calorific value due to high water content than MDO. As a result of ND-13 mode test with 17% moisture content, it was achieved 24% reduction in NOx production, 76% reduction in smoke density, 11% reduction of $SO_2$ and 13% reduction in power loss.

Effects of Beef Fat Replacement with Gelled Emulsion Prepared with Olive Oil on Quality Parameters of Chicken Patties

  • Meltem, Serdaroglu;Berker, Nacak;Merve, Karabiylkoglu
    • Food Science of Animal Resources
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    • v.37 no.3
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    • pp.376-384
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    • 2017
  • The objective of this study was to investigate the effect of using gelled emulsion (olive oil 46%, inulin 9%, gelatin 3%) as fat replacer on some quality parameters of chicken patties. For this purpose GE, prepared with olive oil, gelatin and inulin was replaced with beef fat at a level of 0%, 25%, 50%, 100% (C, G25, G50, G100). In this study syneresis, thermal stability, centrifuge and creaming stability of gelled emulsion were analyzed. Chemical composition, technological paramerers (cooking yield, water holding capacity, diameter reduction, fat and moisture retention) and textural and sensory properites were evaluated in comparision to control patties. High thermal stability was recorded in GE (93%), also creaming stability results showed that GE protected its stability without any turbidity and separation of the layer. The complete replacement of beef fat with GE showed detrimental effect on all investigated cooking characteristics except fat retention. Replacement of beef fat with GE at a level of 50% resulted similar cooking characteristics with C samples. Color parameters of samples were affected by GE addition, higher CIE $b^*$ values observed with respect to GE concentration. The presence of GE significantly affected textural behaviors of samples (p<0.05). Our results showed that GE prepared with inulin and olive oil is a viable fat replacer for the manufacture of chicken patty.

Highly Efficient Production of Monodisperse Poly(ethylene glycol) (PEG) Hydrogel Microparticles by Utilizing Double Emulsion Drops with a Sacrificial Thin Oil Shell (얇은 오일쉘 이중에멀젼을 이용한 고효율 단분산성 하이드로젤 마이크로 입자 생산)

  • Kim, Byeong-Jin;Jeong, Hye-Seon;Choi, Chang-Hyung
    • Korean Chemical Engineering Research
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    • v.60 no.1
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    • pp.139-144
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    • 2022
  • This study reports a microfluidic approach to produce monodisperse hydrogel microparticles in a simple and highly efficient manner. Specifically, we produce double emulsion drops with a thin oil shell surrounding an aqueous prepolymer solution, which is solidified via UV-induced free radical polymerization. When they are dispersed in an aqueous solution, the oil shell is dewetted due to the absence of surfactants, resulting in production of highly uniform hydrogel microparticles (C.V.=1%). Results show that production of monodisperse hydrogel microparticles with controllable size and composition can be achieved with minimal use of oil unlike water-in-oil (w/o) single emulsion-based approach. Furthermore, in-depth study of flow patterns in microfluidic device using a phase diagram exhibits a crucial relationship among relative flow rates while providing windows of readily controllable parameters for reliable manufacturing of hydrogel microparticles.

Rheological Behaviour of Water-in-Oil Emulsions using Quaternium-18 Hectorite (쿼터늄-18 헥토라이트를 사용한 Water-in-Oil 에멀젼의 유변학적 거동)

  • Cho, Wan-Goo;Kim, Byung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.4
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    • pp.407-414
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    • 2009
  • Water-in-Oil (W/O) emulsions are widely used in cosmetics. However, O/W (Oil-in-Water) emulsions are generally superior to W/O emulsions in terms of stability. In this study, we investigated the changes of viscosity, the size of emulsion droplets, and rheological properties of emulsions prepared using distearyldimonium chloride (DDC), magnesium aluminum silicate (MAS) and quaternium-18 hectorite (QH). In addition to the changes of the composition, we tested the condition of homogenization including rotation per minute of the mixer and the mixing time. The viscosity of emulsions with DDC and AMS were not changed with time and the stability of emulsions was stable during the storage time. However, the fluidity of emulsions were low due to the forming gel network in the emulsions. The gelling power of the emulsions with QH was rather weaker than that of the emulsions with DDC and MAS. The viscosity of emulsions with QH was gradually reduced and the phase separation of emulsions with high concentration of oil was observed throughout the storage time, however, the stability of emulsions with DDC, MAS and QH was excellent, the fluidity of emulsions was enhanced, and the viscosity of emulsions was sustained for a long time after setting of emulsions.

Production of Water/n-decane Emulsion Fuel and Evaluation of Rheological Stability (물/n-데칸 에멀젼 연료의 제조 및 유변학적 안정성 평가)

  • Kim, Hye Min
    • Journal of Aerospace System Engineering
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    • v.11 no.4
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    • pp.8-14
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    • 2017
  • In this study, the production of proper emulsion fuel and the evaluation of its rheological stability in various experimental conditions were carried out. The W/O (water-in-oil) emulsion fuel was made using n-decane, pure water, and Span 80 was used as a surfactant. Increments of water volume ratio and fuel temperature were the factors, which boosted the phase separation of the emulsion fuel. Rheological characteristics for different water/oil volume ratio, temperature, and elapsed time after the fuel production were examined. As the water volume ratio in the fuel increased, the behavior of non-Newtonian fluid was observed. Viscosity declined as the fuel temperature increased due to the cohesion of water droplets in the fuel. The effect of elapsed time on viscosity was not severe for lower water ratio. However, gradual decrease of viscosity 3 hours after fuel production, in the case of ratio of 3:7, was clearly observed.

Preparation of Porous SiC by Freeze Drying of Polycarbosilane Emulsion (폴리카보실란 에멀젼의 동결건조를 이용한 다공체 SiC 제조)

  • Hwang, Yeon
    • Korean Journal of Materials Research
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    • v.26 no.6
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    • pp.320-324
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    • 2016
  • Porous SiC beads were prepared by freeze-drying a polycarbosilane (PCS) emulsion. The water-in-oil (w/o) emulsion, which was composed of water, PCS dissolved p-xylene, and sodium xylenesulfonate (SXS) as an emulsifier, was frozen by dropping it onto a liquid $N_2$ bath; this process resulted in 1~2 mm sized beads. Beads were cured at $200^{\circ}C$ for 1 h in air and heat-treated at $800^{\circ}C$ and $1400^{\circ}C$ for 1 h in an Ar gas flow. Two types of pores, lamella-shaped and spherical pores, were observed. Lamellar-shaped pores were found to develop during the freezing of the xylene solvent. Water droplets in the w/o emulsion were changed into spherical pores under freeze-drying. At $1400^{\circ}C$ of heat-treatment, porous SiC was synthesized with a low level of impurities.

3D-Printed Microhydrocyclone for Oil/Water Separation (유수분리를 위한 3D 프린팅 기술 기반의 마이크로하이드로사이클론)

  • Kim, Joowan;Kim, Won Jin;Park, Seung;Park, Cherry;Yoo, Jung Heum;Ji, Inseo;Kang, Jeon-Woong;Kim, Taeyung;Hong, Jiwoo
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.289-294
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    • 2022
  • Oil contained in domestic and industrial wastewater or marine spilled oil gives rise to severe environmental pollution issues such as water pollution and ecosystem destruction. The membrane filtration method as one of representative oil/water separation strategies has technological challenges such as membrane fouling and low separation rate. In this work, we devise a 3D-printed microhydrocyclone for oil/water separation by utilizing a digital lighting processing-based 3D printer. We demonstrate that the 3D-printed microhydrocyclone can effectively separate oil and water phases from oil-in-water emulsion.

Improving the Microbial Safety of Fresh-Cut Endive with a Combined Treatment of Cinnamon Leaf Oil Emulsion Containing Cationic Surfactants and Ultrasound

  • Park, Jun-Beom;Kang, Ji-Hoon;Song, Kyung Bin
    • Journal of Microbiology and Biotechnology
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    • v.28 no.4
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    • pp.503-509
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    • 2018
  • Endive is widely consumed in a fresh-cut form owing to its rich nutritional content. However, fresh-cut vegetables are susceptible to contamination by pathogenic bacteria. This study investigated the antibacterial activities of the combined treatment of cinnamon leaf oil emulsion containing cetylpyridinium chloride or benzalkonium chloride (CLC and CLB, respectively) as a cationic surfactant and ultrasound (US) against Listeria monocytogenes and Escherichia coli O157:H7 on endive. The combined treatment of CLC or CLB with US reduced the population of L. monocytogenes by 1.58 and 1.47 log colony forming units (CFU)/g, respectively, and that of E. coli O157:H7 by 1.60 and 1.46 log CFU/g, respectively, as compared with water washing treatment. The reduction levels of both pathogens were higher than those observed with 0.2 mg/ml sodium hypochlorite. In addition, the combined treatment showed no effect on the quality of the fresh-cut endive (FCE). In particular, the degree of browning in FCE was less for the treatment group than for the control and water washing treatment groups. Thus, cationic surfactant-based cinnamon leaf oil emulsions combined with US may be an effective washing treatment for the microbial safety of FCE.