• Title/Summary/Keyword: OH Chemiluminescence

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The Characteristics of Local Reaction Intensity with Changing Combustor Pressure in the Swirl-stabilized Flame (스월화염에서 연소실 압력 변동에 의한 국소 반응강도의 특성)

  • Noh, Young-Gu;Kim, Jong-Ryul;Kim, Tae-Hyung;Seo, Sang-Il;Kim, Sung-Chul;Na, Jong-Moon;Choi, Gyung-Min;Kim, Duck-Jool
    • Journal of the Korean Society of Combustion
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    • v.14 no.4
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    • pp.41-47
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    • 2009
  • An experimental study was performed to confirm the effect of the changing combustor pressure(-30~30 kpa), combustion characteristics were investigated by measuring the local chemiluminescence intensity, the local temperature distribution and emission. In order to investigate combustion ones, the combustor pressure index($P^*$) was controlled in the range of 0.7~1.3 for each equivalence ratio in the present combustion system, where $P^*$ is defined as the ratio of absolute pressure to atmospheric one. The local mean temperature showed the uniform distributions for lower pressure index, which increased with increasing equivalence ratio. The mean $OH^*$ chemiluminescence intensity, showed high level for lower pressure index for ${\Phi}{\get}1.0$ conditions. EINOx decreased with decreasing pressure index for overall equivalence ratio conditions.

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Combustion Characteristics of Methane/Oxygen Gas in Pre-mixed Swirl Flame (메탄/순산소 예혼합 화염의 선회 특성)

  • Choi, Won-Seok;Kim, Han-Seok;Cho, Joo-Hyeong;Kim, Yong-Mo;Ahn, Kook-Young;Woo, Ta-Kwan
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.1979-1983
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    • 2008
  • The effects of carbon dioxide addition to oxygen have been investigated with swirl-stabilized premixed methane flame in a laboratory-scale pre-mixed combustor. The methane fuel and oxydant mixture gas ($CO_2$ and $O_2$) were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for different amount of carbon dioxide addition to the methane fuel and different swirl strengths. The effects of carbon dioxide addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using chemiluminescence techniques to provide information about flow field. The results show that the flame area increases at upstream of reaction zone because of increase in recirculation flow for increase in swirl intensity. The flame area is also increased at the downstream zone by recirculation flow because of increase in swirl intensity which results in higher centrifugal force. The OH and CH radical intensity of reaction zone decrease with carbon dioxide addition because the carbon dioxide plays a role of dilution gas in the reaction zone.

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A Study of Combustion Instability Mode in Dual Swirl Gas Turbine Combustor by PLIF and Chemiluminescence Measurement (PLIF 및 자발광 계측을 이용한 이중선회 가스터빈 연소기에서 연소불안정 모드 연구)

  • Choi, Inchan;Lee, Keeman;Juddoo, Mrinal;Masri, A.R.
    • Journal of the Korean Society of Combustion
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    • v.19 no.1
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    • pp.29-38
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    • 2014
  • This paper described an experimental investigations of combustion instability mode in a lean premixed dual swirl combustor for micro-gasturbine system. When such the instability occurs, a strong coupling between pressure oscillations and unsteady heat release excites a self-sustained acoustic wave which results in a loud, annoyed sound and may also lead a structural damage to the combustion chamber. The detailed period of flame behavior and heat release in combustion instability mode have been examined with high speed OH and CH-PLIF system and $CH^*$ chemiluminescence measurement, flame tomography with operated at 10 kHz and 6 kHz each. Experiment results suggest that unstable flame behavior has a specific frequency with 200 Hz and this frequency is accords with about 1/2 sub-harmonic of combustor resonance frequency, not fundamental frequency. This is very interesting phenomenon that have not reported yet from other previous works. Therefore, when a thermo-acoustic instability with Rayleigh criterion occurs, the fact that the period of heat release and flame behavior are different each other was proposed for the first time through this work.

Experimental Study on Laminar Lifted Methane Jet Flame Diluted with Nitrogen and Helium

  • Sapkal, Narayan;Lee, Won June;Park, Jeong;Kwon, Oh Boomg
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.387-389
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    • 2014
  • Laminar lifted methane jet flame diluted with nitrogen and helium in co-flow air has been investigated experimentally. This paper examines the role of chemistry, intermediate species responsible for stabilization of lifted flame. To elucidate the stabilization mechanism in lifted methane jet flames with Sc<1, the chemiluminescence intensities of $CH^*$ and $OH^*$ were measured using ICCD camera at various nozzle exit velocities and fuel mole fractions. It has been observed that the $OH^*$ species can play an important role in stabilization of lifted methane jet flame as they are good indicators of heat release rate which can affect on flame speed and increase stability through reduction in ignition delay time.

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Experimental Study on Laminar Lifted Methane Jet Flame Diluted with Nitrogen and Helium

  • Sapkal, Narayan;Lee, Won June;Park, Jeong;Kwon, Oh Boomg
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.125-128
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    • 2014
  • Laminar lifted methane jet flame diluted with nitrogen and helium in co-flow air has been investigated experimentally. This paper examines the role of chemistry, intermediate species responsible for stabilization of lifted flame. To elucidate the stabilization mechanism in lifted methane jet flames with Sc<1, the chemiluminescence intensities of $CH^*$ and $OH^*$ were measured using ICCD camera at various nozzle exit velocities and fuel mole fractions. It has been observed that the $OH^*$ species can play an important role in stabilization of lifted methane jet flame as they are good indicators of heat release rate which can affect on flame speed and increase stability through reduction in ignition delay time.

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Flame Structure and Light Emission Characteristics in Coaxial Laminar Partially Premixed $CH_{4}/Air$ Flames;Effect of Central Fuel Injection (이중동축 메탄/공기 층류 부분 예혼합화염에서의 화염구조와 자발광 배출 특성;안쪽관 연료주입의 영향)

  • Oh, Jeong-Seog;Jeong, Yong-Ki;Jeon, Chung-Hwan;Chang, Young-June
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1116-1121
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    • 2004
  • In this study, the effect of central fuel injection on a coaxial laminar $CH_{4}/air$ flame was experimented at the defined premixing condition(${\Phi}=1.90$, ${\sigma}=50/75/100%$, x/D=10). The partial premixing parameter are the equivalence ratio that total fuel is fixed at 200cc/min, the fuel split degree which means the percentage of fuel entering the outer tube to the total amount, and the mixing distance indicating the nonreactant mixture's homogeneity between inner tube top and burner exit. The object is to investigate the flame structure and chemiluminescence characteristics of laminar partial premixed flame as changing mixing parameters. The radical signal was acquired from ICCD camera and PMT. Each intensity was compared with Abel inverted value for measuring the effect of background light on the peak signal location and the intensity at central preheat zone. The results show that the peak location of each radical was broaden as the fuel split degree increasing because the mixing quality was enhanced. and $OH^{\ast}$ is a good indicator for flame front between reaction and preheat zone. At last $CH_{2}^{\ast}$ has the same tendency with $CH^{\ast}$ but a thinner reaction zone than $CH^{\ast}$ due to a rapid decay on the burned gas side.

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Antioxidative and Free Radical Scavenging Activity of Water Extract From Dandelion (Taruaxacum officinale) (민들레 물추출물의 항산화 및 자유라디칼 소거활성)

  • 강미정;신승렬;김광수
    • Food Science and Preservation
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    • v.9 no.2
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    • pp.253-259
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    • 2002
  • The antioxidative and free radical scavenging activity of water extracts of dandelion were investigated. Antioxidative and radical scavenging activity were assessed by means of different tests; inhibition of peroxidation on linoleic acid model system, scavenging DPPH radical, scavenging of hydroxyl radical by chemiluminescence assay, scavenging of superoxide anion radical by EPR spectroscopy and scavenging of hydrogen peroxide. The leaf extract showed strong antioxidant activity in linoleic acid system. The antioxidant activity of water extracts of dandelion increased with increasing concentrations of extracts. The scavenging activity of the dandelion extracts, on inhibition of the DPPH radical, was related to the reaction time. Hydroxyl radical were generated by lenten reaction and dandelion extract was found to scavenge OH˙in a concentration-dependent manner. The water extract of leaf had effective scavenging activities on hydrogen peroxide and superoxide anion radical. From the these data, it is evident that water extract of dandelion leaf is an effective scavenger for OH˙, O$_2$¨, DPPH˙, hydrogen peroxide. And, the antioxidative effect observed is believed to be partly due to this radical scavenger activity.

Laminar Lifted Methane Jet Flames in Co-flow Air

  • Sapkal, Narayan P.;Lee, Won June;Park, Jeong;Lee, Byeong Jun;Kwon, Oh Boong
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.83-86
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    • 2015
  • The Laminar lifted methane jet flames diluted with helium and nitrogen in co-flow air have been investigated experimentally. The chemiluminescence intensities of $OH^{\ast}$ and $CH_2O^{\ast}$ radicals and the radius of curvature for tri-brachial flame were measured using an intensified charge coupled device (ICCD) camera, monochromator and digital video camera. The product of $OH^{\ast}$ and $CH_2O^{\ast}$ is used as a excellent proxy of heat release rate. These methane jet flames could be lifted in buoyancy and jet dominated regimes despite the Schmidt number less than unity. Lifted flames were stabilized due to buoyancy induced convection in buoyancy-dominated regime. It was confirmed that increased $OH^{\ast}$ and $CH_2O^{\ast}$ concentration caused an increase of edge flame speed via enhanced chemical reaction in buoyancy dominated regime. In jet momentum dominated regime lifted flames were observed even for nozzle exit velocities much higher than stoichiometric laminar flame speed. An increase in radius of curvature in addition to the increased $OH^{\ast}$ and $CH_2O^{\ast}$ concentration stabilizes such lifted flames.

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An Experimental Investigation of the Characteristic of Radical ($OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$) and Pollutant Emission in Partially Premixed Swirling Methane-air Flames. (스월을 강화한 메탄/공기 부분 예혼합화염에서 자발광($OH^{\ast}$, $CH^{\ast}$, 그리고 $C_2^{\ast}$) 배출특성과 배기배출물에 관한 실험적 연구)

  • Ahn, Kyuong-Min;Jeong, Yong-Ki;Chang, Young-June;Jeon, Chung-Hwan
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.320-327
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    • 2005
  • An experimental study was performed to investigate the effects of partially premixing, varying the equivalence ratios from $1.36{\sim}{\infty}$, and swirlers with swirl numbers of 0, 0.28, 0.64, and 1.32, on the characteristic of radical ($OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$) and pollutant emission in partially premixed swirling flames. The signal from the electronically excited state of $OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$ was detected through a band pass filter with a photo multiplier tube, and flow fields images were detected through a schlieren system. The results demonstrated that the flame height decreases and jet spreading angle increase with increasing a swirl number. The more momentum ratio and swirl number increase, the more decrease flame height, and the generation of sooting flame is promoted.

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Symptoms on Generation of Combustion Oscillation and their Detection (진동연소 발생에 관한 징후와 이의 검출)

  • 양영준
    • Journal of Energy Engineering
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    • v.13 no.3
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    • pp.205-213
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    • 2004
  • Usefulness of an optical fiber was demonstrated by detecting the generation of self-excited combustion oscillations. OH chemiluminescence intensity detected by the optical fiber showed mostly excellent agreement with those obtained by high speed CCD camera measurements when combustion oscillations were strong. Symptoms of self-excited combustion oscillation were also studied in order to predict the onset of combustion oscillation before it proceeded to a catastrophic failure. For the purpose, we have found and proposed unique measures to tell the onset of self-excited combustion oscillations based on the careful statistics of fluctuating properties in flames, such as pressure or omission of OH radicals.