• Title/Summary/Keyword: Oil mixtures

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A study on the reaction rate and the antioxidant effects of caramelization reaction mixtures (Caramelization 온도별 반응속도와 반응 생성물의 유지에 대한 항산화효과에 관한 연구)

  • 최인덕;안명수
    • Korean journal of food and cookery science
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    • v.11 no.4
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    • pp.396-400
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    • 1995
  • The antioxidant effects in soybean oil was investigated by browning reaction mixtures formed by sugar and reaction temperatures above 110$^{\circ}C$. 0.1 M solution of xylose, glucose and sucrose were heated at 110, 120, 130, 140 and 150$^{\circ}C$ for 24 hrs respectively. A reaction rate constant(k), activation energy (Ea) and Q$\sub$10/ value were determined by color intensity that was measured absorbance at 490 nm in each temperature. Soybean oil containing the ethanol extracts taken from the browning reaction mixtures that were heated at 110, 130 and 150$^{\circ}C$ was stored in an incubator kept at 45.0${\pm}$1.0$^{\circ}C$ for 24 days. The results are as follows: 1. When 0.1 M solution of xylose, glucose and sucrose were heated at 110$^{\circ}C$ and 120$^{\circ}C$, the intensity of glucose browning mixtures was the highest, but heated at 150$^{\circ}C$, the color intensity increased in order of xylose > glucose > sucrose after 24 hrs. 2. The reaction rate constant (k) was increased rapidly above 140$^{\circ}C$ and appeared maximum at 150$^{\circ}C$, esp. xylose was the highest. The activation onergy (Ea) of xylose was the highest as 93.28 Joule/mole and the Q$\sub$10/ value of xylose was appeared 1.28. Q$\sub$10/ value was also the highest in xylose. 3. The browning reaction mixtures that were heated at 110$^{\circ}C$ appeared little antioxidant effects. But, in heated at 130$^{\circ}C$ and 150$^{\circ}C$, the antioxidant effects appeared in sucrose browning reaction mixtures. Therefore, in browning reaction mixtures that heated above 110$^{\circ}C$, only sucrose browning reaction mixtures appeared antioxidant effects and xylose, glucose appeared little antioxidant effects. On the contrary xylose and glucose increased peroxide values of soybean oil.

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A Study on the Oil Record Book Guide Line for the PSC Inspection (선박의 항만국검사대비 기름기록관리에 관한 실무적용 연구)

  • Kwon, K.S.
    • Journal of Korea Ship Safrty Technology Authority
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    • s.31
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    • pp.81-96
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    • 2011
  • The transportation of oil has increased due to the growth of marine industries and oil refineries. Oil residues and waste discharged to the ocean has increased due to accidental and/or intentional discharges. The International Marine Organization(IMO) has made compulsory that every oil tanker of 150 gross tonnage and above and every ship of 400 gross tonnages other than tankers and above should be provided with an oil record book. The entries in the oil record book should be made in accordance with the IMO guidelines. Specifically, engine room generated oil residues should be recorded in the oil record book from January 1, 2011. Also, the developed IMO guideline should be added for the prevention of dispute with the Port State Control Officers and(or) Tanker Vetting Inspectors. This oil record book will be in operation and of valued assistance to the marine officers, according to the IMO policy for the prevention of the waste oil and the oil mixtures from the machinery space. For the convenience, added Code & Item No. list, FAQs and reviewed and revised Examples.

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Vapor Pressure and Miscibility for R474A/POE Oil Mixtures (R-404A/POE 오일 혼합물의 증기압과 혼화성)

  • 이정훈;박영무
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.4
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    • pp.285-292
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    • 2002
  • The vapor pressure and miscibility measurement apparatus was developed and used to obtain data for refrigerant/oil mixture. The vapor pressure and miscibility data for R-404A/32 ISO VG polyol ester (POE) oil mixture and R-404A/46 ISO VG polyol ester oil mixture are obtained over the temperature range from -20 to $60^{\circ}$ with at $10^{\circ}$ intervals and the oil concentration range from 0 to 70 wt%. Using the experimental data, an empirical model was developed to predict the temperature vapor pressure-concentration relations for R-404A/46 ISO VG polyol ester oil mixtures at equilibrium. In the R-404A/32 ISO VG polyol ester oil mixture, the average root-mean-square deviation between measured data and calculated results from the empirical model is 1.24% and in the R-404A/46 ISO VG polyol ester oil mixture, that is 1.37%. Miscibility for R-404A/32 ISO VG polyol ester oil mixture was observed all over the experimental conditions. Immiscibility for R-404A/So1est 46 oil mixture was observed at the low oil concentrations (20~30 wt%) over the high experimental temperature range (50~$60^{\circ}$).

Study on the Biodegradability of Dispersants and Dispersant/Bunker-C Oil Mixtures and the Dissolved Oxygen Consumption in the Seawater(II) - The Biodegradability of Dispersant/Bunker-C Oil Mixtures and the Dissolved Oxygen Consumption in the Seawater - (해수중에서 유처리제 및 유처리제/Bunker-C유 혼합물의 생분해도와 용존산소소비에 관한 연구(II) - 유처리제/Bunker-C유 혼합물의 생분해도와 용존산소소비 -)

  • KIM Gwang-Su;PARK Chung-Kil;KIM Jong-Gu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.26 no.6
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    • pp.519-528
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    • 1993
  • The biodegradation experiment, the TOD analysis and the element analysis for dispersant, Bunker-C and dispersant/Bunker-C oil mixtures were conducted for the purposes of evaluating the biodegradability of dispersnat/Bunker-C oil mixtures and studying the consumption of dissolved oxygen with relation to biodegradation in the seawater. The results of biodegradation experiment showed the mixtures with $1:10{\sim}5:10$ mix ratios of dispersant to 4mg/l of Bunker-C oil to be $0.34{\sim}2.06mg/l$ of $BOD_5$ and to be $1.05{\sim}5.47mg/l$ of $BOD_{20}$ in natural seawater. The results of TOD analysis showed 1mg of Bunker-C oil to be 3.16mg of TOD. The results of element analysis showed the contents of carbon and hydrogen to be $87.3\%\;and\;11.5\%$ for Bunker-C oil, respectively, but nitrogen element was not detected in Bunker-C oil. The biodegradability of dispersant/Bunker-C oil mixture shown as the ratio of $BOD_5$/TOD was increased from $3\%\;to\;11\%$ as a mix ratio of dispersant to 4mg/l of Bunker-C oil changed from 1:10 to 5:10, and the mixtures were found to belong in the organic matter group of low-biodegradability. The deoxygenation rates($K_1$) and ultimate oxygen demands($L_o$) obtained through the biodegration experiment and Thomas slope method were found to be $0.072{\sim}0.097/day$ and $1.113{\sim}6.746mg/l$ for the mixtures with $1:10{\sim}5:10$ mix ratios of dispersant to 4mg/l of Bunker-C oil, respectively. The ultimate oxygen demand of mixture was increased as a mix ratio of dispersant to Bunker-C oil changed from 1:10 to 10:5. This means that the more dispersants are applied to the sea for Bunker-C oil cleanup, the more decreases the dissolved oxygen level in the seawater.

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Study for Whitening Activity of Mixture of Arbutin and Oil Soluble Licorice Extract (알부틴과 유용성감초 추출물 혼합물에 의한 미백활성 연구)

  • Jang, Hye In
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.2
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    • pp.635-644
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    • 2019
  • The aim of this study was to investigate whitening effect of combination between arbutine and oil soluble licorice extract. Inhibitory effects of arbutin and oil soluble licorice extract against tyrosinase activity and melanogenesis in B16 melanoma cells were assessed in vitro to determine whitening effect. MTT assay with B16 melanoma cells showed that mixture (arbutin and oil soluble) was not each concentration. Both oil soluble licorice extract and arbutin induced dose-dependent inhibition of mushroom tyrosinase activity. Various concentrations (oil soluble extract : arbutin = 1:1. 1:1.5, 1:2, 1:2.5, 1:5) of mixtures also significantly inhibited tyrosinase activity in B16 melanoma cells by 40-51%. In addition, the mixtures reduced the melanin contents of B16 melanoma cells by more than 50% at each concentration. These results suggest that mixtures of arbutin and oil soluble licorice extract are very effective whitening ingredients.

Experimental Study on Combustion of Boiler Fuel Made of Light-Oil and Bio-Oil (경유와 바이오오일 혼합연료의 연소에 대한 실험연구)

  • Yang, JeBok;Lee, InGu;Hwang, KyungRan
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.201-204
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    • 2012
  • Combustion characteristics of boiler fuels made of bio-oil and light-oil were experimentally investigated. Bio-oil was obtained by fast pyrolysis of woody biomass. Emulsion fuel made by mixing bio-oil (up to 30wt%) with light-oil and surfactant was completely burnt, resulting in the formation of combusted gas containing CO concentration less than 10ppm. Simple mixtures of bio-oil and light-oil with separate delivery lines also gave nice combustion characteristics.

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Gas cooling heat transfer coefficient for $CO_2$-PEC9 mixture under supercritical condition (초임계조건에서 $CO_2$-PEC9 혼합물의 물성예측을 통한 냉각 열전달특성 연구)

  • Yun, Rin
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.821-826
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    • 2009
  • Due to environmental concerns $CO_2$ has been reintroduced as a potential candidate to replace HFCs in refrigeration systems. Oils are always required in a vapor-compression cycle, and thus actual working fluid in the system is $CO_2$-oil mixtures even though the oil concentrations are low at the heat exchangers and the expansion device. The cooling heat transfer coefficients for $CO_2$-oil mixtures under supercritical condition are required to designing of the gas cooler in the $CO_2$ refrigeration system properly. In the present study, the gas cooling heat transfer coefficients for $CO_2$-PEC9 was estimated by using the Gnileinski correlation, and the Kim and Ghajar model through the previous prediction models for the thermo-physical properties of $CO_2$-oil mixture. The Gnileinski correlation was used when the oil wt.% in the mixture is less than 1.0, and for the higher oil concentration the Kim and Ghajar model was applied. The estimated results agree with the experimental results conducted by the Dang et al.

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The Surface Activities of Surfactant Mixtures (혼합 개면활성제의 개면활성에 관한 연구)

  • 정혜원
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.3
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    • pp.348-354
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    • 1994
  • The changes of surface activities in the aquaous solutions of mixed surfactants composed of linear sodium dodecylbenznesulfoate (LAS), polyoxyethylene nonyl phenylether (PE, EO=10) and polyethylene glycol monolauryl ether (LE, EO=25) have been studied. Addition of nonionic surfactants to LAS reduces the surface tension, especially at the lower concentration than cmc. The interfacial tension of olive oil/LAS was lower than the other surfactant solutions. The removal of triolein from cotton fabrics by nonionic surfactants and mixtures is higher than by LAS. The addition of NaCI to surfactant solutions even though reduces surface tension smaller but enthances oil removal more than that of $CaCl_2$.

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The Biodegradation Characteristics of the Mixtures of Bunker-A, B Oils with Dispersants in the Seawater

  • BAEK Joong-Soo;KIM Gwang-Su;CHO Eun-il
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.29 no.6
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    • pp.787-796
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    • 1996
  • The biodegradation experiment, the TOD analysis and the element analysis for dispersant, Bunker-A oil and Bunker-B oil were conducted to study the biodegradation characteristics of a mixture of Bunker-A oil with dispersant and a mixture of Bunker-B oil with dispersant in the seawater. The results of biodegradation experiment showed 1mg of dispersant to be equivalent to 0.26 mg of $BOD_5$ and to 0.60 mg of $BOD_{20}$ in the natural seawater. The results of TOD analysis showed each 1 mg of dispersant, Bunker-A oil and Bunker-B oil to be equivalent to 2.37 mg, 2.94 mg and 2.74 mg of TOD, respectively. The results of element analysis showed carbon, hydrogen, nitrogen and phosphorus contents of dispersant to be $82.1\%,\;13.8\%,\;1.8\%\;and\;2.2\%$, respectively. Carbon and hydrogen contents of Bunker-A oil were found to be $73.3\%\;and\;13.5\%$, respectively, and carbon, hydrogen and nitrogen contents of Bunker-B oil to be $80.4\%,\;12.3\%\;and\;0.7\%$, respectively. Accordingly, the detection of nitrogen and phosphorus in dispersant shows that dispersants should be used with caution in coastal waters, with relation to eutrophication. The biodegradability of dispersant expressed as the ratio of $BOD_5/TOD$ was found to be $11.0\%$. As the mix ratios of dispersant to Bunker-A oil (3 mg/l) and a mixture of Bunker-B oil (3mg/l) were changed from 1 : 10 to 5 : 10, the biodegradabilities of a mixture of Bunker-A oil with dispersant and Bunker-B oil with dispersant increased from $2.1\%\;to\;7.2\%$ and from $1.0\%\;to\;4.4\%$, respectively. Accordingly, the dispersant belongs to the organic matter group of middle-biodegradability while mixtures in the mix ratio range of $1:10\~5:10$ belong to the organic matter group of low-biodegradability. The deoxygenation rate constant $(K_1)$ and ultimate biochemical oxygen demand $(L_0)$ obtained from the biodegradation experiment and Thomas slope method were found to be 0.125/day and 2.487 mg/l for dispersant (4 mg/l), respectively. $K_1\;and\;L_0$, were found to be $0.079\~0.131/day$ and $0.318\~2.052\;mg/l$ for a mixture of Bunker-A oil with dispersant and to be $0.106\~0.371/day$ and $0.262\~1.106\;mg/l$ for a mixture of Bunker-B oil with dispersant, respectively, having $1:10\~5:10$ mix ratios of dispersant to Bunker-A oil and Bunker-B oil. The ultimate biochemical oxygen demands of the mixtures increased as the mix ratio of dispersant to Bunker-A, B oils changed from 1 : 10 to 5 : 10. This suggests that the more dispersants are applied to the sea for the cleanup of Bunker-A oil or Bunker-B oil, the more decreases the dissolved oxygen level in the seawater.

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A study on the development of oil skimming ship for large quantity of oil pollution (대형 오염방제 선박의 개발에 관한 연구)

  • 권기생
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.2 no.1
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    • pp.57-65
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    • 1996
  • The latest date, No. 1 YouII was grounded and sunk into the sea at MAMHYUNGJEDO ( South brother Island) in Sep. 21. 1995, and M.V. Sea Prince of V.L.C.C also made a big oil poullution accident owing to Typhoon "Paei" at front sea of Yeu Choun on Jul. 25. 1995. The large or small scall scale of oil poullution accident frequently was occurred about 300-350 cases per ine(1) year. The countries advanced in marine relations like as, nited Kingdom and Japan, have perfect system The country of expert education, training and oil recovery equipments in oil poullution accidents. The large quantity oil skimming ship's basic condition need general skimming ship which was high speed and large quantity skimming ability , and hve to store the recovered oil into tanks This oil skimming shop are composit the skimmer whuch move up and down according to the wace movements, storage tank which storage the recovered oil in after side, transfer pump which transformed from flooding tank to separating tank and separating tank which separated the oil mixtures, Also there are cylindrical floated which keep the auto positing, gate which keep the auto positing, gate which protect and guide the recovering oil from sea and balance weight for skimmer balance. Also there are cylindrical floated which keep the auto positing, gate which protect and guide the recovering oil from sea and balance weight for skimmer balance. The important arrangement is twin arm which moved by two hinge and move te skimming unit by wave movement. In gate of inside, made long wear in the gate bellow position, there are also connected the flexible hose for oil mixtures drop. The separating tank composited with multi-divided bulkhead for ffective oil and sea water separating by settling and flotation principle. As use the above natural princile and equipment, we can remove the large quantity oil by developed oil skimming ship.ming ship.

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