• Journal of the Korea Concrete Institute
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• v.26 no.4
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• pp.421-428
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• 2014

This paper describes the experimental results of insulated concrete sandwich wall panels (CSWP) with corrugated glass fiber-reinforced polymer (GFRP) shear connectors under in-plane shear loading. Corrugated GFRP shear connectors were used to improve the thermal property of insulated CSWP and to achieve composite action between the interior and exterior concrete wall panels. Test specimens were consist of three concrete panels with two insulation layers between concrete panels and middle concrete panels was loaded in the direction of gravity. To evaluate the effects of insulation types (extruded polystyrene, XPSS and expanded polystyrene, EPS), shear connector pitch (300 and 400 mm) and width (10 and 15 mm) on in-plane shear behavior of insulted CSWP, failure mode and shear flow-average relative slip relationship of specimens were investigated. Test results indicate that the bond stress between concrete panel and insulation is considerable initially. Especially in case of insulated CSWP without shear connector, initial stiffness of CSWP with XPSS is superior to that of CSWP with EPS. The shear connector's contribution to in-plane shear performance of insulated CSWP depends on the type of insulation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.3
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• pp.403-414
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• 1994

Nonlinear analysis of RC containment structure under thermal load and pressure is presented to trace the behaviour after an assumed LOCA. The temperature distribution varying with time through the wall thickness is determined by transient finite element analysis with the two time level scheme in time domain. The layered shell finite elements are used to represent the containment structures in nuclear power plants. Both geometric and material nonlinearities are taken into account in the finite element formulation. The constitutive relation of concrete is modeled according to Drucker-Prager yield criteria in compression. Tension stiffening model is used to represent the tensile behaviour of concrete including bond effect. The reinforcing bars are modeled by smeared layer at the location of reinforcements accounting elasto-plastic axial behaviors. The steel liner model under Von Mises yield criteria is adopted to represent elastic-perfect plastic behaviour. Geometric nonlinearity is formulated to consider the large displacement effect. Thermal stress components are determined by the initial strain concept during each time step. The temperature differential between any two consecutive time steps is considered as a load incremental. The numerical results from this study reveal that nonlinear temperature gradient based on transient thermal analysis will produces excessive large displacement. Nonlinear behavior of containment structures up to ultimate stage can be traced reallistically. The present study allows more realistic analysis of concrete containment structures in nuclear power plants.

• Journal of the Korean Vacuum Society
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• v.7 no.3
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• pp.267-267
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• 1998

The fluorine doped silicon oxide (SiOF) intermetal dielectric (IMD) films have been of interest due to their lower dielectric constant and compatibility with existing process tools. However instability issues related to bond and increasing dielectric constant to water absorption when the SiOF films was exposured to atmospheric ambient. Therefore, the purpose of this research is to study the effect of post oxygen plasma treatment on the resistance of moisture absorption and reliability of SiOF film. Improvement of moisture absorption resistance of SiOF film is due to the forming of thin SiO₂layer at the SiOF film surface. It is thought that the main effect of the improvement of moisture absorption resistance was densification of the top layer and reduction in the number of Si-F bonds that tend to associate with OH bonds. However, the dielectric constant was increased when plasma treatment time is above 5 min. In this study, therefore, it is thought that the proper plasma treatment time is 3 min when plasma treatment condition is 700 W of microwave power, 3 mTorr of process pressure and 300℃ of substrate temperature.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.11
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• pp.1087-1094
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• 2008

Diazinon is a phosphorothiate insecticide widely used in the world including Korea. This study investigates the feasibility of photolysis and photocatalysis processes for the degradation of diazinon in water. Both photolysis and photocatalysis reactiosn were effective in degrdading diazinon, however lower TOC removals were achieved. In case of photocatalysis, approximately 40% of nitrogen from diazinon was recovered as NO$_3^-$, and less than 5% of phosphorus as PO$_4{^{3-}}$. However, the sulfur in diazinon molecule was completely recovered to SO$_4{^{2-}}$ from photocatalysis reaction, and the recovery from photolysis was 50%, indicating that P=S bond easily breaks first during photolysis and photocatalysis. The poor recoveries of ionic byproducts and TOC from photolysis and photocatalysis indicate the presence of other organic intermediates during reactions. The formation of organic intermediates were identified during reactions using GC/MS and LC/MS/MS, and the main degradation products were diazoxon, and 2-isopropyl-4-methyl-6-hydroxypyrimidine (IMP), respectively. Finally, the acute 48-hr toxicity test using Daphnia magna were employed to measure the toxicity reduction during photocatalysis of degradation. The results showed that the toxicity increased until 180 min of the photocatalysis reaction (from EC$_{50}$ (%) of 69.6 to 13.2%), however, acute toxicity completely disappeared (>100%) after 360 min. The toxicity results showed that the intermediates from photocatalysis such as diazoxon were more toxic than diazinon itself, however these intermediates can be degraded or mineralized with further reaction.

• THE INTERNATIONAL COMMERCE & LAW REVIEW
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• v.46
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• pp.133-158
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• 2010

Independent guarantee is a creation of the need from the both sides, i.e. the applicant (principal debtor) and the beneficiary (creditor). The former used to have to deposit cash in favor of the beneficiary in case of his default, which laid a burden on his liquidity while the latter still wanted to have the equivalent to cash. Independent guarantee satisfied the both parties by freeing the applicant of a deposit and maintaining the beneficiary's right at the same time. The fact that independent guarantee has three payment mechanisms is not widely known to the public. They are (i) payment on first demand, (ii) payment upon submission of third-party documents, (iii) payment upon submission of an arbitral or court decision. From the applicant's point of view, the order in his favor is (iii), followed by (ii) and (i). As there shouldn't be a case where one party is at a disadvantage against the other, useful insight is being sought for the benefit of the applicant. First, the applicant can offer his intention to provide a payment mechanism (ii) or (iii) rather than (i) if he must deliver it. Second, if the beneficiary still wants to have (i) and the applicant is in a position not to reject it, the latter should thoroughly check any provisions that may work against him later. Third, the applicant could use counterbalancing provisions in underlying contract to cope with protective clauses in the guarantees. Forth, the applicant should review the beneficiary's sincerity to prevent unfair calling risks. The applicant may use an ECA(Export Credit Agency) in his country to which he can transfer not only unfair calling risks, but also political risks. On the other hand, a bank needs to keep the following advice in mind. The foremost important thing for the bank not to forget is that it provides a guarantee as a service provider, not as a responsible party for the feasibility of the project, etc. Credit risk of the applicant should require the greatest attention when issuing a guarantee: the bank should look into the possibility that it can procure immediate reimbursement from its customers after payment to the beneficiary. Second, the applicant's ability to complete the project should be reviewed by checking its track records, techniques and reputation, etc. Third, the bank may also use an ECA to cover the beneficiary's unfair calling risks as well as political risks. In the case of Korea, as Korea Export Insurance Corporation(KEIC) can cover all the risks mentioned above, the bank could use its service called 'Export Bond Insurance.' What's better for the bank is that ECA cover can enhance the bank's asset quality by putting it zero on its risk weighted asset.

• Journal of the Korea Concrete Institute
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• v.21 no.4
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• pp.401-408
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• 2009

A compression lap splice becomes an important issue due to development of ultra-high strength concrete. Current design codes regarding compression lap splice do not utilize merits of the improved strength of ultra-high strength concrete. Especially, a compression lap splice can be calculated longer than a tension lap splice according to the codes because they do not consider effects of compressive strength of concrete and transverse reinforcement. This anomaly confuses engineers in practice. Design equation is proposed for compression lap splice in 40 to 70 MPa of compressive strength of concrete. The proposed equation is based on 51 specimens conducted by authors. Basic form of the equation includes main parameters which are derived from investigating test results. Through two-variable non-linear regression analysis of measured splice strengths, a strength equation of compression lap splices is then derived. A specified splice strength is defined using a 5% fractile coefficient and a lap length equation is constructed. By the proposed equation, the anomaly of lap lengths in tension and compression is got rid of. In addition, the equation has a reliability equivalent to those of the specified strengths of materials.

• Journal of the Korea Concrete Institute
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• v.20 no.3
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• pp.405-412
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• 2008

Six alkali-activated (AA) concrete mixes were tested to explore the significance and limitations of developing an environmental friendly concrete. Ground granulated blast-furnace slag and powder typed sodium silicate were selected as source material and an alkaline activator, respectively. The main parameter investigated was the replacement level of lightweight fine aggregate to the natural sand. Workability and mechanical properties of lightweight AA concrete were measured: the variation of slump with time, the rate of compressive strength development, the splitting tensile strength, the moduli of rupture and elasticity, the stress-strain relationship, the bond resistance and shrinkage strain. Test results showed that the compressive strength of lightweight AA concrete sharply decreased when the replacement level of lightweight fine aggregate exceeded 30%. In particular, the increase in the discontinuous grading of lightweight aggregate resulted in the deterioration of the mechanical properties of concrete tested. The measured properties of lightweight AA concrete were also compared, wherever possible, with the results obtained from the design equations specified in ACI 318-05 or EC 2, depending on the relevance, and the results predicted from the empirical equations proposed by Slate et al. for lightweight ordinary Portland cement concrete. The stress-strain curves of different concrete were compared with predictions obtained from the mathematical model proposed by Tasnimi. The measured mechanical properties of lightweight AA concrete generally showed little agreement with the predictions obtained from these equations.

• Journal of the Korean Magnetics Society
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• v.11 no.2
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• pp.58-62
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• 2001

The L $i_{0.5}$F $e_{2.5-x}$A $l_{x}$ $O_4$ systems (x=0, 0.3, 0.6, 0.9, 1.2, 1.5) were investigated by X-ray diffraction and Mossbauer spectroscopy. The structure of all the samples is cubic spinel type and lattice constant decrease with increasing Al content x. The Moissbauer spectra reveal two sextet for 0$\leq$x$\leq$0.6, two sextet and a doublet for 0.9$\leq$x$\leq$1.2, and a doublet for x=1.5. The cation distribution of the samples is (L $i_{1-a}$$^{+}$F $e_{a}$ $^{3+}$)$^{A}$[L $i_{a-0.5}$$^{+}$A $l_{2.5-a-x}$$^{+}$F $e_{2.5-a-x}$$^{3+}$]$^{B}$ $O_4$$^{2-}$ and substituted $Al^{3+}$ ions decrease the covalency of F $e^{3+}$- $O^{2-}$ bond in B-sites and A-B super-exchange interactions.tions.s.tions.ons.s.

• Economic and Environmental Geology
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• v.30 no.4
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• pp.279-289
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• 1997

Dark to pale green-colored, Cr-bearing sericites from hydrothermal alteration zone of the Narim gold deposit were investigated mineralogically and geochemically. The alteration zone is composed mineralogically of quartz, carbonate minerals and green sericite with minor amounts of chlorite, barite and sulfide minerals (pyrite, sphalerite, galena). The zone is enriched in As (967 to 1520 ppm), Cu (31 to 289 ppm), Ni (1027 to 1205 ppm), Pb (0.20 to 1.24 wt.%) and Zn (1.03 to 1.07 wt. %) compared with fresh rocks such as granitic gneiss, porphyritic biotite granite and basic dyke. The Cr, probably the chromophore element, is highly enriched in the alteration zone (1140 to 1500 ppm), host granitic gneiss (1200 ppm) and porphyritic biotite granite (1200 ppm). Occurrence and grain size of sericite are diverse, but most of the Cr-bearing sericites (150 to $200{\mu}m$ long and 20 to $30{\mu}m$ wide) occur along the boundaries between ore veins and host rocks (especially basic dyke and granitic gneiss). X-ray diffraction data of the sericite show its monoclinic form with unit-cell parameters of $a=5.202{\AA}$, $b=8.994{\AA}$, $c=20.103{\AA}$, ${\beta}=95.746^{\circ}$ and $V=935.83{\AA}^3$, which are similar with the normal 2M1-type muscovite. Representative chemical formula of the sericite is ($K_{1.54}Ca_{0.03}Na_{0.01}$)($Al_{3.42}Mg_{0.38}Cr_{0.14}Fe_{0.06}V_{0.02}$)($Si_{6.69}Al_{1.31}$)$O_{20}(OH)_4$. The Cr content increases with decrease of the octahedral Al content, and ranges from 0.36 to 2.58 wt.%. DTA and TG curves of the sericite show endothermic peaks at $342^{\circ}$ to $510^{\circ}$, $716^{\circ}$ to $853^{\circ}$ and $1021^{\circ}C$, which are due to the expulsion of hydroxyl group. The total weight loss by heating is measured to be about 8.8 wt. %, especially at $730^{\circ}C$. Infrared absorption experiments of the sericite show broad absorption band due to the O-H bond stretching vibration near the $3625cm^{-1}$, coupled with the 825 and $750cm^{-1}$ doublet. The vibration bands related with the H-O-Al and Si-O-Al bonds occur at $1030cm^{-1}$ and 500 to $700cm^{-1}$, respectively. Based on paragonite content of the sericite, the formation temperature of the Narim gold deposit is calculated to be $220{\pm}10^{\circ}C$.

• Journal of the Korea Concrete Institute
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• v.24 no.2
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• pp.111-120
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• 2012

This paper is a report about lap splice performance of rebar embedded in the strain-hardening cement-based composites (SHCCs) under monotonic and repeated tension loading. Ten mix proportions of cement-based composites such as SHCCs and normal concrete were investigated. The study parameters are comprised of (1) types of reinforcing fibers (polyethylene and steel fiber), (2) replacement levels of expansive admixture (EXA, 0% and 10%), and (3) compressive strength (30 and 100 MPa) of cement-based composites. Lap splice lengths (ld) of rebars in SHCC materials and normal concrete were 60% and 100% of splice length calculated by code requirements for structural concrete, respectively. Test results indicated that SHCCs materials can lead to enhancements in the lap splice performance of embedded rebar. All of the fiber reinforcement conditions (PE-SHCC and PESF-SHCC) considered in this study produced considerable improvements in the tensile strength, cracking behavior, and bond strength of lap-spliced rebar. Furthermore, adding EXA to SHCC matrix improved the tensile lap splice performance of rebar in SHCC materials. However, for controlling crack behavior, the performance of PE-SHCC was better than that of PESF-SHCC due to its mechanical properties. This study demonstrated an effective approach for reducing required development length of lap spliced rebar by using SHCC materials.