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Spectroscopic Studies of TP6F PI Switched by Hole-Injection

  • Lee, Gyeong-Jae;Im, Gyu-Uk;Kim, Dong-Min;Lee, Mun-Ho;Gang, Tae-Hui;Jeong, Seok-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.297-298
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    • 2011
  • Metal/poly (4,4'-aminotriphen-ylene hexafluoroisopropylidenediphthalimide) (TP6F PI)/metal structure exhibited an electrically volatile phase transition with high (OFF) or low (ON) resistive states when voltage between electrodes swept. Here, we demonstrate a noble set-up in which holes are injected by photoelectron emission process during the voltage sweep instead of direct charge carrier injection via metal electrode, which enables direct investigation into changed electronic structures of TP6F PI both in ON and OFF states using photoemission spectroscopy methods. In the I-V measurement, TP6F PI shows a non-volatile behavior. In spectroscopic results, this non-volatile behavior is leaded from the structural modification of the O=C double bond in phthalimide of TP6F PI by hole injection.

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A Study on the Real Time Expert System for Power System Fault Diagnosis (전력계통의 실시간 고장진단을 위한 전문가 시스템에 관한 연구)

  • Park, Young-Moon;Chung, Jae-Gil;Kim, Gwang-Won
    • Proceedings of the KIEE Conference
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    • 1997.07c
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    • pp.927-929
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    • 1997
  • In this paper, a new expert system scheme, called Logic Based Expert System (LBES), is proposed for real time fault diagnosis of power system. In LBES, Expertise is represented by logical connectives and converted into a Boolean function. The set of Prime Implicants (PIs) of the Boolean function contains all the sound inference results which can be obtained from the expertise. Therefore, off-line inference is possible by off-line PI identification, which reduces the on-line inference time considerably and makes it possible to utilize-the LBES in real-time environment.

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Numerical Analysis on the Development of Shut off Damper for a Tsunami at a Nuclear Plant (원자력 발전소의 해일 차단용 댐퍼 개발을 위한 수치해석)

  • Park, Joo-Young;Yi, Chung-Seob;Chin, Do-Hun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.23 no.5
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    • pp.471-477
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    • 2014
  • The purpose of this study was to predict the load effect on a damper installed at a nuclear power plant building after a tsunami using a volume of fluid (VOF) numerical analysis method. The wave height was determined by a sine wave function and the tsunami condition was estimated by the wave length. Also, using computational fluid dynamics (CFD), the maximum damper load was set as a boundary condition for the structural analysis that verified how stress and deformation affect the damper. As a result, such simulations estimated the highest stress distribution for a wave length of 350 m with a maximum stress present at the cross point of stiffness installed at the rear end of the damper. The total deformation was approximately 32 mm at the center of damper.

High Resolution Linear Graphs : Graphical Aids for Designing Off-Line Process Control)

  • Lee, Sang-Heon
    • Journal of the military operations research society of Korea
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    • v.27 no.1
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    • pp.73-88
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    • 2001
  • Designing high quality products and processes at a low cost is central technological and economic challenge to the engineer. The combination of engineering concepts and statistical implementations offered by Taguchi\`s off-line design technique has proven t be invaluable. By examining some deficiencies in designs from the Taguchi\`s highly fractional, orthogonal main effect plan based on orthogonal arrays, alternative method is proposed. The maximum resolution or the minimum aberration criterion is commonly used for selecting 2$^{n-m}$ fractional designs. We present new high resolution (low aberration) linear graphs to simplify the complexity of selecting designs with desirable statistical properties. The new linear graphs approach shows a substantial improvement over Taguchi\`s linear graphs and other related graphical methods for planning experiment. The new set of linear graphs will allow the experimenter to maintain the simple approach suggested by Taguchi while obtaining the best statistical properties of the resulting design such as minimum aberration as a by-product without dependency on complicated computational algorithm or additional statistical training.g.

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Kinetics analysis of energetic material using isothermal DSC (등온 DSC를 이용한 고에너지 물질의 정밀 반응 모델 기법 개발)

  • Kim, Yoocheon;Park, Jungsu;Kwon, Kuktae;Yoh, Jai-ick
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.219-222
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    • 2015
  • The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The frequency factor and activation energy are extracted as a function of product mass fraction. The extracted kinetic scheme does not assume multiple chemical steps to describe the response of energetic materials; instead, multiple set of Arrhenius factors are used in describing a single global step. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.

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Charge Transfer Mechanism of Electrically Bistable Switching Devices based on Polyimide

  • Lee, Gyeong-Jae;Im, Gyu-Uk;Kim, Dong-Min;Lee, Mun-Ho;Gang, Tae-Hui;Jeong, Seok-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.374-374
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    • 2010
  • Charge transfer mechanism of poly(4,4'-aminotriphenylene hexafluoroisopropylidenediphthalimide) (TP6F PI) which exhibits bistable ON and OFF switching has been studied using photoemission electron spectroscopy (PES) and near-edge x-ray absorption fine structure (NEXAFS). Here, we demonstrate novel set-up in which holes are injected by photoemission process instead of direct charge carrier injection via metal electrode. The accumulated charges on the PI surface in the OFF state abruptly flow across the PI film when the bias voltage of a back electrode reaches a specific value, indicating that the film is changed to the ON state. Core level and x-ray absorption spectra probed at charge injection region via photoemission process do not show any evidences implying structural modification of TP6F PI during the phase change. Whereas, in valence band spectra, the highest occupied molecular orbital (HOMO) is shifted toward Fermi level, responsible for improved hole-mobility of TP6F PI of ON state.

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Mix Design of High Performance Concrete Using Maximum Density Theory (최대 밀도 이론을 이용한 고성능콘크리트의 배합 설계)

  • Lee, Seung-Han;Jung, Yong-Wook
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.377-383
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    • 2007
  • In recent years the field application of high performance concrete has been increased to improve the quality and reliability of concrete structures. The mix design of the high performance concrete includes the 2 set-off mixture theory of mortar and coarse aggregate and that of paste and aggregate. The 2 set-off mixture theory of mortar and coarse aggregate has a problem of having to determine its value through repeated experiments in applying the rheological characteristics of mortar. The 2 set-off mixture theory of paste and aggregate has never been applied to high performance concrete since it doesn't take into account the relationship between optimum fine aggregate ratio and unit volume of powder nor does it consider the critical aggregate volume ratio. As the mixture theory of these high performance concretes, unlike that of general concrete, focuses on flowability and charge-ability, it does not consider intensity features in mix design also, the unit quantity of the materials used is determined by trial and error method in the same way as general concrete. This study is designed to reduce the frequency of trial and error by accurately calculating the optimum fine aggregate ratio, which makes it possible to minimize the aperture of aggregate in use by introducing the maximum density theory to the mix design of high performance concrete. Also, it is intended to propose a simple and reasonable mix design for high performance concrete meeting the requirements for both intensity and flowability. The mix design proposed in this study may reduce trial and error and conveniently produce high performance concrete which has self-chargeability by using more than the minimum unit volume of powder and optimum fine aggregate with minimum porosity.

Composition and Catch Variation of Fishes by a Set Net in the Coastal Waters off Gwideuk, Jeju Island (제주도 귀덕 연안 정치망 어획물의 조성 및 변동)

  • Cha, Byung Yul;Kim, Dae Kwon;Yoon, Jang Taek;Kim, Byung Yeob
    • Korean Journal of Ichthyology
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    • v.20 no.1
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    • pp.28-35
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    • 2008
  • Fishes by a set net in the coastal waters off Gwideuk, Jeju Island were studied to determine species composition and catch variation, 2004. The fishing period conducted by a set net in Gwideuk fishing ground were from April to December. A total of 45,473.2 kg including 21 species was caught during the survey period. Most of them consisted of fishes of 17 species and a few were cephalopods of 4 species. Dominant species were Trachurus japonicus and Siganus fuscescens, 44.3% in the total. And sub-dominant species were Sepioteuthis lessoniana, Seriola dumerili, Seriola quinqueradiata, Loligo bleekeri, Seriola lalandi accounting for 54.4%. Although the number of species had a tendency to decreased from July to December, the catch by a set net was higher in summer and autumn than in spring. Such catch variations were closely related to recruitment of dominant species and also the seasonal variation of fishing ground temperature.

Oceanographic Condition and Fishing Condition of the Set Net Fishing Ground in Yeosu Bay (여수연해 정치망어장의 해황과 어황에 관한 연구)

  • Kim, Dong-Soo;Lee, Cho-Chool;Park, Yong-Seak
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.24 no.4
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    • pp.150-157
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    • 1988
  • The oceanographic condition around the set net fishing ground in Yeosu Bay was investigated by the oceanographic observation in June, July and August, 1988. Also the catch of the set net was analized by daly catch data of the three set net fishing ground from April to September, 1988. The results obtained are as follows: 1) The coastal surface water is high temperature and low salinity through the influence of land, and the off shore water and bottom water are low temperature and high salinity. 2) The eddy current and the sharp thermocline in June appeared in August at the set net fishing ground, and a good catch appeared in June and August. 3) The surface temperature and salinity at the set net fishing ground are 11$^{\circ}C$ to 27$^{\circ}C$ and 31.60$\textperthousand$ to 34.80$\textperthousand$. The surface temperature and salinity of a maximum good catch are 21$^{\circ}C$ and 33.80$\textperthousand$ to 33.99$\textperthousand$ respectively. 4) The dominant species of fish were spanish mackerel, scad, anchovy, sardine, common mackerel, hairtail, crab, yellow tail, in order of catch.

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Study on Improving Energy-Efficiency of Set-top Box (셋톱박스의 에너지 효율 개선에 관한 연구)

  • Lee, Sang-Hak;Yun, Jung-Mee
    • The KIPS Transactions:PartD
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    • v.18D no.3
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    • pp.197-204
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    • 2011
  • Set-top Box which receives broadcasting signal and delivers it to display device such as TV usually doesn't have low-power mode, standby power mode. On the other side, most consumer electronics support standby power mode. The main reasons come from technical barriers and operational stability. Set-top box normally consumes 80~90% power of active mode even though turning off. This is much higher compared to other consumer electronics which consume less than 1W in standby power mode. However, most developed countries including Korea are enforcing the regulations which enhance energy efficiency of set-top box. This paper describes design and development of low-power set-top box. Key technologies are SoC supporting low-power mode, system hardware and software operating in separated power mode, and middleware managing the power with broadcasting system. Finally, we show energy saving expectation through development and proliferation.