• Title/Summary/Keyword: OPR

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Atomic Layer Deposition of TiO2 Thin Films from Ti(OiPr)2(dmae)2 and H2O

  • Lee, Jae P.;Park, Mi H.;Chung, Taek-Mo;Kim, Yun-Soo;Sung, Myung M.
    • Bulletin of the Korean Chemical Society
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    • v.25 no.4
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    • pp.475-479
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    • 2004
  • $TiO_2$ thin films were grown on Si (100) substrates by atomic layer deposition using $[Ti(OPr^i )_2(dmae)_2]$ and water as precursors. The thickness, chemical composition, crystalline structure, and morphology of the deposited films were investigated by transmission electron microscopy, UV spectrometry, X-ray photoelectron pectroscopy, X-ray diffraction, and atomic force microscopy. The results show that $TiO_2$ ALD using $[Ti(OPr^i )_2(dmae)_2]$ as a precursor is self-controlled at temperatures of 100-300$^{\circ}C$. At the growth temperatures below 300$^{\circ}C$, the surface morphology of the $TiO_2$ films is smooth and uniform. The $TiO_2$ film was grown with a preferred orientation toward the [101] direction at 400$^{\circ}C$.

Validation of Vibration and Stress Analysis Method for APR1400 Reactor Vessel Internals Comprehensive Vibration Assessment Program (APR1400 원자로내부구조물 종합진동평가프로그램 진동 및 응력해석 방법 검증)

  • Kim, Kyu Hyung;Ko, Do Young;Kim, Sung Hwan
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.23 no.4
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    • pp.308-314
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    • 2013
  • The vibration and stress analysis program of comprehensive vibration assessment program(CVAP) is to theoretically verify the structural integrity of reactor vessel internals(RVI) and to provide the basis for selecting the locations monitored in measurement and inspection programs. This paper covers the applicability of the vibration and stress analysis method of APR1400 RVI CVAP. The analysis method was developed to use 3-dimensional detail hydraulic and structural models with ANSYS and CFX. To assess the method, the hydraulic loads and structural reponses of OPR1000 were predicted and compared with the measured data in the OPR1000 RVI CVAP. The results predicted with this method were close to the measured values considerably. Therefore, the analysis method was developed properly.

An Experimental Study on the Micro Friction and Wear Characteristics of Organically Modified Hybrid Ceramic Materials by A Sol-Gel Process (졸-겔 공정에 의한 유기변성 하이브리드 세라믹 물질의 미세 마찰마모 특성)

  • Han, Hung-Gu;Kong, Ho-Sung;Yoon, Eui-Sung;Yang, Seung-Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.05a
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    • pp.215-225
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    • 2002
  • In order to enhance the thermal stability of binder materials of bonded type solid lubricants, several combinations of metal-alkoxide based sol-gel materials such as methyltrimethoxysilane(MTMOS), $titaniumisopropoxide(Ti(Opr^{j})_{4})$, $zirconiumisopropoxide(Zr(Opr^{j})_{4})$ and $aluminumbutoxide(Al(Obu^{t})_{4})$ were chemically modified by epoxy-, acrylic- and fluoro-silane compounds, respectively, in this work. Friction and wear characteristics of these hybrid ceramic materials were tested with a micro tribe-tester where a reciprocating steel ball slid on a test material, and the tribological property was also evaluated with respect to both heat-curing temperature and tile time. Test results generally showed that hybrid ceramic materials modified by epoxy-silane compounds had a low friction compared to others. And the higher heat-curing temperature and the longer heat treatment time resulted in the higher friction and the lower wear. IR spectroscopic analyses revealed that it was caused mainly by the increased metal oxide content in hybrid ceramics when the heat-curing temperature was over $320^{\circ}C$.

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Friction and Wear Characteristics of Bonded Film Lubricants of Organically Modified Hybrid Ceramic Binder Materials (유기변성 하이브리드 세라믹 물질을 결합제로 이용한 고체피막윤활제의 마찰마모 특성)

  • 한흥구;공호성;윤의성
    • Tribology and Lubricants
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    • v.19 no.4
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    • pp.203-210
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    • 2003
  • In order to enhance the thermal stability of binder materials of bonded type solid lubricants, several metal-alkoxide based sol-gel materials such as methyltrimethoxysilane(MTMOS), titaniumisopropoxide (Ti(Opr$\^$i/)$_4$), zirconiumisopropoxide (Zr(Opr$\^$i/)$_4$) and aluminumbutoxide (Al(Obu$\^$t/)$_4$) were modified chemically by both epoxy and acrylic silane compounds. Friction and wear characteristics of the bonded solid lubricants, whose binders were of several hybrid ceramic materials, were tested with a reciprocating tribo-tester. Wear life was evaluated with respect to the heat-curing temperature, friction temperature, type of supplement lubricants, and ratio of binder materials. Test results showed that the Si-Zr hybrid ceramic materials modified by epoxy-silane compounds had a higher wear life compared to others. Sb$_2$O$_3$ was the most effective supplement lubricants in the high temperature, and BUS analyses revealed that it was caused mainly by a strong anti-oxidation effect to MoS$_2$ particles. The higher heat-curing temperature resulted in the higher wear life, and the higher friction temperature resulted in the lower wear life.

Environmental Fatigue Evaluation of APR1000 Reactor Vessel (APR1000 원자로용기의 환경피로 평가)

  • Kim, Jong Min;Kim, Yong Hwan
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.26 no.3
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    • pp.207-212
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    • 2013
  • APR1000(Advanced Power Reactor 1000) was developed to export 1000MW nuclear power plants by adding ADFs(Advanced Design Features) including 60 years design life, local frequency control operation, 0.3g SSE, etc. to OPR1000(Optimized Power Reactor 1000). In this paper, environmental fatigue analyses for the reactor vessel in APR1000 have been performed as per Reg. Guide 1.207. Outlet nozzle, which has a relatively high cumulative usage factor in the reactor vessel was evaluated and a structural integrity is maintained under the reactor coolant environment.

Analysis of Chemical Cleaning for the Top-of-Tubesheet of NPP's Steam Generator (원전 증기발생기 관판 상단 화학세정 결과 분석)

  • Lee, Han-Chul;Sung, Ki-Bang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.4
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    • pp.2043-2048
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    • 2013
  • OPR-1000 CE Steam Generator, of which tube material is composed of Alloy-600 HTMA in nuclear power plant, secondary side is generated ODSCC(Outside Diameter Stress Corrosion Cracking) due to the accumulated sludge. ODSCC is centered around the tube sheet and is being affected depending on the height of the sludge. Chemical cleaning was carried out for a top-of-the-tube sheet(TTS) of Steam Generator in order to decrease corrosive condition of the secondary side of Steam Generator tubes and suppress the occurrence of stress corrosion cracking. The amount of sludge removal was 259.2kg. The height of the accumulated sludge was reduced from 0.71 to 0.34 inches. Corrosion rate as the maximum 2.34 mils was satisfied to within EPRI (Electric Power Research Institute) recommendation(10 mils).

Micro Friction and Wear Characteristics of Organically Modified Hybrid Ceramic Materials Synthesized by A Sol-Gel Process (졸-겔 공정에 의한 유기변성 하이브리드 세라믹 물질의 미세 마찰마모 특성)

  • Han, Hung-Gu;Kong, Ho-Sung;Yoon, Eui-Sung;Yang, Seung-Ho
    • Tribology and Lubricants
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    • v.18 no.5
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    • pp.324-332
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    • 2002
  • In order to enhance the thermal stability of binder materials of bonded type solid lubricants, several metal-alkoxide based sol-gel materials such as methyltrimethoxysilane(MTMOS), titaniumisopropoxide$(Ti(Opr^i)_4),$ zirconiumisopropoxide $(Zr(Opr^i)_4)$ and aluminumbutoxide$(Al(Obu^t)_4)$ were chemically modified by epoxy-, acrylic- and fluoro-silane compounds, respectively. Friction and wear characteristics of these hybrid ceramic materials were tested with a micro tribo-tester, and evaluated with respect to both heat-curing temperature and the time. Test results generally showed that hybrid ceramic materials modified by epoxy-silane compounds had a low friction compared to others. And the higher het-curing temperature and the longer heat treatment time resulted in the higher friction and the lower wear. IR spectroscopic analyses revealed that these results were caused mainly by the increased metal oxide content in hybrid ceramics when the heat-curing temperature was over $320^{\circ}C.$