• Title/Summary/Keyword: OPC replacement

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Chloride Penetration Analysis of Fly Ash Concrete using Potentiometric Titration and XRF (플라이애시를 혼입한 콘크리트의 전위차 적정법과 XRF를 이용한 염화물 침투 분석 )

  • Eun-A Seo;Ji-Hyun Kim;Ho-Jae Lee
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.5
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    • pp.16-22
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    • 2023
  • In this study, a salt water immersion test was performed on concrete specimens simulating the concrete mix design of the nuclear power plant, and the correlation between the amount of chloride and the XRF component according to the depth of the concrete was analyzed. The amount of chloride on the surface of the nuclear power plant concrete increased slightly with increasing immersion time in salt water, but the amount of chloride in the depth of 5.5 mm or more showed a clear tendency to increase with increasing immersion time in salt water. As a result of analyzing the correlation between the amount of chloride in concrete and the XRF component, the concrete with 20% FA substitution compared with the OPC concrete showed a very high correlation between the composition ratio of Cl ions and the evaluation result of salt damage resistance by XRF component analysis. Accordingly, it was confirmed that chlorine ion analysis and salt damage resistance performance evaluation by XRF component analysis were possible through repeated data accumulation in the nuclear power plant concrete mix with 20% fly ash replacement.

Characteristics of Concrete Using Coal-By-product as Fine Aggregate (석탄 부산물인 경석을 잔골재로 사용한 콘크리트의 특성)

  • In-Hwan Yang;Seung-Tae Jeong;Geun-Woo Park;Gyeong-Min Choi
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.1
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    • pp.53-62
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    • 2024
  • In this paper, an experimental study on the strengths and material properties of concrete manufactured by using coal gangue, as a fine aggregate was conducted. Experimental parameters included coal gangue aggregate contents as a replacement of fine aggregate by 50 % and 100 % (by volume) and fly ash contents. The water-binder ratio was fixed at 0.38. In addition, 30 % of the OPC binder was replaced with fly ash in some mixtures. Test of the unit weight, compressive, split tensile, and flexural tensile strength of concrete were performed and test results were analyzed. Unit weight, compressive strength, split tensile strength, and flexural tensile strength decreased as the coal recycled aggregates increased. In addition, TGA and SEM experiments, which are microstructure experiments, were conducted to analyze thermogravimetric analysis and ITZ by section.

Effect of the Kinds and Replacement Ratios of Mineral Admixtures on the Development of Concrete Resistance against the Penetration of Chloride Ions (혼화재 종류 및 치환율이 콘크리트의 내염성능 향상에 미치는 영향에 관한 연구)

  • Kim Young-Jin;Lee Sang-Soo;Kim Dong-Seuk;Yoo Jae-Kang
    • Journal of the Korea Concrete Institute
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    • v.16 no.3 s.81
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    • pp.319-326
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    • 2004
  • This paper investigates the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete replaced mineral admixtures for 3${\~}$4 replacement ratios under water-binder ratios ranged from 0.40 to 0.55. For the electro-migration test, Tang and Nilsson's method was used to estimate the diffusion coefficient of chloride ion. As a results, the water-binder ratios, kinds of mineral admixtures and replacement ratios, water curing periods had a great effect on the diffusion coefficient of chloride ion, and the optimal replacement ratios had a limitation for each mineral admixtures. Also, the use of mineral admixtures by mass(replacement of OPC) enhance the resistance ability against chloride penetration compared with the plain concrete. The compressive strength was shown related to the diffusion coefficient of chloride ion, the compressive strength increases with the diffusion coefficient of chloride ion decreasing. Below the 50 MPa, the variation of diffusion coefficient of concrete replaced mineral admixtures was bigger than that of plain concrete.

Study on Mechanical Properties of Geopolymer Concrete using Industrial By-Products (산업부산물을 사용한 지오폴리머 콘크리트의 역학적 특성에 관한 연구)

  • Kim, Si-Hwan;Koh, Kyung-Taek;Lee, Jang-Hwa;Ryu, Gum-Sung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.52-59
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    • 2014
  • This study examines the compressive strength, elastic modulus and splitting tensile strength of geopolymer concrete in order to evaluate its mechanical characteristics according to the admixing of fly ash and blast furnace slag. Moreover, identical tests are also conducted considering the amount of powder, the mixing ratio of alkali activator and the mixing ratio of silica fume for further comparative analysis considering various variables. The comparison with the formulae specified in Korean and overseas codes reveal that a mixing ratio of 18% is adequate for the alkali activator and that a replacement ratio of 5% by silica fume is recommended for silica fume. The elastic modulus of the geopolymer concrete appears to increase slightly with the increase of the compressive strength per variable and age and to be smaller than the values predicted by the formulae specified in Korean and overseas codes. In addition, the examination of the stress-strain curves shows that the geopolymer concrete exhibits ductile behavior compared to the conventional OPC. In view of the splitting tensile strength, high strength is observed for a powder content of $400kg/m^3$ and a replacement ratio of 18% by silica fume. The resulting ratio of the compressive strength to the splitting tensile strength is seen to range between 8.7 and 10.2%.

Evaluation of Mechanical Properties of Mortar Mixed with Zeolites and Active Hwangtoh (제올라이트 및 활성 황토를 혼입한 모르타르의 역학적 특성 평가)

  • Kwon, Seung-Jun;Lim, Hee-Seob;Kim, Hyeok-Jung;Hyun, Jung-Hwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.405-412
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    • 2019
  • In this study, the physical and chemical properties of mortar are evaluated by micro-analysis, taking into account the substitution rate(20%, 30%, and 40%) of zeolite with porous properties and active hwangtoh. First, the physical and chemical properties of zeolite and active hwangtoh are reviewed to confirm that the specific surface area of those is similar with ordinary portland cement, and the main chemical composition is SiO2, Al2O3, Fe2O3, etc.. So, it is thought that they have the properties of pozolan reactive materials. As the results of the strength test considering the amount of substitution based on that of cement, It is confirmed that strength decreases with the increase of the replacement amount of zeolite and active hwangtoh, and the strength of mortar with replacement rate of 20% is higher than OPC mortar. It is confirmed that the amount of porosity is increased due to chemical properties of zeolite and active hwangtoh, and in particular, the size of the pore is greater than 1㎛ in mortar mixed with active hwangtoh.

Evaluation on Workability and Compressive Strength Development of Concrete Using Modified Fly-Ash by Vibration Grinding (진동분쇄를 사용한 개질 플라이애시 콘크리트의 유동성 및 압축강도 발현 평가)

  • Ahn, Tae-Ho;Yang, Keun-Hyeok;Jeon, Young-Su
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.66-74
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    • 2021
  • The objective of this study is to evaluate the practical application potential and limitations of the modified fly ash(MFA) by vibration grinding as a partial replacement of ordinary portland cement(OPC). The test parameters investigated were the replacement level of fly ash(FA) and FA for OPC, varying from 10% to 40%, and curing temperatures of 5, 20, and 40℃. The various characteristics(including slump, air content, bleeding, setting time, compressive strength development, and hydration products) of MFA concrete were measured and then compared with those of the concrete with conventional FA. Test resul ts showed that the MFA prefers to FA in reducing the bl eeding of fresh concrete and enhancing the compressive strength gain at an early age. The compressive strength ratios between MFA and FA concrete specimens at an age of 1 day were 135%, 146%, and 111% at the curing temperatures of 5, 20, and 40℃, respectively. The corresponding ratios at an age of 28 days were approximately 110%, regardless of the curing temperatures. The X-ray diffraction analysis also revealed less calcium hydroxide products in MFA pastes than in FA pastes.

A Study on Strength and Chloride Resistance of Concrete Using the Metakaolin (메타카올린 사용에 따른 콘크리트의 강도 및 염화물 저항성)

  • Kim, Myung-Yu;Yang, Eun-Ik;Yang, Joo-Kyoung;Park, Hae-Guun;Chun, Sang-Eun;Lee, Myeong-Sub
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.521-524
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    • 2008
  • The requirement for durability of concrete is increasing recently as a high-rise concrete structure is built. For this reason, the concern about high performance concrete is being high. Recently, metakaoline to be profitable in economical aspect as well as to have strength and durability of level similar to silica fume is evaluated highly as new admixture. In this study, the workability, the strength, the chloride resistance and the air-void structure more than 50${\mu}m$ are evaluated by comparing both metakaolin and silica fume. According to the results, when the metakaoline is compared with silica fume in properties of fresh concrete, it seems to the similar level of properties. Metakaoline concrete showed the highest value in the strength property. And, it is showed that replacement of the metakaoline more than 10% is superior than both silica fume and OPC in long and short-term chloride resistance. In conclusion, replacement of the metakaoline more than 10% is the most excellent performance in terms of strength and chloride resistance

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A Durability Assessment on Complex Deterioration of Concrete with Ground Granulated Blast-Furnace Slag Replacement (복합열화 환경하에서의 고로슬래그미분말 사용 콘크리트의 내구성능 평가)

  • Lee, Seung-Hoon;Kim, Hyung-Doo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.2
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    • pp.171-175
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    • 2010
  • This paper presents the experimental results of frost durability characteristics including freezing-thawing and de-icing salt scaling of the concrete for gutter of the road and marine structure. Mixtures were proportioned with the three level of water-binder ratio(W/B) and three binder compositions corresponding to Type I cement with 0%, 30% and 50% GGBS(Ground granulated blast furnace slag) replacement. Also, two different solutions of calcium chloride were used to evaluate their effect on the frost durability resistance. Specially, in case of complex of freezing and thawing with salt and carbonation, the deterioration of concrete surface is evaluated. Test results showed that the BFS30 and BFS50 mixture exhibited higher durability and lower mass loss values than those made with OPC mix and the use of GGBS can be used effectively in terms of economy and frost durability of the concrete to be in complex deterioration. Therefore, the resistance to complex deterioration with freezing-thawing was strongly influenced by the strength and the type of cement.

Flexural Behavior of Concrete-ECC Composite Beam Reinforced with Steel Rebar (철근 보강된 콘크리트-ECC 복합보의 휨 거동)

  • Hyun, Jung-Hwan;Bang, Jin-Wook;Lee, Bang-Yeon;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.104-111
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    • 2020
  • The purpose of this study is to investigate the flexural behavior and plastic hinge of reinforced concrete-ECC composite beams. Ordinary portland cement was used as a binder, and high volume fly ash was also used to improve the properties of ECC. An ECC designed in this study showed high tensile strain capacity of 3.0%. Three types of beams were manufactured according to the replacement length of concrete with ECC. From the bending tests, it was found that load-bearing capacity as well as ductility of beam increased with an increase in the replacement length of concrete with ECC. Curvature ductility and plastic hinge length of beam were also increased.

An Experimental Study on Evaluation of Repair Mortars with CAC (Calcium Aluminate Cement) for Sewer Pipe (하수관거 보수용 CAC 모르타르 성능평가에 대한 실험적 연구)

  • Chung, Jee-Seung;Kang, Weon-Dae
    • Journal of the Korean Society of Safety
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    • v.27 no.4
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    • pp.68-75
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    • 2012
  • The biogenic corrosion of mortars adopted in sewage repair by sulfuric acid-producing bacteria was considered in this paper. Calcium aluminate cement (CAC) was known to resist microbiologically-induced corrosion significantly better than portland and blended portland cement.In this study, CAC as well portland cement mortars were tested as main binder to evaluate the corrosion resistance by the chemical immersion test. Replacement ratios of CAC were changed as 0, 20, 40, 50, 60% of OPC binder and 0, 2, 4, 6% of EVA(Ethylene Vinyl Acetate) were also adopted to increase properties of CAC repair mortars in sewage application. Setting time, compressive strength, acid resistance and adhesive strength were measured for various experiments. As a results of the experiments, the proper formulation of repair mortars was found at 40% of CAC and 4% of EVA. Finally, the CAC mortars adopted in field sewer pipe and were demonstrated to superior in adhesion and workability.