• Polymer(Korea)
• /
• v.38 no.4
• /
• pp.535-543
• /
• 2014

This work, which was about the synthesis of naphthalimidopropyl acrylate and GMA copolymers and their physical properties, investigated the compositions of the copolymer, the reactivity ratios of the monomer, resonance effect (Q), polar effect (e) and fluorescence of naphthalene. Azobisisobutyronitronitryl (AIBN) as an initiator was employed at $60^{\circ}C$ with dimethylformamide (DMF) of solvent for the copolymerization of NIPA. $r_1$ was found to be higher than $r_2$ from the reactivity ratios of the monomer obtained from Fineman-Ross (F-R), Kelen-$T{\ddot{u}}d{\ddot{o}}s$(K-T) methods. NIPA was found to be more copolymerized than GMA. $r_1{\cdot}r_2$ product was lower than 1, copolymerization was maked random-alternating type. The fluorescence spectrum of these polymers showed a weak monomer fluorescence band at 380 nm and a strong excimer fluorescence band at about 460 nm. Fluorescence life time of NIPA monomer showed fluorescence cover with UV 355 nm at room temperature, and life time showed $5.1449{\times}10^{-7}s$.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
• /
• v.19 no.12
• /
• pp.1339-1349
• /
• 2008

In this paper, a nonlinear relationship between an input complex envelope and an output complex envelope of m-th harmonic zone is theoretically analyzed, and AM/$AM_m$ and AM/$PM_m$ are defined. A scheme to extract these characteristics from measured in-phase and quadrature-phase data is suggested. The proposed analysis is verified with a fundamental-fundamental and fundamental-third harmonic measurements for a InGaP power amplifier(PA). Based on the harmonic-band nonlinear analysis and extraction scheme, a new technique to send a signal in m-th harmonic band with a harmonic signal Linearization Digital Predistortion(DPD) scheme is presented. A numerical analysis and a Look-Up Table(LUT) based DPD algorithms to linearize output signal on m-th harmonic zone are developed. For a 16- and a 64-QAM input signals, a DPD for third harmonic signal linearization is implemented, and output spectrum and signal constellation are measured. The wholly distorted signals are linearized, and thus the measured Error Vector Magnitudes (EVM) are 6.4 % and 6.5 % respectively. The results show that a proposed scheme linearizes a nonlinearly distorted harmonic band signals. The proposed nonlinear analysis and predistortion scheme can be applied to multiband transmitter in next generation software defined radio(SDR)/cognitive radio(CR) wireless system.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.15 no.7
• /
• pp.4659-4664
• /
• 2014

The noise produced in a factory is a cause of the noise complaint of the surrounding residential areas. In addition, it affects the work efficiency and health of workers. This paper presents the results of a basic study to reduce the noise generated from the blower, which is often used in the factory of a small and medium scale, using an active noise controller (ANC) in three-dimensional space. For this purpose, the simulator program, which can compare various parameters of the original noise and controlled noise, such as sound pressure levels, power spectra, and equivalent noise levels, was developed. The noise data was recorded at 17 points around a turbo fan blower currently being operated in a small-medium size factory. The simulation results showed that the power spectrum was reduced by a maximum of 40dB in the low frequency band and the average equivalent noise level attenuation was 12.6dB.

• Journal of Biomedical Engineering Research
• /
• v.28 no.4
• /
• pp.556-568
• /
• 2007

Unsatisfied results of return of spontaneous circulation (ROSC) estimates were caused by the fact that the predictability of the predictors was insufficient. This unmet estimate of the predictors may be affected by transitional events due to behaviors which occur during cardiopulmonary resuscitation (CPR). We thus hypothesized that the discrepancy of ROSC estimates found in statistical characteristics due to transitional CPR events, may affect the performance of the predictors, and that the performance of the classifier dichotomizing between ROSC and No-ROSC might be different during CPR. In a canine model (n=18) of prolonged ventricular fibrillation (VF), standard CPR was provided with administration of two doses of epinephrine 0 min or 3 min later of the onset of CPR. For the analysis of the likelihood of a successful defibrillation during CPR, Support Vector Classification was adopted to evaluate statistical peculiarity combining time and frequency based predictors: median frequency, frequency band-limited power spectrum, mean segment amplitude, and zero crossing rates. The worst predictable period showed below about 1 min after the onset of CPR, and the best predictable period could be observed from about 1.5 min later of the administering epinephrine through 2.0-2.2 min. As hypothesized, the discrepancy of statistical characteristics of the predictors was reflected in the differences of the classification performance during CPR. These results represent a major improvement in defibrillation prediction can be achieved by a specific timing of the analysis, as a change in CPR transition.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.11 no.6
• /
• pp.2196-2201
• /
• 2010

The video transmission system using OFDM method at 18GHz frequency band was developed for wireless video transmission from subway to monitoring center when subway running. It is composed of digital modulation board and RF board. And it has a robust characteristics of multipath fading in subway tunnels at 18GHz. To verify the system, we used spectrum analyzer for analysing the output of transmission system and get the results that it has 350MHz frequency, 8MHz bandwidth and -19dBm channel power. Also we tested video receiving using MPEG-2 encoder and got good quality images.

• Journal of the Institute of Electronics Engineers of Korea SP
• /
• v.44 no.1
• /
• pp.70-75
• /
• 2007

In order to mitigate the problems in storage space and network bandwidth for the full CD quality audio with 44.1 kHz sampling rate, current existing digital audio is always restricted by sampling rate and bandwidth. This kind of restriction normally can be resolved by using low bit rate audio codec such as MP3, OGG, and AAC. However it suffers a major problem such as a loss of high frequency fidelity. This high frequency loss will reproduce only the band-limited low-frequency part of audio in the standard CD-quality audio. In general, the high frequency contents of audio have lots of information such as localization and ambient information, and bright nature of audio. The purpose of this paper is to implement on ARM platform system that can effectively estimate and compensate the missing high frequency contents of MP3 audio. From the experimental results with spectrum analysis and listening test, we confirm the superiority of the proposed algorithms for MP3 audio quality enhancement.

• Biomolecules & Therapeutics
• /
• v.14 no.1
• /
• pp.30-35
• /
• 2006

Tissue-type plasminogen activator (t-PA) is a multidomain serine protease containing two kringle domains, TK1-2. Previously, Pichia-derived recombinant human TK1-2 has been reported as an angiogenesis inhibitor although t-PA plays an important role in endothelial and tumor cell invasion. In this work, in order to improve in vivo efficacy of TK1-2 through elimination of immune reactivity, we mutated wild type TK1-2 into non-glycosylated form (NE-TK1-2) and examined whether it retains anti-angiogenic activity. The plasmid expressing NE-TK1-2 was constructed by replacing $Asn^{l17}\;and\;Asn^{184}$ with glutamic acid residues. After expression in Pichia pastoris, the secreted protein was purified from the culture broth using S-sepharose and UNO S1-FPLC column. The mass spectrum of NE-TK1-2 showed closely neighboring two peaks, 19631.87 and 19,835.44 Da, and it migrated as one band in SDS-PAGE. The patterns of CD-spectra of these two proteins were almost identical. Functionally, purified NE-TK1-2 was shown to inhibit endothelial cell migration in response to bFGF stimulation at the almost same level as wild type TK1-2. Therefore, the results suggest that non-glycosylated NETK1-2 can be developed as an effective anti-angiogenic and anti-tumor agent devoid of immune reactivity.

• Analytical Science and Technology
• /
• v.20 no.5
• /
• pp.406-412
• /
• 2007

The formation of inclusion complexes between ${\beta}$-cyclodextrin and diethylenetriamine substituted-pyridine copper(II) perchlorate; [Cu(dien)(sub-py)] $(ClO_4)_2$, were studied by spectrophotometric methods. On account of charge-transfer band(MLCT) and $^2T_2{\rightarrow}^2E$, the two high peaks were observed as an inclusion complex for the [${\beta}$-CD]$[Cu(dien)(p-Cl-py)]^{2+}$ in the ultraviolet region of the spectrum. The ${\beta}$-CD and $[Cu(dien)(sub-py)]^{2+}$ ion formed a 1:1 complex, and the formation constants were decreased with the increasing temperatures, due to weak binding energy between ${\beta}$-CD and $[Cu(dien)(sub-py)]^{2+}$ ion. This reaction was controlled by enthalpy. In a correlation of the Hammett substituent constants and formation constants for the reaction, formation constants were increased by strong binding energy in the inclusion complexes when electron donating groups were substituted in pyridine ring.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.28 no.2B
• /
• pp.237-248
• /
• 2008

Precipitation variability in Korea is mainly influenced by climate circulation such as sea surface temperature, not a local convection. Therefore, this study investigates relationship between monthly precipitation of 61 station observed by Korea Meteorological Administration and global sea surface temperatures (SSTs). The main components of monthly precipitation in Korea are extracted by a method which consists of the principal analysis combined with the cluster analysis, to examine the correlation between monthly rainfalls and SSTs. The relationships between main components of monthly precipitation and SSTs exists in Pacific Ocean. At the result of Wavelet Transform analysis, The 2-4 year band have a strong wavelet power spectrum and the low frequency. the correlation coefficient between low frequency components of monthly rainfalls and SSTs calculated bigger then correlation coefficient between main components and SSTs. Hence, these results propose a prediction possibility of monthly precipitations using the varition of SSTs.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.13 no.2
• /
• pp.89-105
• /
• 2008

Sea level and atmospheric pressure data of 1999-2005 from four stations along the Korean east coast were analyzed to understand the sea level variability and its causal mechanism. The results of the wavelet and the auto-spectrum analyses indicate that the sea level fluctuations of 3-17 day period are statistically significant at the 95% confidence level, especially in spring to early summer. In this period, the coherency between the sea levels and the atmospheric pressures in a cross-spectrum is high, implying the importance of an inverted barometric effect in generation of the sea level fluctuations. To learn about the sea level variability, the cross-spectrum analyses were applied between the sea levels of the adjacent stations. The results show a case of southward phase propagations along the coast, as in 1999, 2003 and 2005, and an another case of no progressive phase lags between the stations, as in 2000-2002, and 2004. The phase speed in the former case is 12-15 m/s, which is a commonly observed phase speed of coastal Kelvin waves. Generation of such fluctuations seems to be related to low pressure cells developed in the Asian continent in spring and summer and moving eastward over the coastal region north of the stations. The latter case of no progressive phase lag, however, occurs when the low pressure cells developed in the continent move along the region south of the stations. In this case, the northeastward phase propagation with a speed of 5-8 m/s is observed along the southwestern coast of Japan.