• Bulletin of the Korean Chemical Society
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• v.25 no.9
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• pp.1346-1350
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• 2004

Pseudo-first order rate constants $(k_{obs})$ are reported for the following solvolyses in approximately isodielectric mixtures: 3- and 4-methoxybenzyl chloride, bromo- and chlorodiphenylmethane, and 4-chloro-, 4,4'-dichloro and 4-methyl-chlorodiphenylmethane in 0-80% v/v nitromethane-methanol mixtures; and bromo- and chlorodiphenylmethane and 4-methyl-chlorodiphenylmethane in various acetonitrile-methanol mixtures (in the range 0-50% v/v) at$25^{\circ}C.$ These data, and literature data for t-butyl halides (Cl, Br, and I), and for p-methoxybenzoyl chloride, show rate maxima in solvent compositions of ca. 30% aprotic cosolvent, explained by a stoichiometric solvent effect on electrophilic solvation. Linear relationships are observed between $(k_{obs})/[MeOH]^2$ and [AP]/[MeOH], where [AP] refers to the molar concentration of aprotic cosolvent. The results are consistent with competing third order contributions to $k_{obs}$, $k_{MM}[MeOH]^2$ with hydrogen-bonded methanol as electrophile, and $k_{MAP}[MeOH][AP]$ with hydrogen-bonding disrupted by the aprotic solvent.

• Earthquakes and Structures
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• v.8 no.3
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• pp.699-712
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• 2015

Bracing structures with off-centre bracing system is one of the new resistant systems that frequently used in the frame with pin connections. High ductility, high-energy dissipation and decrease of base shear are advantages of this bracing system. However, beside these advantages, reconstruction and hard repair of off-centre bracing system cause inappropriate performance in the earthquake. Therefore, in this paper, the goal is investigating the behavior of this type of bracing system with ductile element (circular dissipater), in order to providing replacement of damaged member without needing repair or reconstruction of the general system. To achieve this purpose, some numerical studies have been performed using ANSYS software, a frame with off-centre bracing system and optimum eccentricity (OBS-C-O) and another frame with the same identifications without ductile element (OBS) has been created. In order to investigate precisely on the optimum placement of circular elements under monotonic load again three steal frames were modeled. Furthermore, the behavior of this general system investigated for the first time, linear and nonlinear behavior of these two steel frames compared to each other, to achieve the benefit of using the circular element in an off-centre bracing system. Eventually, the analytical results revealed that the performance of steel ring at the end of off-centre braces system illustrating as a first defensive line and buckling fuse in the off-centre bracing system.

• Journal of the Korea Institute of Building Construction
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• v.11 no.6
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• pp.567-575
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• 2011

With the development of construction information, a computerization tool for architectural process control is a necessary tool. However, the reality is that the conditions and understanding of users are not sufficient to fully utilize such a tool. In particular, it was analyzed that the reason for the negative feedback from hands-on workers regarding the current process control information system is that there is a difficulty in accessing the system for users that are not process and planning experts, due to a lack of information and technical contents at the phase of control and planning prior to the process plan. Therefore, the demands of users and a direction for the improvement of a system in terms of optimizing process control computerization were investigated, with the aim of addressing the disadvantages of the existing system and developing a professional system that is specialized in the construction industry. Therefore, it is necessary to construct an integrated WBS (IWBS) that combines WBS with CBS, and subsequently, it is judged that the most important aspect is the integrated technology of compatibility and operation of data that is linked with OBS. The process information must then deal with the changing information; in other words, the amount of construction, construction cost, and the required construction period etc., by coding data into a 4-unit index, such as a project unit (WBS Level 1), a project facility unit (WBS Level 2), a management department unit (OBS Level 1), and a control manager unit (OBS Level 2). After that, it was found that it is necessary to develop a computer system to consistently integrate process information into a management department.

• The Magazine of the IEIE
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• v.29 no.10
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• pp.1225-1225
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• 2002

• The Magazine of the IEIE
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• v.29 no.10
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• pp.79-88
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• 2002

• Broadcasting and Media Magazine
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• v.18 no.2
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• pp.100-113
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• 2013

• 대한생식의학회:학술대회논문집
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• 2006.06a
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• pp.72-75
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• 2006

• Journal of The Institute of Information and Telecommunication Facilities Engineering
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• v.8 no.4
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• pp.195-200
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• 2009

In this paper, we propose a new priority Optical Burst Switching (OBS) protocol based on a hop count, which can provide an efficient utilization in optical wireless networks. Under several legacy schemes, a switch drops the burst with a shorter time among ones regardless of its traversed hop count. As a result, the dropped burst that have been traversed more hops might cause to waste bandwidth than the one traversed a few hops. Noting that this problem, we propose a Just Enough Time (JET) with a hop count scheme which can reduce the wasted bandwidth by prioritizing the burst traversed more hops over others. The simulation results shows that the proposed scheme has more advantages over the legacy schemes in terms of the burst blocking probability and the link utilization.

• Bulletin of the Korean Chemical Society
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• v.32 no.1
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• pp.137-140
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• 2011

The aminolysis reactions of phenyl N-benzyl thiocarbamate with benzylamines in acetonitrile at $50.0^{\circ}C$ are investigated. The reactions are first order in both the amine and the substrate. Under amine excess, pseudo-first coefficient ($k_{obs}$) are obtained, plot of $k_{obs}$ vs free amine concentration are linear. The signs of ${\rho}_{XZ}$ (< 0) are consistent with concerted mechanism. Moreover, the variations of $\rho_X$ and $\rho_Z$ with respect to the sustituent in the substrate and large ${\rho}_{XZ}$ value indicate that the reactions proceed concerted mechanism. The normal kinetic isotope effects ($k_H/k_D$ = 1.3 ~ 1.5) involving deuterated benzylamine nucleophiles suggest a hydrogen-bonded, four-centered-type transition state. The activation parameters, ${\Delta}H^\ddagger$ and ${\Delta}S^\ddagger$, are consistent with this transition state structure.

• ETRI Journal
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• v.37 no.5
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• pp.888-897
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• 2015

Group scheduling is an operation whereby control packets arriving in a time slot schedule their bursts simultaneously. Normally, those bursts that are of the same wavelength are scheduled on the same channel. In cases where the support of full wavelength converters is available, such scheduling can be performed on multiple channels for those bursts that are of an arbitrary wavelength. This paper presents a new algorithm for group scheduling on multiple channels. In our approach, to reach a near-optimal schedule, a maximum-weight clique needs to be determined; thus, we propose an additional algorithm for this purpose. Analysis and simulation results indicate that an optimal schedule is almost attainable, while the complexity of computation and that of implementation are reduced.