• 한국식품저장유통학회지
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• 제30권1호
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• pp.122-131
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• 2023

초음파와 대두유 용매를 병용하여 감 껍질 유래 카로티노이드 함유 대두유를 제조하고 그의 이화학적 특성을 파악하기 위하여, Box-Behnken design과 반응표면분석법을 이용하여 추출물의 카로티노이드 농도 기준 최적 추출조건(온도 62℃, 시간 32 min, 대두유/감 껍질 비율 3.1)을 결정하였고, 이 조건에서 얻은 추출물(카로티노이드 강화 대두유)과 무처리 대두유(control)의 이화학적 특성을 비교하였다. 추출물의 총카로티노이드 함량은 강화되었고, 이러한 카로티노이드 강화 대두유의 색도는 대조구보다 명도는 낮았지만 높은 적색도와 황색도값을 보였다. 대두유의 산화 및 가열 안정성에 대한 초음파 처리와 감 껍질 유래 카로티노이드의 영향은 미미한 것으로 나타났다. 카로티노이드 강화 대두유의 점도와 활성화 에너지는 대조구보다 약간 높았다. 이로써 감 껍질에 초음파-대두유 용매 추출법을 적용하여 황적색의 카로티노이드 강화 대두유의 제조가 가능하였고, 이는 일반 유지 대체제는 물론 첨가물로서도 활용성이 높을 것으로 기대된다.

• 한국식품영양과학회지
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• 제41권12호
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• pp.1747-1752
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• 2012

본 연구는 문관나무 종자유로부터 새로운 유지자원으로의 활용 가능성을 평가하기 위하여 여러 가지 이화학적 특성분석을 하였다. 문관나무 종자유를 초임계 추출(420 atm, $50^{\circ}C$), 헥산 추출, 가열압착($160^{\circ}C$, $180^{\circ}C$) 방법으로 추출하였다. 그 결과 추출 수율은 헥산 추출이 $53.5{\pm}2.5%$로 가장 높았으며, 다음으로 $160^{\circ}C$ 가열압착 추출이 $48.3{\pm}6.5%$, $180^{\circ}C$ 가열압착 추출과 초임계 추출은 각각 $44.7{\pm}1.7%$, $44.7{\pm}2.5%$의 수율을 보였다. 산가를 측정한 결과, 초임계 추출 종자유가 3.44 mg/g으로 가장 높았으며 가열압착 추출 종자유가 1.3 mg/g 정도로 가장 낮았다. 문관과 종자유의 과산화물가를 측정한 결과, 가열압착 추출 종자유($160^{\circ}C$)가 3.10 meq/kg으로 가장 높았으며 다음으로 가열압착 추출 종자유($180^{\circ}C$)가 2.36 meq/kg, 헥산 추출 종자유와 초임계 추출종자유가 각각 1.59, 1.13 meq/kg 순으로 나타났다. 문관나무의 종자유로부터 지방산 조성을 분석한 결과 oleic acid(C18:1)와 linoleic acid(C18:2)가 60% 이상 함유되어 있었다. 또한 문관나무 종자유의 총 phytosterol 실험 결과 가열압착 추출 종자유($160^{\circ}C$)의 함량이 $65.91{\pm}0.62$ mg/100 g으로 가장 높았다. 본 연구는 문관나무 종자유의 추출방법별 이화학적 특성 분석을 통해 문관나무 종자유 활용에 대한 기초자료로 활용될 수 있을 것으로 판단된다.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2003년도 International Symposium on Clean Environment
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• pp.119-122
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• 2003

Quantitation methods of total petroleum hydrocarbons to determinate oil contaminated level in soil were discussed. Extraction characteristics of several pretreatment methods and practical detection limit and reappearances in gas chromatography/mass spectrometry. with each pretreatment method were investigated. The obtained results showed that the newly adopted quantitation method and mechanical shaking extraction method using methanol with extraction solvent are more practical and applicable to real sample than the conventional methods. In applying these methods to gasoline, kerosene, fuel oil which are major source of soil contamination, the practical quantitation limit and % relative standard deviation was able to determine with range of 2.5 - 10 ppm, 5 - 7 ％.

• Environmental Engineering Research
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• 제24권2호
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• pp.202-210
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• 2019

In order to maximize the utilization of sewage sludge, a waste from wastewater treatment facility, the residual sewage sludge generated after lipid and carbohydrate extraction for biodiesel and bioethanol production was used to produce bio-oil by pyrolysis. Thermogravimetric analysis showed that sludge pyrolysis mainly occurred between 200 and $550^{\circ}C$ (with peaks formed around 337.0 and $379.3^{\circ}C$) with the decomposition of the main components (carbohydrate, lipid, and protein). Bio-oil was produced using a micro-tubing reactor, and its yield (wt%, g-bio-oil/g-residual sewage sludge) increased with an increase in the reaction temperature and time. The maximum bio-oil yield of 33.3% was obtained after pyrolysis at $390^{\circ}C$ for 5 min, where the largest amount of energy was introduced into the reactor to break the bonds of organic compounds in the sludge. The main components of bio-oil were found to be trans-2-pentenoic acid and 2-methyl-2-pentenoic acid with the highest selectivity of 28.4% and 12.3%, respectively. The kinetic rate constants indicated that the predominant reaction pathway was sewage sludge to bio-oil ($0.1054min^{-1}$), and subsequently to gas ($0.0541min^{-1}$), rather than the direct conversion of sewage sludge to gas ($0.0318min^{-1}$).

• 한국식품과학회지
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• 제23권6호
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• pp.673-676
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• 1991

Aqueous process를 이용하여 전지 대두분에서 대두유와 대두단백을 동시에 추출하였다. 효소 처리나 초음파 처리를 하지 않은 aqueous extraction의 경우 최적 추출조건은 pH8, 6배의 희석률 $40^{\circ}C$, 120-150 mesh의 크기로 나타났으며 62%의 유지와 62%의 단백질이 추출되었다. 효소처리를 하였을 경우에는 유지는 최고 86%, 단백질은 최고 89%가 추출되었고, 초음파 처리를 하였을 경우에는 유지와 단백질은 모누 90%가 추출되었다. Aqueous extraction으로 얻어진 대두유는 hexane으로 추출한 대두유보다는 Lovibond의 붉은색과 노랑색이 약간 짙었으나 Folch 용매로 추출한 것 보다는 두 가지 색도가 모두 배우 약했다.

• Journal of Biosystems Engineering
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• 제41권3호
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• pp.177-183
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• 2016

Purpose: Mee (Madhuca longifolia) is an economically important tree growing throughout Sri Lanka. Its importance is mainly attributed to its oil with high nutritional and medicinal values. However, an inefficient extraction method limits its use. This study revealed the possibility of extracting oil from mee seeds by using a screw-type oil expeller. Methods: A popular screw-type oil expeller was used in the experiment. Extract bar clearance and speeds of the main spiral shaft were altered to increase the oil expelling efficiency of the machine. The quality of refined oil at the optimum oil yield was determined by measuring the refractive index, saponification value, iodine value, unsaponifiable matter, free fatty acid, and specific gravity. Results: An optimum yield of 35% oil was obtained when the machine capacity was 30 kg/h and energy consumption was 0.13 kWh/kg. This optimum machine condition was observed at an extract bar clearance of 0.5 mm and a main spiral shaft speed of 90 rpm. The refractive index, saponification value, iodine value, unsaponifiable matter, free fatty acid, and specific gravity of the oil were 1.4, 203, 59, 3.5%, 0.2%, and 0.907 g/cm3 respectively. Color of the mee oil was closer to yellow, which is revealed by the lightness value (L) of 24.93 and positive value (b) of 11.81. Conclusion: The screw-type oil expeller can be used for economically extracting mee oil on a commercial scale.

• 한국식생활문화학회지
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• 제25권6호
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• pp.788-794
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• 2010

Camellia sinensis L. (green tea) seed oils were prepared by roasting at $213^{\circ}C$ and pressing (RP), pressing (P), and nhexane extraction (H). The physico-chemical properties of the RP, P, and H samples, including fatty acid composition, color, and sensory characteristics were analyzed. RP, P and H samples were thermally oxidized at $180^{\circ}C$, and oxidative stability was determined by DPPH, CDA, and p-AV at 0, 20, 40, 60, and 80 min. Compared to the P and H samples, RP resulted in significantly higher thermal oxidative stability according to the DPPH, CDA, and p-AV results (p<0.05). The ratio of unsaturated fatty acids to saturated fatty acids among RP, P, and H samples were significantly different (p<0.05). The oleic acid and linoleic acid contents in green tea seed oils were 58 and 23%, respectively. Hunter's color value of lightness (L) for the RP, P, and H samples was not significant. Redness (a) of RP was $3.47{\pm}0.119$ and yellowness (b) of H was $60.10{\pm}2.483$, which were significantly different. Compared to RP samples, H and P samples had the highest color and off-odor values in the sensory evaluation. RP samples showed the highest taste value and were significant overall (p<0.05). The thermal stability of RP extraction was more stable than any other method. Camellia sinensis L. seed oil extracted by RP had better sensory characteristics than other edible oils, including soybean oil, grape seed oil, and extra virgin olive oil.

• Applied Biological Chemistry
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• 제37권1호
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• pp.37-42
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• 1994

청호(Artemisia apiaceae Herba)를 simultanuous distillation 및 steam distillation으로 추출하여 정유의 관능적 특성을 조사하고, GC 및 GC-MS로 분석하여 34개 성분을 확인하였다. 정유의 관능적 특성은 camphorous하면서 herbal하였고, 정유의 steam distillation에 의한 수율은 0.23%, simultanuous distillation extraction에 의한 수율은 0.37%이었다. 확인된 34개 성분 중에서 camphene, camphor, borneol and caryophv-llene 등이 많이 함유되어 있었다. 또 정유를 11개로 분획한 후 좋은 향기 특성을 갖고 있는 5개의 분획물만을 성분 분석하였으며 특히 분획물 F-5와 F-6은 기능성 약리효능을 얻을 수 있는 의료용 향료로 개발가능성을 보였다.

• Journal of Applied Biological Chemistry
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• 제42권4호
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• pp.175-179
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• 1999

Grape seed oil was extracted using different preparatory treatments as follows: (1) grinding, (2) grinding and roasting, (3) grinding and wet- roasting, (4) grinding, roasting, and wet-roasting, and (5) grinding, wet-roasting, and wet-roasting. The highest antioxidant activity was obtained from the sample with the method (2). Initial states of oxidation were similar except method (1) that showed more oxidized state, being P.O.V.8. Acid values were observed in the range from 1.42 to 1.89. The lowest acid value was found as 1.42 in method (1) and those of others were somewhat higher, indicating that heating process of roasting produced some free fatty acids. From the results of sensory evaluation, the best odor and taste were obtained from the methods (2) and (3). Repetitive procedure of wet-roasting, like method 5, caused some loss of flavor components and decrease in the sensory evaluation score. Addition of grape seed oil (method 2) to soybean and perilla oil at the level of 20% retained considerable antioxidant activities as much as 4.3 and 5 times, respectively, than 100% soybean or perilla oil stored for 12 weeks. When soybean or perilla oil was mixed with 20% grape seed oils, P.O.V. decreased to half of that of unmixed oils.

• 한국식품저장유통학회지
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• 제11권1호
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• pp.42-46
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• 2004

치자로부터 청색 및 황색색소, 고량으로부터 암갈색 색소를 주정을 이용하여 추출ㆍ농축하여 60$^{\circ}$Brix 농도의 추출물을 회수하였는데, 각각의 수율은 0.68, 1.97, 0.63% (w/w)였다. 이들을 대두유: 물: 유화제: 치자청: 치자황: 고량색소=8: 22: 42: 10: 15: 13 (w/w)의 비율로 혼합하고 균질화하여 유용성 천연 검정색소를 얻었다. 이 색소를 대두유에 용해시킨 결과 대두유의 품온이 30∼4$0^{\circ}C$ 범위에서 가장 높은 용해도를 나타내었다. 대두유에 한 번 용해된 색소물질은 혼합 대두유의 품온을 2$0^{\circ}C$ 이하로 유지하여도 재분리현상이 발생하지 않는 것으로 확인되었다