• Geotechnical Engineering
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• v.4 no.3
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• pp.35-42
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• 1988

A series of consolidated-undrained cubical triaxial tests was performed to investigate the three- dimensional strength characteristics of anisotropic overconsolidated clay. All specimens sampled in field were loaded under conditions of principal stress directions fixed and aligned with the directions during sampling. A sufficient number of tests It was performed to deter.mine the three- dimensional failure surface in the octahedral plane. The adjusted effective friction angles obtained by the stress state projected on the same octahedral plane did not show anisotropy, while the measured effective friction angles showed considerally difference according to the axes of speccimens. Therefore, Lade failure criterion proposed fort isotropic materials could be also used practically for anisotropic overconsolidated clay. The direction of the plastic strain increment wrectors superimposed on the principal stress space was nearly perpendicular to the traces of the failure surface in the octahedral plane.

• Magazine of the Korean Society of Agricultural Engineers
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• v.38 no.6
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• pp.64-73
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• 1996

The three-dimensional strength behavior of compacted decomposed granite soil was studied using cubical triaxial tests with independent control of the three principal stresses. All specimens were loaded under conditions of principal stress direction fixed and aligned with the directions of compacted plane. For comparable test conditions, the major principal strain and volume strain to failure were smallest when the major principal stress acted perpendicular to the compacted plane. The opposite extremes were obtained when the major principal stress acted parallel to the compacted plane. In cubical triaxial tests with same b values and with ${\theta}$ values in one of three sectors of the octahedral plane, independent of the range of ${\theta}$, higher friction angles are obtained in tests with b greater than in triaxial compression tests in which b 0.0, Comparison between the results of the drained cubical triaxial tests on lksan compacted decomposed granite soil and the cross section of the Mohr-Coulomb failure surface as well as the cross section of the Mohr-Coulomb failure surface were made. Lade's isotropic failure criterion based on vertical specimens overestimates the strengths for tests performed with values of 0 between 90˚ and 1 50˚ the Mohr-Coulomb criterion generally underestimates the strengths of tests performed with values of ${\theta}$ between $0^{\circ}$ and $180^{\circ}$ except around the $120^{\circ}$.

• Journal of the Korean Geosynthetics Society
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• v.9 no.3
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• pp.19-27
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• 2010

In this study, a series of triaxial tests to Jeju basalt were carried out and then shear strength parameters of rock were estimated by the Lade's three-dimensional failure criterion. Also, the characteristics of shear strength parameters and failure plane which were estimated by the three-dimensional failure criterion were analyzed and this failure criterion was compared with the Mohr-Coulomb failure criterion. The variables of ${\eta}_1$ and m are derived from the relationship between ($I_1^3/I_3-27$) and ($P_a/I_1$) during the failure period using the Lade's three-dimensional failure criterion. The failure plane size of Tracy-basalt has the largest plane and that of Scoria has the smallest plane among other octahedral planes which is the three-dimensional failure plane. Also, the failure plane of Tracy-basalt is formed as a triangle and that of Scoria is formed as a circle among other octahedral planes. As the result of comparison with the triaxial test results and the Lade's failure envelope and the Mohr-Coulomb failure envelope, the Lade's failure envelope matched up under higher stress, while the Mohr-Coulomb failure envelope matched up under lower stress. Also, the Lade's three-dimensional failure plane is larger than the Mohr-Coulomb three-dimensional failure plane. It means that the shear strength parameters estimated by the Lade's failure criterion is larger than that of the Mohr-Coulomb failure criterion.

• Journal of the Mineralogical Society of Korea
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• v.28 no.2
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• pp.127-133
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• 2015

Li-bearing muscovite is commonly found along with trioctahedral lepidolite in granitic pegmatites. Structurally, $Li^+$ ions can replace $K^+$ ions in the interlayer (Int) of muscovite or incorporate into vacancies of the dioctahedral sheet (Sub). However, detailed mechanism of the lithium incorporation into muscovite is challenging to investigate using experimental techniques alone. In the current study, density functional theory (DFT) has been applied to examine the crystal structure and energy variation when $Li^+$ resides in the interlayer or the octahedral sheet. Depending on the position of $Li^+$ (i.e., Int vs. Sub), DFT showed significant differences in the mica's structures such as lattice parameters, sheet thickness, interlayer separation, and OH angles with respect to the ab plane. DFT further showed that, in pure muscovite, $Li^+$ has a lower energy when it is located in Int than Sub. By contrast, in the case of $Fe^{2+}$ substitution into the octahedral sheet, $Li^+$ has a lower energy in Sub than in Int. These results imply that $Li^+$ incorporates into the Al octahedral sheets only when the octahedral sheets possess structural charges, suggesting cation substitution in the octahedral sheets plays an important role in the Li incorporation mechanism into muscovite. They can also explain the experimental observation about the positive relationship between $Fe^{2+}$ and $Li^+$ amounts in Li-bearing muscovite.

• Geotechnical Engineering
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• v.10 no.3
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• pp.111-118
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• 1994

A series of drained cubical triaxial tests was performed to investigate the finfluence of the intermediate principal stress on the deformation and strength characteristics of sand. Test results showed that the strength of sand as represented by the friction angle increased from triaxial compression condition (b:0) with increasing magnitude of the intermediate principal stress until the vus of b reached 0.75, land it decreased slightly with closing to b= 1. Also it was found that the projection of the plastic strain increment vector on the octahedral plane was perpendicular to the trace of the failure surface on that plane. The prediction by the isotropic single hardening model sllowed good coinidence with experimental results.

• Bulletin of the Korean Chemical Society
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• v.18 no.10
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• pp.1050-1052
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• 1997

The complexes M(CO)4-1,2-(PPh2)2-1,2-C2B10H10 (M=Cr 2a, Mo 2b, W 2c) have been prepared in good yields from readily available bis-diphenylphosphino-o-carboranyl ligand, closo-1,2-(PPh2)2-1,2-C2B10H10 (1), by direct reaction with Group Ⅵ metal carbonyls. The infrared spectra of the complexes indicate that there is an octahedral disposition of chelate bis-diphenylphosphino-o-carboranyl ligand around the metal atom. The crystal structure of 2a was determined by X-ray diffraction. Complex 2a crystallizes in the monoclinic space group P21/n with cell parameters a = 12.2360(7), b = 17.156(1), c = 16.2040(6) Å, V = 3354.1(3) Å3, and Z =4. Of the reflections measured a total of 2514 unique reflections with F2 > 3σ(F2) was used during subsequent structure refinement. Refinement converged to R1 = 0.066 and R2 = 0.071. Structural studies showed that the chromium atom had a slightly distorted pseudo-octahedral configuration about the metal center with two phosphine groups of o-carborane occupying the equatorial plane cis-orientation to each other. These metal carbonyl complexes are rapidly converted to the corresponding metal carbene complexes, [(CO)3M=C(OCH3)(CH3)]-1,2-(PPh2)2-1,2-C2B10H10 (M= Cr 3a, Mo 3b, W 3c), via alkylation with methyllithium followed by O-methylation with CF3SO3CH3.

• Korean Journal of Materials Research
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• v.26 no.4
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• pp.167-172
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• 2016

The high temperature deformation behavior of $Ni_3Al$ and $Ni_3(Al,Mo)$ single crystals that were oriented near <112> was investigated at low strain rates in the temperature range above the flow stress peak temperature. Three types of behavior were found under the present experimental conditions. In the relatively high strain rate region, the strain rate dependence of the flow stress is small, and the deformation may be controlled by the dislocation glide mainly on the {001} slip plane in both crystals. At low strain rates, the octahedral glide is still active in $Ni_3Al$ above the peak temperature, but the active slip system in $Ni_3(Al,Mo)$ changes from octahedral glide to cube glide at the peak temperature. These results suggest that the deformation rate controlling mechanism of $Ni_3Al$ is viscous glide of dislocations by the <110>{111} slip, whereas that of $Ni_3(Al,Mo)$ is a recovery process of dislocation climb in the substructures formed by the <110>{001} slip. The results of TEM observation show that the characteristics of dislocation structures are uniform distribution in $Ni_3Al$ and subboundary formation in $Ni_3(Al,Mo)$. Activation energies for deformation in $Ni_3Al$ and $Ni_3(Al,Mo)$ were obtained in the low strain rate region. The values of the activation energy are 360 kJ/mol for $Ni_3Al$ and 300 kJ/mol for $Ni_3(Al,Mo)$.

• Tunnel and Underground Space
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• v.21 no.6
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• pp.526-535
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• 2011

A new failure criterion for concrete, which takes into account the effect of the intermediate principal stress, is proposed. The new criterion, which takes the advantages from both the Mohr-Coulomb and the Willam-Warnke criteria, is linear in the meridian section, while its octahedral section is always smooth and convex. Fitting the triaxial compression data with the proposed criterion shows the high performance of the new criterion. A new formula for the factor of safety of concrete is defined based on the new failure criterion and it is employed in the stability analysis of the concrete plugs installed in the pilot plant. The new formula for the factor of safety measures the degree of closeness of a stress state to the failure surface in the octahedral plane. Finally, 3-D finite element analyses of pilot plant were carried out to obtain the stress distributions in the plugs. Then, the stress distributions are converted to those of factor of safety by use of the proposed formula. Based on the distribution of factor of safety in the concrete plugs, the stability of the tapered and wedge-shaped plugs is evaluated.

• Bulletin of the Korean Chemical Society
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• v.18 no.10
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• pp.1061-1066
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• 1997

The complexes M(CO)4-1,2-(PPh2)2-1,2-C2B10H10 (M=Cr 2a, Mo 2b, W 2c) have been prepared in good yields from readily available bis-diphenylphosphino-o-carboranyl ligand, closo-1,2-(PPh2)2-1,2-C2B10H10 (1), by direct reaction with Group Ⅵ metal carbonyls. The infrared spectra of the complexes indicate that there is an octahedral disposition of chelate bis-diphenylphosphino-o-carboranyl ligand around the metal atom. The crystal structure of 2a was determined by X-ray diffraction. Complex 2a crystallizes in the monoclinic space group P21/n with cell parameters a = 12.2360(7), b = 17.156(1), c = 16.2040(6) Å, V = 3354.1(3) Å3, and Z =4. Of the reflections measured a total of 2514 unique reflections with F2 > 3σ(F2) was used during subsequent structure refinement. Refinement converged to R1 = 0.066 and R2 = 0.071. Structural studies showed that the chromium atom had a slightly distorted pseudo-octahedral configuration about the metal center with two phosphine groups of o-carborane occupying the equatorial plane cis-orientation to each other. These metal carbonyl complexes are rapidly converted to the corresponding metal carbene complexes, [(CO)3M=C(OCH3)(CH3)]-1,2-(PPh2)2-1,2-C2B10H10 (M= Cr 3a, Mo 3b, W 3c), via alkylation with methyllithium followed by O-methylation with CF3SO3CH3.

• Analytical Science and Technology
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• v.21 no.6
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• pp.562-568
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• 2008

A novel two-dimensional cadmium(II)-nickel(II) bimetallic host clathrate, $[Cd{NH_2CH_2CH_2OH}_2Ni(CN)_4]{\cdot}3C_6H_5NH_2{\cdot}H_2O$, 1, has been synthesized and structurally characterized by X-ray single crystallographic method. The clathrate 1 crystallizes in the monoclinic system, space group $P2_1/c$ with a = 14.370(3), b = 7.728(1), c = 28.172(4) ${\AA}$, ${\beta}=97.58(1)^{\circ}$, V = 3101.1(9) ${\AA}^3$, Z = 4. The host framework of the clathrate 1 is built of the cyanide bridges between octahedral Cd(II) atom and square planar Ni(II) atom. The octahedral Cd atoms ligated by two 2-aminoethanol molecules and four cyanide ligands bridged with square planar Ni atoms. The Ni atoms bridges to four Cd atoms via cyanides is made up of puckered quadrangles of composition $\{CdNi(CN)_2\}_2$, all edges are shared. This cyanide bridges form an infinite two-dimensional host networks stacking along b axis. 2-Aminoethanol ligands bond to Cd atom through N atom as a monodentate ligand in the axial position and four cyanides take an equatorial plane with all in trans-configurations. The aniline guest molecules and water molecules are located in between the host layer sheets, respectively.