• Title/Summary/Keyword: Oil/water separation

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Emulsifying Properties of Concentrated Red Ginseng Extract: Influence of Concentration, pH, NaCl (홍삼농축액 함유 유화액의 유화특성에 관한연구)

  • You, Kawn-Mo;Jang, Hyeon-Ho;Lee, Eui-Seok;Lee, Ki-Teak;Hong, Soon-Taek
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.504-514
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    • 2017
  • This study was carried out to investigate the emulsifying properties of concentrated red ginseng extract (CRGE). First, we determined the interfacial tension of CRGE at the oil-water interface. Second, oil-in-water emulsions were prepared with CRGE and then their physicochemical properties such as fat globule size, zeta-potential, dispersion stability, and microscopic characteristics were determined. It was found that interfacial tension gradually decreased with increasing CRGE concentration, indicative of some surface activity. In emulsions, fat globule size was decreased as CRGE concentration increased, showing a critical value ($d_{43}$$0.39{\mu}m$) at ${\geq}3.5wt%$ of CRGE. In addition, pH and NaCl also influenced on fat globule sizes; they were increased in acidic conditions ($pH{\leq}3$) or in higher NaCl concentration (${\geq}0.4M$) and these results were interpreted in view of the change in zeta potentials. The dispersion stability by separation analyzer ($LUMiFuge^{(R)}$) showed that it was more stable in emulsions with higher CRGE concentration (i.e., ${\geq}3.5wt%$). In conclusion, CRGE was surface-active and it could be used as an emulsifier in preparation of food emulsions.

A Study for Polyol-in-Oil Type Lip Makeup Cosmetics with Natural Pigments (천연색소를 함유하는 유중폴리올(Polyol-in-Oil) 립메이크업 제품에 관한 연구)

  • Lee, Dong Won;Kim, Young Ho;Jung, Eun Ji;Lee, Sang Gil;Pyo, Hyeong Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.39 no.1
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    • pp.65-73
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    • 2013
  • Lip make-up products can be easily taken into body with food. For this reason, those products are requires to meet lots of qualifications compared with other cosmetic products. In addition, concerns about safety on synthesized tar pigments is constantly issued. Thus, demand of natural pigments is gradually increased and many kinds of natural pigments have been developed. However, there are some problems when natural pigments are applied to cometic products instead of synthetic ones. There is a reason that most of natural pigments consist of hydrophilic materials of sort of anthocyanin, but the existing lip make-up products is anhydrous oil dispersion type without water consisting oil and wax. Therefore, when watersoluble natural pigments are applied to anhydrous lip make-up products, color expression is lower and phase separation occurs due to the instability of the product. In addition, natural pigments have disadvantages that they can easily change by pH, heat and sunlight. There are troubles of stability because it is not easy to adjust for these factors in case of anhydrous forms. Aim of study is to develop lip make-up products which have not only safe to human but being high in expression of color by using natural pigments and securing stability of colorant as natural pigments are offered to polyol in oil emulsion. Then, lip make-up products which have heavy moisture while having not dryness that is created when the moisture evaporates are developed.

Treatment of Contaminated Groundwater Containing Petroleum and Suspended Solids Using DAF and Mixed Coagulation Processes (DAF와 혼화응집공정을 이용한 현탁성 고형물 함유 유류 오염 지하수 처리)

  • Lee, Chaeyoung;Jang, Yeongsu
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.8
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    • pp.25-32
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    • 2010
  • Contamination of soil and groundwater by the compounds of hydrocarbon petroleum has been widely accepted as the main cause that harms the environments and health. To remove those pollutants, absorbing clothes, activated carbons, or oil-water separation devices with the gravity method are employed for treatment. However, those materials and devices cannot remove the emulsion pollutants despite of their efficiency for removing free products. Therefore, we investigated the problems which occur during the groundwater treatment for the highly concentrated suspended solid particles, which can be resulted from excavation, and to propose methods to remove TPH(Total Petroleum Hydrocarbon). After coagulation experiment with high molecular polymers, the concentration of SS(Suspended Solids) and COD(Chemical Oxygen Demand) turned to satisfy the groundwater quality criteria within 5 minutes while the concentration of TPH failed to meet the water quality standard of effluent. Consequently, the water quality criteria for effluent could not be met by single DAF(Dissolved Air Flotation) process. However all water quality criteria could be satisfied after 20 minutes when coagulation reactions are carried out simultaneously in the DAF reactor.

Preparation of Storage-Stable Liquid Dyes by Membrane Separation Technology (막분리 기술을 위한 액체염료 제조에 관한 연구)

  • Cho, Jung Hee;Lee, Chung Hak
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.349-359
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    • 1992
  • Studies were carried out on the selective removal of inorganic salts such as NaCl and $Na_2SO_4$ from dye solution, using counter diffusion-reverse osmosis and nanofiltration, respectivey. For the dye solution used in the experiments, 1 to 30% of salts were removed by counter diffusion while the loss of dye molecules was less than 0.3%. The separation factors by one pass operation were 10-500 according to ionic species. In five successive operations, removals of anion($Cl^-$) increased but those of cation($Na^+$) decreased due to the Donnan effect. Effects of feed flow rate on removal efficiencies of various ions were also observed at constant flow rate of stripping water. Reverse osmosis of desalted dye solution by counter diffusion was conducted to prepare highly concentrated liquid dyes. The rejection efficiency of dye molecules was greater than 99%. For the rejection efficiency of chloride ion, experimental values were compared with theoretical ones based on solution-diffusion model. Two stage diafiltration was performed in nanofiltration. The rejection efficiency of chloride ion was continuously decreased due to the Donnan dialysis and even negative rejection was observed. The Donnan effect was more pronounced in the second diafiltration.

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The Manufacturing Characteristics of Magnesium Chloride Emulsion by Different Rotational Speed of Homomixer as Soybean Curd Coagulant (두부응고제로서 Homomixer 회전속도를 달리한 염화마그네슘유화물의 제조특성)

  • Hong, Seung-Seok;Park, Won-Jong;Joung, Kyung-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.3
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    • pp.1252-1257
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    • 2013
  • This study was used homomixer as one of the manufacturing method to establish optimal manufacturing condition with magnesium chloride emulsion as coagulant. The more rotational speed of homomixer was fast, the more particle size of magnesium chloride emulsion was minute. The particle size was distributed between 1 and $5{\mu}m$. The more minute particle size of emulsion had an effect on increasing viscosity of emulsion and delay of oil phase separation during storage period, so the quality of magnesium chloride emulsion had correlation with dispersed phase particle size. After all the experiments, when manufacturing magnesium chloride emulsion, it used more than 10,000 rpm of rotational speed of homomixer, it showed the best result as coagulant according to the state of texture and the water separation ratio of soybean curd.

Effect of PVP on the Physical Stability of O/W Emulsion (O/W 유제의 물리적 안정성에 대한 PVP의 영향)

  • Oh, In-Joon;Lee, Mi-Young;Lee, Jeong-Min;Lee, Yong-Bok;Shin, Sang-Chul;Choi, Bo-Guil;Kim, Chong-Kook
    • Journal of Pharmaceutical Investigation
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    • v.27 no.4
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    • pp.287-293
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    • 1997
  • To make a stable o/w emulsion, the effects of egg lecithin as an emulsifier and polyvinylpyrrolidone (PVP) as an auxiliary emulsifier on the physical stability of emulsion were investigated. The oil-in-water emulsion system was manufactured by microfluidizer and evaluated the physical stability. Average particle size and size distribution of emulsion was measured by dynamic light scattering analyzer and interfacial tension was measured. From the interfacial tension tested, critical micelle concentration of the egg lecithin was 0.1 %w/v and optimal concentration for the preparation of emulsion was 1.0 %w/v. The mean particle size was about $0.2\;{\mu}m$ which was suitable for injections. The short-term accelerated stability studies were conducted by centrifugation, freeze-thaw method and shaking of the emulsion samples. The addition of PVP was caused the reduction in the particle size and improved the physical stability of emulsion. These results suggested that a mixed interfacial film comprising the egg lecithin and PVP was formed at the o/w interface and it was effective in preventing phase separation under thermic or mechanical stress. We used antineoplaston A10 (A10) as a model drug which is peptide and amino acid derivative having a action to the living organism against the development of neoplastic growth by a nonimmunological progress. It has a poor solubility in water and there may be a difficulty in formulation of A10. Emulsion formulation study about A10 was performed. Solubility of A10 in emulsion was about five times as high as that in water. From the results of solubility and partition coefficient, almost A10 molecules in o/w emulsion exist in the interface between oil and water.

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Selective Enrichment of EPA end DHA by Adduct Formation of Folly Acids of Fish Oil and Urea (어유 지방산과 요소의 부가화합물 형성을 이용한 EPA와 DHA의 선택적 농축방법)

  • Han, Dae-Seok;Ahn, Byung-Hak;Shin, Hyun-Kyung
    • Korean Journal of Food Science and Technology
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    • v.22 no.5
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    • pp.520-525
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    • 1990
  • A modified method of urea adduct formation, in which water and organic solvent were used as the wetting agent and the reaction medium. respectively, is suggested to obviate methanolysis and to ease recovery in the separation of eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA) from fish oil. With the new method the fraction in which the total content of EPA. DHA and their precursors is more than 80% could be obtained. Although the total content of precursors in the concentrate was hardly affected by the kind of the wetting agent or the organic solvent, the content of EPA and DHA varied significantly depending on the organic solvent. This finding made it possible to selectively enrich the desired components. After DHA-enriched fraction (I)HA is 50%) was obtained by using pentane, EPA-enriched fraction ( EPA is 53%)) could be obtained from the residue of DHA-enriched fraction by using heptane.

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A Study for Analytical Method of Sudan Colorants in Foods (식품 중 수단색소의 분석법에 관한 연구)

  • 김희연;윤혜정;최장덕;최우정;박선영;이경주;김지혜
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.3
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    • pp.549-552
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    • 2004
  • A simple, efficient and accurate method was developed for the simultaneous determination of non-permitted oil soluble colorants (sudan I, II, III and IV) in foods. The identification has been carried out for sudan colorants by TLC as well as HPLC with photodiode array (PDA) detection. Separation of sudan colorants was achieved within 20 min by a gradient elution with water and acetonitrile as eluents. Sudan colorants showed good linear relationships in the range of 0.1 ~ 100 $\mu\textrm{g}$/mL. The correlation coefficients of the calibration curve for sudan colorants exceeded 0.999. The detection limits (signal-to-noise ratio 3 : 1) for sudan I, II, III and IV were 0.01, 0.01, 0.02 and 0.02 $\mu\textrm{g}$/mL, respectively. This method has been successfully applied to the analysis of red pepper powder, Kimchi and Kakdugi, and the average recoveries for real samples ranged from 83.02% to 104.3%.

Studies on the Composition of Green and Roast Coffee bean (커피생두(生豆)(Green Coffee)와 볶은 커피두(豆)(Roast Coffee)의 성분(成分)에 관(關)한 연구(硏究))

  • Choi, Min-Kang;Lee, Yong-Ock;Ko, Young-Su
    • Journal of Nutrition and Health
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    • v.11 no.1
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    • pp.9-16
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    • 1978
  • A Comparison of the analysis of the green and roast coffee of Arabica and Robusta compositions and regular instant coffee has been investigated by chromatography. The coffee oil were obtained by extracting the green and roast coffee with ethyl ether by soxhlet methood. Instant coffee samples were accurately weighted into 100ml beaker (ca. 0.5g regular coffee and 1.5g decaffeinated coffee) and add ca. 50ml water, heat and boil, remove from heat, and mechanically stried ca. 15min. and filtered of one sample and another sample were without filtrated and proceed with liquid chromatographic separation. The fatty acid compositions of green and roast coffee were compared by gas liquid chromatography and general chemical compositions of sample were analysed. Some similarities between green and roast coffee fatty acids were found in the case of green and roast coffee of both kinds acid methyl esters. They contained stearic, oleic, linoleic, and unknown fatty acid, and palmitic ana linoleic acid were rich.

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SURFACE DEFORMATION MONITORING USING TERRASAR-X INTERFEROMETRY

  • Kim, Sang-Wan;Wdowinski, Shimon;Dixon, Tim
    • Proceedings of the KSRS Conference
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    • 2008.10a
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    • pp.422-425
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    • 2008
  • TerraSAR-X is new radar satellite operated at X-band, multi polarization, and multi beam mode. Compared with C-band or L-band SAR, the X-band system inherently suffers from more temporal decorrelation, but is more sensitive to surface deformation monitoring due to short wavelength (3.1 cm) and high spatial resolution (1m-3m). It is generally expected that sensitivity to estimate surface movement using TerraSAR-X will be increased by the factor of 10, compared to current C-band system with low spatial resolution such as ERS-2, Envisat. Many urban areas are experiencing land subsidence due to water, oil and natural gas withdrawal, underground excavation, sediment compaction, and so on. Monitoring of surface deformation is valuable for effectively limiting damage areas. In addition high accuracy and spatially dense subsidence map can be achieved by X-band InSAR observation, promoting identification and separation of various subsidence processes and leading to enhanced understanding via mechanical modeling. In this study we will introduce some initial InSAR results using new TerraSAR-X SAR data for surface deformation monitoring.

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