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The Scientific Analysis of the roofing tiles excavated at Gyeong Bok Gung (경복궁 출토 기와의 자연과학적 조사 연구 - 소주방지, 흥복전지, 함화당지, 집경당지 출토 -)

  • Hong, Jong-Ouk;Park, Ji-Jee;Lee, Han-Hyeong
    • 보존과학연구
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    • s.29
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    • pp.221-238
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    • 2008
  • Roofing tiles are very important archaeological artifacts which show science, architecture of that time, as well as information about the culture. It has been studied by many researchers steadily, but only focusing on archaeological, art historical and architectural study, so it is very difficult to find natural science research. Gyeongbokgung's roofing tiles were excavated from the ruins of same site, however glaze, body colour and shape of tiles are very diverse with the naked eye. Through natural science research which analyze the chemical composition and physical characteristics of roofing tiles's body and glaze examine the physical and chemical characteristics of each roofing tiles. the result of analazed roofing tiles is following. when roofing tiles were classified by 전암대자율 and chromaticity, each group has part of some matches. When you compare with green gazed traditional brick's glaze of Silla period, Gyeongbokgung roofing tiles have more $Al_2O_3$ and less PbO than Silla period's. We can see the technology of increasing firing temperature is better. and glaze colour depends on content of $Fe_2O_3$ and CuO. A lot of CuO tend to be more blue.

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Thermal Instability of La0.6Sr0.4MnO3 Thin Films on Fused Silica

  • Sun, Ho-Jung
    • Korean Journal of Materials Research
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    • v.21 no.9
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    • pp.482-485
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    • 2011
  • $La_{0.6}Sr_{0.4}MnO_3$ (LSMO) thin films, which are known as colossal magnetoresistance materials, were prepared on fused silica thin films by conventional RF magnetron sputtering, and the interfacial reactions between them were investigated by rapid thermal processing. Various analyses, namely, X-ray diffraction, transmission electron microscopy combined with energy adispersive X-ray spectrometry, and secondary ion mass spectrometry, were performed to explain the mechanism of the interfacial reactions. In the case of an LSMO film annealed at $800^{\circ}C$, the layer distinction against the underplayed $SiO_2$ was well preserved. However, when the annealing temperature was raised to $900^{\circ}C$, interdiffusion and interreaction occurred. Most of the $SiO_2$ and part of the LSMO became amorphous silicate that incorporated La, Sr, and Mn and contained a lot of bubbles. When the annealing temperature was raised to $950^{\circ}C$, the whole stack became an amorphous silicate layer with expanded bubbles. The thermal instability of LSMO on fused silica should be an important consideration when LSMO is integrated into Si-based solid-state devices.

A Study on Na effect of Pt-Na/Ce(1-x)Zr(x)O2 Catalyst Structure for WGS Reaction (WGS 반응에서 Pt-Na/Ce(1-x)Zr(x)O2 촉매의 구조에 따른 Na 영향에 대한 연구)

  • Shim, Jae-Oh;Jeong, Dae-Woon;Jang, Won-Jun;Roh, Hyun-Seog
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.6
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    • pp.654-659
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    • 2012
  • The interest in water gas shift (WGS) reaction has grown significantly, as a result of the recent advances in fuel cell technology and the need to develop small-scale fuel processors. Recently, researchers have tried to overcome the disadvantages of the commercial WGS catalysts. As a consequence, supported Pt catalysts have attracted a lot of researchers due to high activity and stability for WGS at low temperatures. In this study, $Pt-Na/Ce_{(1-x)}Zr_{(x)}O_2$ catalysts with various Ce/Zr ratio have been applied to WGS at a gas hourly space velocity (GHSV) of $45,515h^{-1}$. According to TPR patterns of $Pt-Na/Ce_{(1-x)}Zr_{(x)}O_2$ catalysts, the reducibility increases with decreasing the $ZrO_2$ content. As a result, Cubic structure $Pt-Na/Ce_{(1-x)}Zr_{(x)}O_2$ catalysts exhibited higher CO conversion than tetragonal structure $Pt-Na/Ce_{(1-x)}Zr_{(x)}O_2$ catalysts. Expecially, Pt-Na/$CeO_2$ exhibited the highest CO conversion as well as 100% selectivity to $CO_2$. Moreover, Pt-Na/$CeO_2$ catalyst showed relatively stable activity with time on stream. The high activity of cubic structure Pt-Na/$CeO_2$ catalyst was correlated to its higher oxygen storage capacity (OSC) of $CeO_2$ and easier reducibility of Pt/$CeO_2$.

Development of Wastewater Treatment System by Energy-Saving Photocatalyst Using Combination of Solar Light, UV Lamp and $TiO_2$ (태양광/자외선/이산화티타늄($TiO_2$)을 이용한 에너지 절약형 광촉매 반응 처리시스템 개발)

  • 김현용;양원호
    • Journal of Environmental Health Sciences
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    • v.29 no.1
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    • pp.51-61
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    • 2003
  • Pollution purification using titanium dioxide (TiO$_2$) photocatalyst has attracted a great deal of attention with increasing number of relent environmental problems. Currently, the application of TiO$_2$ photocatalyst has been focused on purification and treatment of waste water. However. the use of conventional TiO$_2$ powder photocatalyst results in disadvantage of stirring during the reaction and of separation after the reaction. And the usage of artificial UV lamp has made the cost of photocatalyst treatment system high. Consequently, we herein studied the pilot-scale design to aid in optimization of the energy-saving process for more through development and reactor design by solar light/UV lamp/ TiO$_2$system. In this study, we manufactured the TiO$_2$sol by sol-gel method. According to analysis by XRD, SEM and TEM, characterization of TiO$_2$ sol were nano-size (5-6 nm) and anatase type. Inorganic binder (SiO$_2$) was added to TiO$_2$ lot to be coated for support strongly, and support of ceramic bead was used to lower separation rate that of glass bead The influences were studied of various experimental parameters such as TiO$_2$ quantity, pH, flow rate. additives, pollutants concentration, climate condition and reflection plate by means of reaction time of the main chararteristics of the obtained materials. In water treatment system, variable realtor as solar light/ or UV lamp according to climate condition such as sunny and cloudy days treated the phenol and E-coli(Escherichia coli) effectively.

Adsorption-Desorption Characteristics of NO, $N_2O$ and $O_2$ over Mixed Oxide Catalysts of AlCoPd (1/1/0.05) and AlCoFe (1/1/2) (AICoPd (1/1/0.05) 및 AICoFe (1/1/2)의 혼합금속산화물 촉매에 의한 NO, $N_2O$$O_2$의 흡탈착 특성 연구)

  • Han, A-Reum;Hwang, Young-Ae;Chang, Kil-Sang
    • Clean Technology
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    • v.17 no.2
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    • pp.142-149
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    • 2011
  • The adsorption and desorption behaviors of NO and $N_2O$ over two mixed oxide catalysts, AlCoPd (1/1/0.05) and AlCoFe (1/1/2), have been investigated for the lean $NO_x$ trap applications. The catalysts showed good adsorption capabilities for NO and $N_2O$ without needing oxidation step. The adsorption decreased a lot when they are co-adsorbed with oxygen. While NO kept high adsorbability and selectivity with respect to oxygen, those of $N_2O$ decreased sharply. From the TPD results, NO and $N_2O$ are considered to decompose into nitrogen and oxygen in the higher temperature range and the oxygen seems to be strongly attached to the catalysts even at high temperature.

The Characteristics of Mg0.1Zn0.9O Thin Films on PES Substrate According to Fabricated Conditions by PLD (PLD법으로 PES 기판 위에 제작된 Mg0.1Zn0.9O 박막의 제작 조건에 따른 특성)

  • Kim, Sang-Hyun;Lee, Hyun-Min;Jang, NakWon;Park, Mi-Seon;Lee, Won-Jae;Kim, Hong-Seung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.8
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    • pp.602-607
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    • 2013
  • Concern for the TOS (Transparent Oxide Semiconductor) is increasing with the recent increase in interest for flexible device. Especially MgZnO has attracted a lot of attention. $Mg_xZn_{1-x}O$, which ZnO-based wideband-gap alloys is tuneable the band-gap ranges from 3.36 eV to 7.8 eV. In particular, the flexible substrate, the crystal structure of the amorphous as well as the surface morphology is not good. So research of MgZnO thin films growth on flexible substrate is essential. Therefore, in this study, we studied on the effects of the oxygen partial pressure on the structural and crystalline of $Mg_{0.1}Zn_{0.9}O$ thin films. MgZnO thin films were deposited on PES substrate by using pulsed laser deposition. We used XRD and AFM in order to observe the structural characteristics of MgZnO thin films. UV-visible spectrophotometer was used to get the band gap and transmittance. Crystallization was done at a low oxygen partial pressure. The crystallinity of MgZnO thin films with increasing temperature was improved, Grain size and RMS of the films were increased. MgZnO thin films showed high transmittance over 80% in the visible region.

Study on the Free CaO Analysis of Coal Ash in the Domestic Circulating Fluidized Bed Combustion using ethylene glycol method (에틸렌글리콜법을 활용한 국내 순환유동층보일러 석탄회의 Free CaO 평가 연구)

  • Seo, Jun-Hyung;Baek, Chul-Seoung;Kim, Young-Jin;Choi, Moon-Kwan;Cho, Kye-Hong;Ahn, Ji-Whan
    • Journal of Energy Engineering
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    • v.26 no.1
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    • pp.1-8
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    • 2017
  • This study was carried out to physicochemical properties and free CaO contents of coal ash in domestic circulating fludized bed combustion power plant using ethylene glycol method. Results of physicochemical properties, there are many differences in CaO contents for the region position in CFBC plant. The reason, It is considered to be reflected that regulation of exhaust concentration for oxides of sulfur and other operation characteristics of region position in CFBC plant. Free CaO contents are 1.96 ~ 10.78% of fly ash and 0.07~4.24 % of bottom ash, fly ash is higher than in the bottom ash. besides CaO contents of raw materials, particle distribution have a lot of influence Free CaO contents.

Design of a high-speed universal controller using DSP and its application (DSP를 이용한 고속 범용 제어기의 구현과 응용)

  • 박준영;이성욱;장평훈
    • 제어로봇시스템학회:학술대회논문집
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    • 1997.10a
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    • pp.69-72
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    • 1997
  • A universal controller is designed using a DSP (digital signal processor). The design objectives of the system are to implement control algorithms that require a lot of calculations and to develop a convenient user-interface environment. To demonstrate the efficiency of the system, the time delay control algorithm is implemented for the 2 D.O.F.SCARA type robot and the experimental results are presented.

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A Study on Operations Research Models for Environmental Management (환경관리에서의 O.R. 모형에 관한 연구)

  • Chang ByungMan
    • Korean Management Science Review
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    • v.21 no.2
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    • pp.1-14
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    • 2004
  • This paper presents a review on the operations research modeis for environmental management including water, land, and air poliution in the environmental chain and including waste treatment, reverse logistics, and product recovery in the supply chain for last 30 years. The integrated and globalized environmental issues have given OR professionals a lot of natural opportunities for an effective environmental management with mathematical programming and computer simulation tool.

The diagnosis and appropriate reducing method on the harmonics for the induction motor installed inverter system (저압인버터를 적용한 펌프모터의 고조파 분석 및 저감방안)

  • Kim, Gi-Tae;Lee, Eun-Chun;Lee, Kyong
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.2056-2057
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    • 2007
  • Recently we installed inverter system in $ind{\acute{u}}ction-m{\acute{o}}tor$ for the energy saving. But inverter system generates harmonics, and it causes a lot of issues. malfunction of meter, damage of instrument, overheating of motor. In this study, you can see how to deal with harmonics of inverter system by diagnosis of the power quality.

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